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Large power factors in wide band gap semiconducting rFeO3 materials for high-temperature thermoelectric applications
While most of the thermoelectric materials work well only at low and mid temperatures, high-temperature thermoelectric materials (T > 900 K) are equally important for the operation of deep-spacecraft missions, nuclear reactors, and high-temperature industrial reactors. To accomplish this demand, this work provides insights into wide band gap semiconducting RFeO3 (rare-earth orthoferrites) for high-temperature thermoelectric applications. Using the first-principles density functional theory calculations, we have demonstrated the coexistence of extremely flat and corrugated flat bands near the Fermi region in a wide band gap material. The presence of such features enhances and sustains the thermopower, electrical conductivity, and power factor, which are the crucial factors for the efficiency of thermoelectric materials. Semiclassical Boltzmann formalism was then employed to study the transport properties of four orthorhombic RFeO3 materials (R = Pr, Nd, Sm, and Gd). Our results reveal high Seebeck coefficients (thermopower) along with the large electrical conductivities over the high hole doping carrier concentration and in the high-temperature region (T > 900 K). Furthermore, significantly large power factors are obtained with very low theoretical minimum lattice thermal conductivity in the range 1.41?1.51 W m?1 K?1. These huge power factors directly suggest the maximum power output in RFeO3, which we believe is a more appropriate performance index than the figure of merit, especially for high-temperature thermoelectric applications. We also emphasize that the outcomes of our work would be certainly useful for experimentalists in designing high-temperature thermoelectric materials. 2020 American Chemical Society -
Ultrahigh Power Factors in Ultrawide-Band-Gap GaB3N4and AlB3N4for High-Temperature Thermoelectric Applications
With recent thermoelectric studies concentrating too much on low- and mid-temperature applications, an interesting question is, "are there any materials suitable for high-temperature thermoelectric operations?"To answer this, we have demonstrated in this work the viability of the ternary ultrawide-band-gap materials GaB3N4 and AlB3N4 for high-temperature thermoelectric applications using the first-principles calculation method. Our accurate transport calculations, considering both elastic and inelastic scattering mechanisms, reveal the ultrahigh power factors as high as 1821 ?W m-1 K-2 in GaB3N4 and 1876 ?W m-1 K-2 in AlB3N4 at 2000 K. The power factors are calculated from the Seebeck coefficients and electrical conductivities for both electron and hole carrier concentrations between 1018 and 1021 cm-3. For the figure-of-merit (ZT) calculation, the obtained power factors along with the electronic thermal conductivities determined from the definite Lorenz numbers and the lattice thermal conductivities from the phonon vibrations were used. The calculated ZT values seem to be appreciable for high-temperature applications considering the materials' stability factor and the temperature range within the optimum electron carrier concentration of 1021 cm-3. Although the lattice thermal conductivities are higher, which decrease the values of ZT, considering the ultrahigh power factors instead of the ZT factor could be the right choice for high-temperature thermoelectric applications. -
Effective and Efficient Video Compression by the Deep Learning Techniques
Deep learning has reached many successes in Video Processing. Video has become a growing important part of our daily digital interactions. The advancement of better resolution content and the large volume offers serious challenges to the goal of receiving, distributing, compressing and revealing highquality video content. In this paper we propose a novel Effective and Efficient video compression by the Deep Learning framework based on the flask, which creatively combines the Deep Learning Techniques on Convolutional Neural Networks (CNN) and Generative Adversarial Networks (GAN). The video compression method involves the layers are divided into different groups for data processing, using CNN to remove the duplicate frames, repeating the single image instead of the duplicate images by recognizing and detecting minute changes using GAN and recorded with Long Short-Term Memory (LSTM). Instead of the complete image, the small changes generated using GAN are substituted, which helps with frame-level compression. Pixel wise comparison is performed using K-nearest Neighbours (KNN) over the frame, clustered with K-means and Singular Value Decomposition (SVD) is applied for every frame in the video for all three colour channels [Red, Green, Blue] to decrease the dimension of the utility matrix [R, G, B] by extracting its latent factors. Video frames are packed with parameters with the aid of a codec and converted to video format and the results are compared with the original video. Repeated experiments on several videos with different sizes, duration, Frames per second (FPS), and quality results demonstrated a significant resampling rate. On normal, the outcome delivered had around a 10% deviation in quality and over half in size when contrasted, and the original video. 2023 CRL Publishing. All rights reserved. -
Improving the Security of Video Embedding Using the CFP-SPE Method
With the amount of data being transferred on a daily basis, it is becoming increasingly dangerous to save data on the Internet in the face of intruders or hackers. This study paper is one of the most effective ways to transmit information in a secure and confidential manner. The authors previously disclosed a way for embedding a secret video inside a cover video in their prior work. The writers have implemented a number of techniques to incorporate the secret video. The current work improves on the existing approach by including encryption and decryption concepts into the video embedding process. The secret data for either a large or little amount of information is put on the cover video utilising the embedding technique. Our proposed method combines compression, encryption, decryption, and secret information embedding to provide a more secure data transfer. 2022 Karthick Panneerselvam et al. -
A MULTI-OBJECTIVE HUNTER-PREY OPTIMIZATION FOR OPTIMAL INTEGRATION OF CAPACITOR BANKS AND PHOTOVOLTAIC DISTRIBUTION GENERATION UNITS IN RADIAL DISTRIBUTION SYSTEMS
This article put forward the determination of the optimal siting and sizing of capacitor banks and PV-DG (Photo-Voltaic Distribution Generation) units in a radial distribution system. A modern population-based optimization algorithm, Hunter-Prey Optimization (HPO), is applied to determine the optimal capacitor bank and PV-DG placement. This algorithm, HPO, got its motivation from the trapping behaviour of the carnivore (predator/hunter) like lions and wolves towards their target animal like deer. The typical IEEE-33 & 69 test bus systems are scrutinized for validating the effectiveness of the suggested algorithm using MATLAB software R2021b version. The acquired results are collated with the existing heuristic algorithms for the active power loss criterion. The nominal or base values for system losses and voltage profile were considered for the comparison, with the results from HPO. The HPO application has an efficient performance in figuring out the most favourable location and capacity of the capacitor banks and PV DGs compared with the other techniques. 2023 by authors and Galileo Institute of Technology and Education of the Amazon (ITEGAM). -
HunterPrey Optimization Algorithm for Optimal Allocation of PV, DSTATCOM, and EVCS in Radial Distribution Systems
This research article instigates a seminal approach for optimizing reactive power in renewable energy sources (RES) and electric vehicles (EVs) coalescing distribution systems, using the innovative HunterPrey Optimization (HPO) algorithm in conjunction with DSTATCOM as a reactive power compensator. The proposed methodology aims to minimize losses, enhance voltage stability, and improve overall system performance by simultaneously optimizing reactive power flows in photovoltaic RES (PV_DG), EV charging stations (EVCS), and DSTATCOMs within the distribution system. Simulations carried on IEEE-33, IEEE-69, and IEEE-118 test bus systems in MATLAB environment demonstrate that the HPO-based approach achieves a 91.47% and 96.61% reduction in real power losses and an improvement in voltage profile with a minimum voltage value of 0.991 and 0.994 p.u. (respectively for IEEE-33 and 69 bus systems), compared to traditional algorithms. These results highlight the lofty performance of the HPO method, effectively addressing the challenges posed by the integration of RES and EVs along with DSTATCOM. 2024 John Wiley & Sons Ltd. -
Cytogenetic Consequences Of Food Industry Workers Occupationally Exposed To Cooking Oil Fumes (Cofs)
Background: Cooking oil fumes (COFs) with smoking habits is a substantial risk that aggravates genetic modifications. The current study was to estimate the biological markers of genetic toxicity counting Micronucleus changes (MN), Chromosome Aberrations (CA) and DNA modifications among COFs exposures and control subjects inherent from South India. Materials and Methods: Present analysis comprised 212 COFs with tobacco users and equivalent number of control subjects. Results: High frequency of CA (Chromatid type: and chromosome type) were identified in group II experimental subjects also high amount of MN and DNA damage frequency were significantly (p < 0.05) in both subjects (experimental smokers and non-smokers). Present analysis was observed absence of consciousnessamong the COFs exposures about the destructive level of health effects of tobacco habits in working environment. Conclusion: COFs exposed workers with tobacco induce the significant alteration in chromosomal level. Furthermore, a high level of rate of genetic diseases (spontaneous abortion) were identified in the experimental subjects. This finding will be helpful for preventive measures of COFs exposed workers and supportive for further molecular analysis 2021,Asian Pacific Journal of Cancer Prevention. All Rights Reserved. -
Carcinogens in Food: Evaluating the Presence of Cadmium, Lead, in Poultry Meat in South India
Objective: Local chickens were spontaneously sampled and slaughtered in the central markets of Coimbatore, Erode, and Namakkal districts, South India. Materials and Methods: Wet digestion was used to extract lead (Pb), cadmium (Cd), and zinc (Zn) in their blood and selected different organs (intestine, breast, liver, and gizzard), and their concentrations were measured using an atomic absorption spectrophotometer. Results: Apart from the blood of chickens from Coimbatore and Namakkal, where Pb was not found, the concentrations of Pb in the blood and organs of chickens from the three towns ranged from 1.8 to 8.33 mg/kg, exceeding the maximum tolerance thresholds (0.1 mg/kg) in internal organs of poultry birds. Except for the intestine of chickens from the three areas, Cd was only found in the heart, blood, and gizzard of Erode chickens, as well as the liver and gizzard of Namakkal chickens, in concentrations ranging from 0.13 to 0.58. According to threshold level, the upper limit met the maximum limits (0.5 mg/kg). Zn was found in all sections of chickens from the three selected districts, with concentrations ranging from 4.96 to 174.17 mg/kg. Conclusion: Its concentrations were within the permissible limits (10-50 mg/kg) in some areas of certain chickens, but it surpassed the permissible limit in the liver of chicken from Coimbatore. Any organs and blood from local chickens sold in Coimbatore, Erode, and Namakkal areas can be hazardous to ones health. This work is licensed under a Creative Commons Attribution-Non Commercial 4.0 International License -
Exosome mediated cell signal toward breast cancer metastasis: A comprehensive review
Breast cancer (BC) is among the most frequent cancer and is, more challenging to treat due to its heterogeneity and metastatic ability. Among extracellular vesicles, exosomes are quite significant for diagnosis and prognosis, given their pleiotropy and drug-carrying abilities. Studying their functions, morphology, biogenesis, and involvement in important pathways can help us understand their role in BC proliferation. A detailed review of their roles in different stages of BC as metastatic disease, such as proliferation, intravasation, epithelial to mesenchymal transition, extravasation, immune evasion, and metastatic growth, can help us understand how to target therapy as well as diagnosis. In the metastatic process, exosome involvement can also be tied to the seed and soil hypothesis, allowing us to understand the direction of progression. From their isolation to the study of their contents in relevance to BC in the process of detection, we have therapeutic applications and can make a significant contribution to the field of oncology. Hence, the present review focuses on this exosome-mediated cell signaling molecule and its importance in BC progression and development. 2022 Anushka and Pappuswamy, et al. -
Structure of molecule, density gradient, orbital locator and reactivity of 5,6-dichloro-1-cyclopentyl-2-(methylsulfinyl)-1H-benzimidazole- potent inhibitor of map kinase
The present work consists of theoretical studies with the DFT technique on the benzo[d]imidazole derivative, 5,6-Dichloro-1-cyclopentyl-2-(methylsulfinyl)-1H-benzimidazole, and its biological evaluation in silico. The molecule is subjected to geometry optimisation and further DFT studies in gas and solvent phases. Upon solvation with polar solvents, gradual variation in properties result. Topological analyses are performed using Multiwfn software (ELF, LOL, RDG and charge transfer) to illustrate the electron density distribution, interactions, and excitation within the title molecule. ADMETLab 2.0, PreADMET, and SwissADME online tools compute the ADMET profile. Select MAP-kinase target proteins are docked against the title molecule using AutoDock Tools and PyMOL. Discovery Studio Visualizer software is run for visualisation and result analysis of the docked ligand-protein complex. 2023 Elsevier B.V. -
Solvent-solute interaction, thermodynamic behaviour, structural, chemical and anti-cancer biological properties of 3(2H)-furanone derivatives
In this work, the structures, reactivities, and electronic and biological properties of the 3(2H)-furanone derivatives, 2-hydroxy-2,5-diphenyl-4-(phenylamino)furan-3(2H)-one (HDPF), 2-methoxy-2,4,5-triphenylfuran-3(2H)-one (MTPF), 3-oxo-2,4,5-triphenyl-2,3-dihydrofuran-2-yl acetate (OTDF), and 2-chloro-2,4,5-triphenylfuran-3(2H)-one (CTPF), are explored via theoretical investigations using DFT (Density Functional Theory) techniques as the main tools for the study. The DFT studies include geometry optimisation, FMO (Frontier Molecular Orbital) analysis, theoretical UV studies, molecular electrostatic potential (MEP) investigations, non-linear optical (NLO) analyses, and the evaluation of thermodynamic parameters. Multiwfn 3.8 software is utilised to conduct the topological analyses. The ADME (Absorption, Distribution, Metabolism, Excretion) profiles are produced with the SwissADME online tool. The target proteins, MCL-1 (Myeloid cell leukemia-1), BCL-2 (B-cell lymphoma-2), and myeloblastin, are docked with the title molecules using AutoDock 1.5.6. 2023 Elsevier B.V. -
Computational investigation into structural, topological, electronic properties, and biological evaluation of spiro[1H-indole-3,2?-3H-1,3-benzothiazole]-2-one
The current work comprises theoretical studies on spiro[1H-indole-3,2?-3H-1,3-benzothiazole]-2-one employing density functional theory (DFT). The optimized structure and molecular geometry of the title compound were calculated. Topological studies were performed using Multiwfn 3.8, these include ELF, LOL and RDG studies to identify the main bonding regions and weak interactions in the molecule. Solvation effects were studied by taking different green solvents, using IEFPCM model. Solvation effects were investigated for electronic properties (HOMO-LUMO and UV), MEP, and NLO properties and some variation is observed in the behaviour of the title compound in gas and solvent phases. Natural bond orbital (NBO) calculations are performed to study the inter- and intra-molecular charge transfer and stability. Pharmacological evaluation comprising of drug-likeness, ADME, environmental toxicity properties using online tools such as SwissADME, Pre-ADMET, and GUSAR, to determine whether the molecule can be a potential drug candidate is performed. Finally, molecular docking against anti-melanoma targets whose Ramachandran plots have been depicted to determine the stability of the target proteins, with PyMOL, AutoDock Suite and Discovery Studio Visualizer, is carried out. 2022 Elsevier B.V. -
Spirocyclic isatin-derivative analogues: Solvation, structural, electronic, topological, reactivity properties, and anti-leukaemic biological evaluation
The present work investigates, via computational methods, three spirocyclic isatin derivatives with ?-methylene-?-butyrolactone cores, whose synthesis, experimental data and structural-activity relationships have been reported, to compare their properties and biological action. DFT (Density Functional Theory) studies, including geometry optimisation, FMO Analysis, theoretical UV spectral analysis, NBO and NLO studies, are performed using Gaussian 09 W with a standard basis set. The IEFPCM model is employed to investigate the solvent effect on the reactivity and stability of the compounds. Topological analyses are also performed, including ELF, LOL, RDG and charge transfer studies. ADME profiling is performed using SwissADME online tool. Anti-leukaemic target proteins are selected and docked with the title compounds to understand their suitability to act against leukaemic conditions. 2023 Elsevier B.V. -
Solvent-solute polarity, electrophilic, steric effects, reactive sites, themodynamic quantities discussion and biological evaluation of lung cancer antiproliferative activities of spirobrassinin derivatives
The current study of spirobrassinin and its related compounds, 1-methoxyspirobrassinol and the 5-bromo analogue of methoxyspirobrassinin is performed to reveal a comparison among these molecules to understand which is the most reactive and bioactive. DFT (Density Functional Theory) studies comprising geometry optimisation (energy minimisation), FMO (Frontier Molecular Orbital) Analysis, theoretical UV analysis, NLO (Non-Linear Optics), NBO (Natural Bond Orbital) and thermodynamics studies are performed using Gaussian 09W. IEFPCM model is employed to investigate the solvent effect on the reactivity and stability of the title compounds. ADME profiles are generated using SwissADME, PreADMET and ADMETLab 2.0. Interesting lung cancer target proteins are docked with the title compounds is finally performed to obtain insight into the molecules' anticancer potential. 2023 Elsevier B.V. -
Structural and antibacterial assessment of two distinct dihydroxy biphenyls encapsulated with ?-cyclodextrin supramolecular complex
?-Cyclodextrin plays a vital role in biological application because it can enhance the stability and solubility of the guest molecules in the supramolecular inclusion complexes. Moreover, the ?-Cyclodextrin inclusion complex has control-releasing behavior and lower toxicity than bare guest molecules. To improve the solubility and stability properties of two structurally different fluorescent guest molecules, namely 2,2?-dihydroxy biphenyl and 3,3?-dihydroxy biphenyls, they involve the ?-Cyclodextrin inclusion complex process. Optical measurements clearly described the efficient binding through the changes in the absorbance and emission intensities of guest molecules in the presence of ?-Cyclodextrin. The Job's plot from absorbance measurements reveals the 1:1 stochiometric ratio of binding of guests and the ?-Cyclodextrin host. The FT-IR spectra of the solid complex show the characteristic stretching and bending vibrations from both the guests and the host molecule. The 1HNMR spectra of the inclusion complex promote downfield shifting of guest molecule protons upon binding with the ?-Cyclodextrin host. The solid complex prepared using the solution method exhibits superior antibacterial activity against both gram-positive and gram-negative bacteria compared to the kneading and physical mixing methods. 2024 -
One-Pot Synthesis of Silver Nanoparticles Derived from Aqueous Leaf Extract of Ageratum conyzoides and Their Biological Efficacy
The main objective of the present research work is to assess the biological properties of the aqueous plant extract (ACAE) synthesised silver nanoparticles from the herbal plant Ageratum conyzoides, and their biological applications. The silver nanoparticle syntheses from Ageratum conyzoides (Ac-AgNPs) were optimised with different parameters, such as pH (2, 4, 6, 8 and 10) and varied silver nitrate concentration (1 mM and 5 mM). Based on the UVvis spectroscopy analysis of the synthesised silver nanoparticles, the concentration of 5 mM with the pH at 8 was recorded as the peak reduction at 400 nm; and these conditions were optimized were used for further studies. The results of the FE-SEM analysis recorded the size ranges (~3090 nm), and irregular spherical and triangular shapes of the AC-AgNPs were captured. The characterization reports of the HR-TEM investigation of AC-AgNPs were also in line with the FE-SEM studies. The antibacterial efficacies of AC-AgNPs have revealed the maximum zone of inhibition against S. typhi to be within 20 mm. The in vitro antiplasmodial activity of AC-AgNPs is shown to have an effective antiplasmodial property (IC50:17.65 ?g/mL), whereas AgNO3 has shown a minimum level of IC50: value 68.03 ?g/mL, and the Ac-AE showed >100 ?g/mL at 24 h of parasitaemia suppression. The ?-amylase inhibitory properties of AC-AgNPs have revealed a maximum inhibition similar to the control Acarbose (IC50: 10.87 ?g/mL). The antioxidant activity of the AC-AgNPs have revealed a better property (87.86% 0.56, 85.95% 1.02 and 90.11 0.29%) when compared with the Ac-AE and standard in all the three different tests, such as DPPH, FRAP and H2O2 scavenging assay, respectively. The current research work might be a baseline for the future drug expansion process in the area of nano-drug design, and its applications also has a lot of economic viability and is a safer method in synthesising or producing silver nanoparticles. 2023 by the authors. -
Marine brown algae (Sargassum wightii) derived 9-hydroxyhexadecanoic acid: A promising inhibitor of ?-amylase and ?-glucosidase with mechanistic insights from molecular docking and its non-target toxicity analysis
Jeopardized glucose hemostasis leads to cronic metaboic disorder like Diabetes mellitus and it is predicted to occur in ?700 million people in the coming 20 years. Our study aims to isolate Palmitic acid (C16H32O3), 9-Hydroxyhexadecanoic acid metabolite from Sargassum wightii to inhibit alpha-amylase and alpha-glucosidase to reduce postprandial hyperglycemia and decline the risk of diabetes. High docking score of palmitic acid with both ?-amylase and ?-glucosidase is observed in in-silico molecular docking analysis, in comparison to commercially available drug acarbose. The three hydrogen bond in palmitic acid interacts with the important amino acids like Arg195, Lys200 and Asp300 in Glide XP docking mode for alpha-amylase. For ?-glucosidase, quantum-polarized ligand docking (QPLD) was used with similar three hydrogen bond interactions. Both docking studies showed significant binding interaction of palmitic acid with ?-amylase (?5.66 and ?5.14 (Kcal/mol)) and with ?-glucosidase (?4.52 and ?3.51(Kcal/mol)) with respect to the standard, acarbose docking score. The bioactive palmitic acid isolated from the brown alga, Sargassum wightii is already seen to inhibit digestive enzyme with non-target property in Artemia nauplii and zebra fish embryos. Further studies are required to investigate its role in in vivo antidiabetic effects due to its non-toxic and digestive enzyme inhibitory properties. It can be recommended in additional pharmaceutical studies to develop novel therapeutics to manage diabetes mellitus. 2023 SAAB -
Empowering Adolescent Emergent Readers in Government Schools: An Exploration of Multimodal Texts as Pathways to Comprehension
This exploratory study, which was part of a larger investigation into multimodality, looked at the comprehension levels of 62 Grade 8 students from two government schools who were identified as emerging readers out of a group of 118 students. Through observations and interactions with teachers and students, the potential for multimodal texts to enhance comprehension was highlighted. The study specifically compared the effectiveness of a digital comic (Text A) and an audio-visual text (Text B) in enabling comprehension among these emergent readers. Participants were instructed to narrate the content and share their interpretations of these texts, with their responses recorded and analyzed. Feedback revealed a marked preference for Text B among 45 of the 62 emergent readers assessed. Employing theoretical frameworks related to comprehension, language production, multimodality, and task structure, this research concentrated on the subset of 45 students who favored Text B. The findings underscore the importance of aligning instructional materials with students preferred learning modalities, suggesting that such alignment enhances comprehension. The study proposes a refined approach to literacy education policy, advocating for the inclusion of diverse modalities to better meet the varied learning needs of students. 2024 Association of Literacy Educators and Researchers. -
Lexical Richness of Adolescents Across Multimodalities: Measures, Issues and Future Directions
Lexical Richness (LR) is a scarcely researched subject in India. The objective of this paper is twofold: (i) To statistically inquire whether LR varies across three multimodalities: visual-only, audio-only, and audio-visual; and (ii) To see which of the two measures of LR (MATTR and Guiraud) is independent of text length and is best suited for short oral productions. 270 students across three types of schools were examined, out of whom 100 willingly completed all three oral tasks. The students were asked to retell the stories transacted in each modality in their own words. Randomization of sampling is done to mitigate the confounding modality bias. Additionally, the genre and parts of the storyline in each modality are similar. The students oral speech samples were recorded, transcribed and analyzed on WordCruncher and TextElixir software. The results revealed that there is statistically significant variance among the modalities. Furthermore, the Moving Average Type Token Ratio (MATTR) is seen to be independent of text length compared to Index of Guiraud. This study also throws light on the observations made during the study, pertinent issues in the field of education, and future directions for research on LR. 2023 IUP. All Rights Reserved. -
Exploring Socio-Variational Patterns in Indian Adolescents Lexical Diversity: Insights for Education
Following the COVID-19 pandemic, vast data emerged regarding the plummeting literacy and readability levels among Indian adolescents, posing a challenge to address in its present condition of a vastly heterogeneous socio-demographic environment. This study is grounded in Bourdieu and Passeron's (1977) theory, which acknowledges schools as places with societal relevance that perpetuate social inequality. This implies the need to formulate robust policies to address educational inequalities. To this extent, the researchers used an exploratory design to evaluate lexical diversity by purposively sampling 100 volunteer teenagers across three schools. In addition to the data received from school officials, survey questionnaires collected socio-economic information (age, gender, area of stay, socio-economic scale [SES], and school type). The authors used the Kuppuswamy SES scale (2022) to determine socio-economic scale measures, as well as the calculation of Lexical Diversity scores through the computational open-source software TextElixir. The findings reveal that age and gender do not affect lexical diversity. However, school type, SES, and area of stay significantly affect adolescents from the lower social class, who need targeted interventions to bridge gaps of educational inequity. This study addresses the limitations of previous correlational studies by offering educational insights to ensure educational equity amidst prevalent social class inequalities. Authors.