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Sum Signed Graph
A sum signed graph S = (G, f, and#963;) is a signed graph of the underlying graph G where f : V (G) and#8722;and#8594; {1, 2, . . . , | V (G) |} is a bijective function and and#963; : E(G) and#8722;and#8594; {+, and#8722;} is newlinea mapping such that and#963;(uv) = +, whenever f(u) + f(v) and#8804; n and and#963;(uv) = and#8722;, whenever f(u) + f(v) gt n. The minimum number of negative and positive edges among all the sum signed labelings of G is known as rna and rna complement number respectively. The maximum number of positive edges among all the sum signed labelings of G is known as adhika number. The set X and#8838; V (G) is said to be a s - dominating of a signed graph whenever X is a dominating set and there exists exactly s number of negative edges between X and its complement. The minimum cardinality of such a dominating set over all signed graphs of the graph G is called an s - domination number. newlineIn the present study, we initiate the study of a new labeling in signed graphs namely, newlinesum signed labeling. The characteristics of sum signed graphs and the bound of rna number of in terms of the number of vertices in the underlying graph are explored by examining the rna number of different graphs. The properties of signed graphs such as negating and balancing is analyzed. The relation between rna number and rna complement number is established. The connection of sum signed labeling with parity signed labeling and cordial labeling is discussed. The absolute cordial condition for graphs satisfying sum signed labeling is examined. The concept of s - domination was also introduced during this period of study. The s domination in both the positive and negative homogeneous signed graph is investigated for each value of s. The properties of s domination in sum signed graphs are also analyzed. The s - domination number for specifc values of s is investigated for various graphs. The maximum value of s for a graph for which the s - domination will exist is discussed. -
Suppression and redfinition of self in the selct novels of Toni Morrison and ALice Walker
Literature is a mirror held onto the society that reflects the culture, history and socio-political issues of specific periods. Books have the uniqueness of transforming lives by weaving characters, to whom we are able to relate their trials, tribulations and achievements become our own. Although confined to the Afro-American milieu, Alice Walker s The Color Purple and Toni Morrison s The Bluest Eye, Sula and Beloved raises issues and concerns that are universal to women across the globe. These writers try to lend voice to an otherwise marginalized and newlinesuppressed group of women, who have been denied a dignified existence. This research, through the methodology of critical analysis and interpretation of texts, tries to understand the concept of self, from the western and eastern perspectives. In the due process, the various factors that contribute to the formation of an individual s self are also identified. Through an analysis of the newlinefemale protagonists in the works of Morrison and Walker, this study examines how it is possible for a woman to progress from the margins to a position that is central, from object to subject. newlineMost often, women are not even conscious that they too have an individuality of their own and need to lead a dignified life. Having got so habituated to oppression, it has almost become a way of life for them. They need to be conscious and aware of the fact that they have to create a space of their own, without compromising on their individuality and dignity. When they fail to do this,they just stagnate and become mere pawns in the hands of men and tend to get exploited. Most of newlinethe female protagonists discussed in this study, go through this phase and are unable to extricat themselves from the traumatized conditions that engulf them. newlineThis study clearly focuses on how women need to be conscious of what is happening to them and realize that they are being deprived of their individuality and dignity. -
Sustainable tourism development through community based waste management in backwater destinations of kerala
According to the United States Environmental Protection Agency, (2002) solid waste newlinemanagement is a great challenge in many tourist destinations because improperly managed solid waste can threaten the environment as well as the life of the local community. Sewage waste and plastic material from tourism houseboats are increasing the pollution in the backwaters of south Kerala. These days it is not completely proper for touristic activities because of their physical and morphological attributes. This can lead to unsustainable negative impact on the backwater (Iskander and El 2014).Therefore this study was seeking to understand the influence of community based waste management towards the sustainable tourism development in the backwaters of south Kerala. The research adopted a descriptive research design. The study consists of three newlinecategories of stakeholders. Public sector, Private sector, and Local community. Public Sector stakeholders include Hotel Officials, Resorts officials and houseboat officials. Private sector stakeholder includes the government representative of concerned backwater destination. Descriptive statistics, ANOVA, Confirmatory factor analysis (CFA), SEM Modelling are the various statistical techniques used in this study. Cross-case analysis was used to analyse newlinethe qualitative aspects of the research study. This study also develops and test a community based waste management model for newlinesustainable tourism development and considered the influence of factors on community support, community involvement, perceived benefits and perceived cost. The structural model indicates that increasing perceived benefits and decreasing perceived cost from backwater tourism would help to enhance community involvement and support for newlinesustainable tourism development in the backwaters of south Kerala. -
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Sustainable tourism management : Issues and challenges of eco wildlife resorts in karnataka
Sustainable tourism principles comprise of visitor satisfaction, the economic newlinesustainability of the industry, environment conservation, socio-cultural and economic newlinedevelopment of local communities. The tourism industry has to consider all these elements while developing any form of tourism for its long-term sustainability. Eco and wildlife resorts are one of the prominent and attractive segments of the accommodation sector. It has a major implication for implementing sustainable tourism practices in their daily operations since they are set close to nature and reside in pristine wildlife regions. It is inevitable for eco and wildlife tourism, to consider all newlinethe elements of sustainable tourism practices and to implement it in their day to day newlineactivities. At the same time, they might have to face issues and challenges in newlineimplementing sustainable practices. So, the main objective of the research is to newlineunderstand operational issues and challenges of eco and wildlife resorts in achieving newlinesustainable tourism principles. The purpose of the study is to investigate the issues and challenges faced by eco and wildlife resorts in implementing sustainable tourism practices and understanding the indicators used by the resorts to measure their sustainable tourism newlinepractices. The scope of the study covers selected eco and wildlife resorts in Karnataka because most eco and wildlife reserve areas are shared by pristine natural areas and are located near villages. The targeted respondents of the study are eco and wildlife resort managers and visitors of eco and wildlife resorts. Based on purposive sampling, 30 resorts are selected for the study, and 410 visitors are selected based on convenient sampling technique. The study employs a mixed-method research design. newlineTriangulation design is used in the study. The study adopted a tool to identify the newlinesustainable tourism indicators used by the resorts to measuring their sustainable newlinetourism practices. -
Sustainable tourism management: Issues and challenges of eco and wildlife resorts in Karnataka
Sustainable tourism principles comprise of visitor satisfaction, the economic sustainability of the industry, environment conservation, socio-cultural and economic development of local communities. The tourism industry has to consider all these elements while developing any form of tourism for its long-term sustainability. Eco and wildlife resorts are one of the prominent and attractive segments of the accommodation sector. It has a major implication for implementing sustainable tourism practices in their daily operations since they are set close to nature and reside in pristine wildlife regions. It is inevitable for eco and wildlife tourism, to consider all the elements of sustainable tourism practices and to implement it in their day to day activities. At the same time, they might have to face issues and challenges in implementing sustainable practices. So, the main objective of the research is to understand operational issues and challenges of eco and wildlife resorts in achieving sustainable tourism principles. -
SVM Ensemble for Insurance Data Analysis
Data mining is the process of analysing data from different perspectives and summarizing it into useful information. Companies with a strong consumer focus use data mining. The information getting from datamining is useful to increase revenue and reduce overall costs of the company. It is applied in retail field, financial sector, communication media, and in marketing organizations. Datamining facilitate these companies to determine relationships among company internal factors such as price, product positioning, or staff skills, and external factors such as competition in products, economic indicators, and customer demographics. Ensemble learning is a machine-learning paradigm where multiple models or learners are trained to solve the problem. This research explores the usage of SVM ensemble for Insurance Data Analysis. The number of Insurance firms is increasing day by day. The main objective of this research is to find out the best policy from a given list of Insurance policies. In this research a detailed study of SVM ensemble is done. An insurance dataset obtained from UCI knowledge discovery in Databases Archive is taken in the research analysis. From the dataset five different Non-life insurance policies were selected and used in this research work. The categories of policies include Fire policy, Home policy, Car policy, Kissan policy and Boat policy. AdaBoost, multiclassifier SVM ensemble was created and tested with the insurance dataset. SVM ensemble produces better accuracy than other ensembles. The knowledge flow of SVM ensemble is loaded in Weka. From each category, the policy that gives a highest accuracy value for SVM ensemble is considered to be the best policy. A graphical user interface is also developed using .NET framework, to view the policy output. This system helps the user to find out a best policy from the analysed data. KEYWORDS: SVM ensemble, Insurance policy, Accuracy, ROC, Support Vector Machine. -
Symbols as Photographic Texts in the Travel Narratives of Paulo Coelho
Brazilian writer Paulo Coelho de Souzas The Pilgrimage, The Alchemist, Zahir, Aleph and Hippie are known for using literary symbols to describe journeys where the protagonists travel to different destinations searching for something valuable. The author resorted to multiple religions, cultures, traditions, mythologies and folklore to derive inspiration to use those symbols and frame his philosophical thoughts. As the symbols used by Coelho can be deciphered in whatever way subject to personal interpretations, one way of understanding them can be from the perspectives of their already established meanings in religions, cultures, traditions, mythologies and folklore. Such a way of understanding limits the possible meanings that can be derived from those symbols. Moreover, another sign system is known for conveying limited meanings, usually called photographs. Though absolute material accuracy is seen as the hallmark of photography, the meaning of photographs also depends upon their interpretations, and photographic truth is considered a myth. Still, photographs possess documentary properties and convey limited meanings to a large extent. This thesis studied the idea of photography, defining the same by understanding the historical developments in photography over time. Knowing the definition and properties of photographs, it looked at how photographs convey limited meanings and exhibit 'iconic' properties in general. After isolating and studying the literary symbols used by Coelho in the five travel narratives mentioned above using the Peircean model of semiotic analysis, the thesis concludes that symbols act as photographic texts to a certain limit in the five novels, as they tend to move towards becoming 'iconic' from 'symbolic' if understood from the perspectives of their existing meanings in religions, cultures, traditions,mythologies and folklore. -
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Synergetic Effect of Metal Nanoparticle Embedded Graphene Membrane : A Novel Approach for Antimicrobial Filtration
Water, the elixir of life, holds a profound significance that extends far beyond its essential utility. It's not just a resource; it pulsates as the life force of our existence, intricately woven into the very fabric of our daily lives. Water is the silent force that shapes our world, from nurturing our health and sustaining social structures to fueling economic development and fostering the environment. However, the adequacy of potable water quality confronts adverse impacts stemming from inadequate wastewater treatment, escalating domestic and industrial waste, and the microbial contamination of surface water sources. Furthermore, climate change emerges as a pivotal factor intensifying the depletion of water levels in natural resources due to diminished rainfall. Reports project that, by 2025, two-thirds of global population might contend with water scarcity. Given the persistence of current scenario, there exists a notable potential for significant conflicts among nations stemming from water scarcity. However, such a predicament can be mitigated through proactive measures, including the preservation of natural resources and the implementation of advanced technologies to recover fresh water from contaminated sources. Advanced technologies for the purification of contaminated water encompass sedimentation, precipitation, filtration, and ion exchange, which can effectively extract clean water from diverse impurities. Notably, membrane-based purification has gained prominence in recent years, owing to its cost- effectiveness and energy-saving attributes. Carbon-based nanomaterials, including carbon nanotubes,fullerenes and graphene have garnered considerable attention in recent research studies, particularly in the realm of membrane applications. Within this, membranes fabricated by carbon nanotubes (CNT) stand out, showcasing exceptional filtering properties attributed to their tubular carbon structure. However, the cost-effectiveness and ease of synthesis impediments pose significant challenges, acting as bottlenecks for their widespread application in water purification. Consequently, graphene-based membranes emerge as a promising alternative to CNT membranes, demonstrating selective separation of ions and molecules. Specifically, membranes derived from graphene oxide (GO) and reduced graphene oxide (rGO) exhibit superior filtering capabilities compared to ceramic and polymeric counterparts, owing to their layered structure featuring tunable nanochannels, hydrophilic or hydrophobic nature, and commendable mechanical resilience. Graphene oxide solution synthesis has been done using Hummer's method, followed by fabrication of high-quality membranes through vacuum filtration techniques. Current work emphasis on recognizing the pivotal influence of membrane thickness on both water flux and dye rejection, meticulous optimization of filtration properties by producing graphene oxide (GO) membranes at various concentrations. Furthermore, reduction of graphene oxide through the hydrothermal method, enabling a comprehensive comparative analysis of water flux and rejection between graphene oxide (GO) and reduced graphene oxide (rGO) membranes was carried out. In our investigation, the results unequivocally validate that the GO 500 sample exhibits optimized filtration properties. Furthermore, the reduced graphene oxide (rGO) variant surpasses graphene oxide (GO) in terms of filtration efficacy, demonstrating superior filtering properties. It is noteworthy to highlight that reduced graphene oxide (rGO) exhibits less antibacterial properties compared to graphene oxide (GO). The disinfection capability of the membrane is pivotal in ensuring the recovery of pure water. To bolster the antibacterial features of GO, we have undertaken an enhancement strategy by incorporating silver nanoparticles. Silver nanoparticle, showcases multifaceted properties including surface plasmon resonance and unique morphologies, which contribute significantly to the inactivation of bacteria. The conducted studies reveal that membranes incorporating graphene oxide with silver (GO-Ag) exhibit remarkable antibacterial properties against both gram-positive and gram-negative bacteria. Additionally, these membranes demonstrate appreciable filtration capabilities and exhibit effective antifouling properties, further emphasizing their potential for advanced applications in water purification systems. Fouling is a significant challenge in membrane technology, as the continuous passage of contaminants results in the formation of layers on membrane surface, thereby diminishing its filtration efficiency. Despite the antifouling properties exhibited by GO- Ag membranes, there exists further improvement in enhancing performance and extending the membrane's lifespan. To address this, we have undertaken a reduction of graphene oxide and incorporated silver nanoparticles, aiming to augment the antifouling properties and overall efficacy of membrane. The conclusive findings indicate that fine-tuned membrane exhibits remarkable antibacterial properties, superior filtration capabilities, and a minimal irreversible fouling ratio. These outcomes provide confirmation that the fabricated membranes stand as potential materials for water purification applications, showcasing a well-rounded set of properties essential for effective and sustainable water treatment. -
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Synthesis and characterization of acid hydrazone complexes
The new azomethine compounds derived from Acetophenone benzhydrazone and Acetophenone nicotinicacidhydrazone have been prepared Further it is synthesized with Cu(II) and Co(II) salts to form stable complexes. The ligand and metal complexes have been characterized by Elemental analysis, IR, NMR, UV/Vis Spectrometry, Vibrating sample magnetometric measurements and Gouy Balance method. The nature of bonding and the stereochemistry of the complexes have been deduced from infrared spectra, electronic spectra, magnetic susceptibility, and an octahedral geometry has been suggested for cobalt (II) and square pyramidal structure for copper (II) complex. The complexes are non-hygroscopic, and photo stable crystalline powders with different melting point. The solubility of the metal-complexes in various solvents confirmed the diversity of the complexes as the ligands. The coordination process takes place through the carbonyl oxygen and the azomethine nitrogen atom, the anionic ion is in the outer sphere of the copper complex. The complexes were proposed to have the formulae [ML1.phen(H2O)]NO3H2O. where M=Cu(II),Co(II) ,and HL1 = acetophenone benzhydrazone and [MHL2phen.( NO3)2 ]H2O HL2 = Nicotinic acid acid hydrazone KEY WORDS: Complexes, Hydrazones, Acetophenone, Synthesis, Characterization. -
Synthesis and characterization of heterocyclic derivatives and studies on their photophysical properties
Photophysical properties such as absorption, fluorescence, quantum yields and lifetime of fluorescent heterocyclic compounds have been a subject of extensive research interest. Absorption and fluorescence emission of fluorescent molecules results in electronic transitions between ground and singlet excited state. The bathochromic or hypsochromic spectral shift brings a considerable change in dipole moment of both the electronic states through solute-solvent interactions. We have synthesized some heterocyclic compounds and studied thier photophysical properties. Different derivatives such as Schiff base, chalcone, maleimide and pyranopyrazole were synthesized and characterized by FTIR, 1H NMR, 13C NMR, mass spectrometry and elemental analysis. Photophysical properties of synthesized compounds have been studied through absorption and fluorescence spectroscopy and DFT calculations. We have used solvatochromic approaches such as Bilot-Kawski, LippertMataga, Bakhshiev, Kawski-Chamma-Viallet and Reichardt's solvent polarity parameters to evaluate dipole moments of ground state and singlet excited state of the synthesized heterocyclic compounds. The influence of specific and non-specific interactions on spectral properties was also investigated by using Kamlet-Abboud-Taft and Catalan multiple linear regression equations. X-ray diffraction analysis of hydroxyl Schiff base derivative has been carried out due to the presence of strong inter and intra molecular hydrogen bonding. Solvatochromic analyses of synthesized compounds were done using Bilot-Kawski, Lippert-Mataga, Bakhshiev, Kawski- Chamma-Viallet and Reichardt methods. All Solvatochromic graphs have been plotted for spectral parameters against solvent polarity parameters using Origin 8 software. The obtained experimental results from all methods were compared with theoretical results. The correlation coefficient between microscopic solvent polarity parameter and spectral Stokes-shifts were higher in comparison to bulk solvent polarity functions. Graphs for each molecule provided good correlation based on least square analysis. Dipole moment values of ground and excited states were calculated using slopes of different solvatochromic methods. Higher value of singlet excited state dipole moment indicated that the molecules were more polarised in the singlet excited state. Kamlet-Abboud-Taft and Catalan multiple linear regression (MLR) analyses were used to analyse the solvent effects on absorption, emission and difference in spectral energies of the synthesized molecules. Single point method was used to calculate the quantum yields of the synthesized compounds in ethanol using an ethanolic solution of anthracene as a reference compound. Edwards atomic increment method was applied to calculate the Onsager cavity radii of all the molecules using van der Waals volume. DFT/TD-DFT was used for quantum mechanical calculations of all the molecules. The geometrical structures of the synthesized molecules were optimized using B3LYP/6-311G(d, p) basis set. The positions of HOMO-LUMO orbitals were identified and the band gaps for all the molecules were calculated. Mulliken atomic charges and electrostatic potential surface (MEP) have also been evaluated for all the molecules to identify the ICT pathway and evaluate electrophilic and nucleophilic reactive sites around the molecules . The fluorescence quenching studies of a chalcone derivative by aniline in n-butanol and 1,4-dioxane was performed at 25 ? C which indicated that quenching reactions are diffusion limited. -
Synthesis and Characterization of Vanadyl Complexes of Heterocyclic Acid Hydrazones
Two acid hydrazones, Furan-2-carbaldehyde nicotinic hydrazone and Furan-2-carbaldehyde benzhydrazone have been synthesised and they are characterized by elemental analysis, IR, NMR and UV spectral analysis. Vanadyl complexes of these two hydrazones were synthesised and characterised by elemental analysis, IR, UV, EPR, molar conductivity and magnetic susceptibility measurements. Spectral data indicates the square pyramidal geometry for the monomeric ve coordinated oxovanadium (IV) complexes with the general formula [VO(L)(OCH3 )].The vanadium complex of the acid hydrazone was studied for its catalytic activity. The complex was found to be a good catalyst in quinoxaline synthesis. -
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