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A Simple and Efficient Ligand-Free Copper-Catalyzed C-N Bond Formation of Aryl (Hetero) Halides and N-Heteroaryl Amines
In this protocol, we report a simple, inexpensive, and user-friendly conventional method for C-N cross coupling between aryl/heteroaryl halides and hetero aryl amines using copper iodide as a catalyst in DMSO as a solvent to prepare pyrimidines and pyrazines derivatives. The reaction conditions were optimized by screening in various copper catalysts and bases. The substrate scope of the reaction was also carried out to prepare novel functionalized N-arylated compounds in good yields. 2021 Taylor & Francis Group, LLC. -
A simple and efficient synthesis of imidazoquinoxalines and spiroquinoxalinones via pictect-spengler reaction using Wang resin
An efficient approach for the synthesis of various imidazoquinoxalines and spiroquinoxalinones has been reported from 2-(1H-imidazol-1-yl) aniline and different aldehydes using Wang-OSO3H as a reusable catalyst to get in good yields. The reaction condition has been optimized by screening in various solvents and a gram scale experiment has also demonstrated. Further, the substrate scope of the reaction has also been well demonstrated. 2021 Taylor & Francis Group, LLC. -
A simple software for swift computation of photon and charged particle interaction parameters: PAGEX
PAGEX is a compact and user-friendly cross-platform software developed for swift computation of photon (X-ray and ?-ray) and charged particle interaction parameters for various applications. It is designed based on well-established theoretical formulations and computational techniques integrating various Python packages to effectively calculate parameters such as partial/total photon interaction cross-sections and mass attenuation coefficients, charged particle mass stopping powers and cross-sections, effective atomic number and electron density, mass-energy absorption coefficient, KERMA and build-up factors over a wide energy range. This tool is capable of generating both tabular and graphical outputs which can be saved in any user desired format. PAGEX has been verified against other widely employed software and databases, demonstrating good agreement. This software which facilitates robust computation is freely available from the authors. 2021 Elsevier Ltd -
A simulation model to estimate the amount of waste collected in a common bin after compulsory segregation /
Mathematics Applied In Science And Technology, Vol.7, Issue 1, pp.314-318, ISSN No: 0973-6344. -
A site-isolated Lewis acidic aluminium and Brsted basic amine sites in the dimeric silsesquioxane cage as a reusable homogeneous bifunctional catalyst for one-pot tandem deacetalization/deketalization-Knoevenagel condensation reactions
The development of multifunctional catalysts for one-pot tandem reactions is significantly required to attain multiple sequential transformations in a single reactor, which would considerably decrease the number of manipulations demanded for chemical manufacturing in industries. Herein, dimeric silsesquioxane Al-POSS-NH2 (2), a homogenous bifunctional acid-base catalyst containing environmentally friendly robust silica and high chemical and thermal stabilities, permanent catalytic activity, and reusability, was synthesized by the reaction of trisilanol aminopropyl hexaisobutyl-POSS (1) with trimethylaluminium. Al-POSS-NH2 was successfully used as a bifunctional catalyst for one-pot tandem reactions because of the synergism and effective compartmentalization between Lewis acidic aluminium and Brsted basic amine sites (>10.0 in the dimeric silsesquioxane cage, which was confirmed by DFT and QTAIM studies. Subsequently, different acetals were tested to obtain their corresponding benzylidene malononitrile derivatives using Al-POSS-NH2 for the one-pot tandem deacetalization-Knoevenagel condensation reactions and showed high efficiency (>90%) under optimized conditions (DMF, 0.3 mol% catalyst loading and 80 C) with different reaction times. Furthermore, the bifunctional Al-POSS-NH2 catalyst was separated from the reaction mixture via the precipitation method by adding acetonitrile into the reaction mixture and reusing it for five consecutive cycles without losing activity considerably, thus providing the inherent advantage over traditional homogeneous catalysts. In a one-pot tandem deketalization-Knoevenagel condensation reaction for various ketals, the reaction condition was slightly modified by increasing the catalyst loading (0.6 mol%) and reaction time (16 to 24 hours) to acquire better conversion and yield of their desired products. Finally, the present study suggests that the bifunctional POSS might facilitate the rapid development of environmentally friendly and economically feasible catalysts for multistep reactions. 2023 The Royal Society of Chemistry. -
A Smartphone Coupled Freshness Indicator Prepared by Rub-coating of Hibiscus Flowers on Paper substrates for Visual Monitoring of the Spoilage of Milk
This study developed an inexpensive and easy-to-use milk freshness indicator (H-Paper) by rub-coating hibiscus flowers onto paper. As per the best of our knowledge, this is the first example of a food quality indicator prepared by direct hand-rubbing of a natural halochromic material onto paper substrates. Unlike the previously reported colorimetric indicators from natural sources, our indicator does not require the extraction of anthocyanins from the natural product. The H-Paper undergoes a quantifiable color change from green to purple to pink corresponding to fresh, spoiling, and spoiled milk samples. Digital photographs of H-Paper treated with milk samples were acquired using a smartphone, and RGB indices were analyzed using a free application. The red chromatic shift was used as a parameter to quantify color change of H-Paper to follow the spoilage of milk. Anthocyanins present in the hibiscus flowers are responsible for this colorimetric response. This work demonstrates a proof-of-concept for directly rub-coating halochromic materials onto a substrate to fabricate food freshness indicators. The H-Paper indicator has advantages of naked-eye analysis, consumer-friendliness, and instrument-free operation. This requires neither any laboratory accessories nor the expertise of a trained analyst for its preparation and operation, which is appropriate for use in resource-limited settings. 2022 Wiley-VCH GmbH. -
A social psychological investigation of Anti-nationalism in contemporary India A media analysis
The paper aims to explore the consensual and dissident social representations of anti-national that has re-entered the media lexicon in India post an alleged anti-national student protest in Jawaharlal Nehru University in the capital city of Delhi, India on February 9, 2016. The Social Representation Theory (SRT) is used to analyze the selected media reports of six daily newspapers, three each in English and Hindi language for a period of one year subsequent to the event. Results of thematic anchoring and anchoring by antinomy, a methodology used by Birgitta Hjer, are reported. The results reveal how the intergroup tensions and ideological differences in the polity constitute the conflicting social thinking on the referent. The paper has global implication for opening the possibilities of negotiation and transformation of social meanings related to nationalism and anti-nationalism. The Author(s) 2025. -
A space for the space theorist remembering henri lefebvre
Despite being somewhat ignored in Indian academia, Henri Lefebvre comes to our rescue every time, helping us understand and respond to spacetime challenges. 2020 Economic and Political Weekly. All rights reserved. -
A stakeholder theory approach to analysing strategies for improving pandemic vaccine supply chain performance
This study aims to formulate strategies that impact the vaccine supply chain (VSC). This study measures the VSC performance using the proposed strategy concerning stakeholders theory. From the literature review and experts consent, the strategies are classified into six broad strategies as-VSC traceability, VSC visibility, VSC velocity, digitalising VSC, localising VSC, and vaccine inventory. A questionnaire is developed for surveying healthcare organisations and hospitals. All six proposed hypotheses got accepted. The developed model satisfies all the model fit parameters. Strategies like VSC traceability, VSC visibility, VSC velocity, digitalising VSC, localising VSC, and vaccine inventory have positively impacted vaccine supply chain performance. This research will be helpful for healthcare professionals and organisations for the faster delivery of the vaccine. This research will also help policymakers in improving the performance of VSC. This study is also the first to use the stakeholder theory approach for measuring VSC performance. Copyright 2024 Inderscience Enterprises Ltd. -
A Statistical Analysis and Comparison of the spread of Swine Flu and COVID-19 in India
Introduction: The world is currently experiencing the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) [COVID-19], however, this is not a new phenomenon; it occurred in 2009-2010 in the form of novel influenza A. (H1N1). The H1N1 virus primarily afflicted people between the ages of 26 and 50, but SARS-CoV-2 primarily afflicted those over the age of 60, increasing the number of deaths owing to their weakened immunity. The report provides a case study of the impact of H1N1 and SARS-CoV-2 in India. Methods: Data is obtained from The Hindustan Times newspaper, GoI press releases and World Health Organization (WHO) reports. Results: The incidence rate was initially low and it was only by the 10-15th week that it started increasing. There is an initial upward trend before levelling out followed by a second wave and third wave. COVID-19 exhibited a steeper growth, where the steps taken by the Government were ineffective leading to higher death cases. Kerala was affected due to the travellers returning from the Middle East, while Maharashtra and Delhi saw large incidence rates due to the migrant influx and communal gathering. Conclusion: The most effective and practical approach is to test the symptomatic patients and aggressive testing to contain the transmission. Awareness campaigns to educate the public about social distancing and personal hygiene is more practical. There is still scope of improvement with regards to the public health care support, preparedness and response. Lockdown measures could have been avoided if the initial screening was conducted properly. 2022 UPM Press. All rights reserved. -
A statistical analysis of the stochastic drift between sensex & nifty - An in-depth study /
International Journal Of Innovative Research & Development, Vol.4, Issue 5, pp.208-212, ISSN No: 2278-0211 (Online) -
A statistical approach to study anatomical changes of pink guava cultivar (Psidium guajava L. cv Arka Kiran) during its ripening at the room temperature storage
The ripening of climacteric fruit like guava is a complex process that is highly coordinated with its cellular backbone. In the present study, we combined microscopy, spectrophotometry, and statistical analysis to evaluate the anatomical changes in the pink variety of guava during five ripening stages (pre-ripe, ripe, color-turn, half over-ripe, and over-ripe) during its storage at room temperature (282 C). The cholorophyll content of the peel, as determined by the measurement of chlorophyll a, b, and total chlorophyll, showed a significant decrease during the maturation process (4.05, 4.53, and 8.62 ?g/cm2, respectively, in the pre-ripe stage to not detectable in the over-ripe stage). Gradual loss of integrity of the fruit pulp (pericarp) from the preserved bee-hive structure to cell mass was also monitored by studying the cellular anatomy with brightfield and scanning electron microscopy. The epidermal thickness and width of the cortical parenchyma cells revealed statistical differences from the initial pre-ripe stage to the final full-ripe stage. Finally, based on the cellular dimensions, multivariate analysis using PCA (Principal Component Analysis) tool grouped the stages into three clusters, namely, pre-ripe: ripe, color-turn: half-over ripe, and over-ripe stages. In conclusion, this study provided significant insights into cultivar-specific anatomical changes in guava fruit, with potential for future research to develop variants with longer post-harvest storage life. 2024 The Author(s) -
A Statistical Search for Star-Planet Interaction in the Ultraviolet Using GALEX
Most (?82%) of the over 4000 confirmed exoplanets known today orbit very close to their host stars, within 0.5 au. Planets at such small orbital distances can result in significant interactions with their host stars, which can induce increased activity levels in them. In this work, we have searched for statistical evidence for star-planet interactions in the ultraviolet (UV) using the largest sample of 1355 Galaxy Evolution Explorer (GALEX) detected host stars with confirmed exoplanets and making use of the improved host-star parameters from Gaia DR2. From our analysis, we do not find any significant correlation between the UV activity of the host stars and their planetary properties. We further compared the UV properties of planet host stars to that of chromospherically active stars from the RAdial Velocity Experiment (RAVE) survey. Our results indicate that the enhancement in chromospheric activity of host stars due to star-planet interactions may not be significant enough to reflect in their near- and far-UV broadband flux. 2020. The American Astronomical Society. All rights reserved.. -
A Stochastic Method for Optimizing Portfolios Using a Combined Monte Carlo and Markowitz Model: Approach on Python
The main of the study is to comprehend how the mean variance efficient frontier method may be used in conjunction with Markowitz portfolio theory to produce an optimal portfolio. The study uses daily observations 8 pharma companies closing price namely Auropharma, Granules, Glaxo, Lauruslabs, Pfizer, Sanofi and Torntpharma. Further, Nifty pharma index is considered as benchmark index to check the performance of the chosen companies. The study chosen the reference period from 2020 to 2023 and required data has been extracted from the National Stock Exchange (NSE). This research is based on implementing a stochastic method for efficient portfolio optimisation employing a blended Monte Carlo and Markowitz model. In order to forecast the price of these indices in the future and to determine the likelihood of profit or loss while investing in a portfolio of stocks representing the aforementioned indices, the study also uses Monte Carlo simulation. The study involves two algorithms, namely the deterministic optimisation algorithm, which uses Markowitz Portfolio Theory, and the probabilistic optimisation algorithm, which uses Monte Carlo simulation. The study employed correlation matrix to find the exist relationship between the chosen companies and benchmark index. Also, expected return and volatility has been identified with the help of standard deviation using Python. The study found that the NIFTY Pharma index offers a higher return of 14.35. In addition to this, NIFTY Pharma portfolio's volatility is considerably higher. The study concludes that the NIFTY pharma portfolio is more suitable for those investors who have an appetite for risk. 2024 R. Mallieswari et al., published by Sciendo. -
A Stochastic Method for Optimizing Portfolios Using a Combined Monte Carlo and Markowitz Model: Approach on Python
The main of the study is to comprehend how the mean variance efficient frontier method may be used in conjunction with Markowitz portfolio theory to produce an optimal portfolio. The study uses daily observations 8 pharma companies closing price namely Auropharma, Granules, Glaxo, Lauruslabs, Pfizer, Sanofi and Torntpharma. Further, Nifty pharma index is considered as benchmark index to check the performance of the chosen companies. The study chosen the reference period from 2020 to 2023 and required data has been extracted from the National Stock Exchange (NSE). This research is based on implementing a stochastic method for efficient portfolio optimisation employing a blended Monte Carlo and Markowitz model. In order to forecast the price of these indices in the future and to determine the likelihood of profit or loss while investing in a portfolio of stocks representing the aforementioned indices, the study also uses Monte Carlo simulation. The study involves two algorithms, namely the deterministic optimisation algorithm, which uses Markowitz Portfolio Theory, and the probabilistic optimisation algorithm, which uses Monte Carlo simulation. The study employed correlation matrix to find the exist relationship between the chosen companies and benchmark index. Also, expected return and volatility has been identified with the help of standard deviation using Python. The study found that the NIFTY Pharma index offers a higher return of 14.35. In addition to this, NIFTY Pharma portfolio's volatility is considerably higher. The study concludes that the NIFTY pharma portfolio is more suitable for those investors who have an appetite for risk. 2024 R. Mallieswari et al., published by Sciendo 2024. -
A stochastic propagation model to the energy dependent rapid temporal behaviour of Cygnus X-1 as observed by AstroSat in the hard state
We report the results from analysis of six observations of Cygnus X-1 by Large Area X-ray Proportional Counter (LAXPC) and Soft X-ray Telescope (SXT) onboard AstroSat, when the source was in the hard spectral state as revealed by the broad-band spectra. The spectra obtained from all the observations can be described by a single-temperature Comptonizing region with disc and reflection components. The event mode data from LAXPC provides unprecedented energy dependent fractional root mean square (rms) and time-lag at different frequencies which we fit with empirical functions.We invoke a fluctuation propagation model for a simple geometry of a truncated disc with a hot inner region. Unlike other propagation models, the hard X-ray emission (>4 keV) is assumed to be from the hot inner disc by a single-temperature thermal Comptonization process. The fluctuations first cause a variation in the temperature of the truncated disc and then the temperature of the inner disc after a frequency dependent time delay.We find that the model can explain the energy dependent rms and time-lag at different frequencies. 2019 The Author(s) Published by Oxford University Press on behalf of the Royal Astronomical Society. -
A strategic evaluation on competency of Karanataka destinations through destination management organizations /
American Journal Of Industrial and Business Management, Vol.6, pp.102-108, ISSN: 2164-5175. -
A Strategic Review on Use of Polyhydroxyalkanoates as an Immunostimulant in Aquaculture
Background and Objective: Increasing concerns over the use of antibiotics in aquaculture have emerged researchers to focus on short chain fatty acids and other biocompatible molecules as alternatives for disease prophylaxis and treatment. Polyhydroxyalkanoates well studied as biopolymeric materials for using in packaging and biomedicine were not focused much for their abilities to act as antimicrobial agents in aquaculture until recent years. Application studies of polyhydroxyalkanoates as aquafeed additives have highlighted their promising roles as ecofriendly alternatives for commercial antibiotics with strong immunomodulatory effects in fish-es and shrimps. The major aim of this review was to explore up-to-date scientific research studies on use of polyhydroxyalkanoates as aquafeed additives and their immunomodulatory effects. Results and Conclusion: Up-to-date, limited scientific literatures have been published on the use of polyhydroxyalkanoates and their copolymers as alternatives to antibiotics in aquaculture. This research field includes a great scope of development due to the promising immu-nomodulatory and antimicrobial activity of polyhydroxyalkanoates against common pathogens in aquaculture, as reported in literatures. Although several hypothesis and research data for explaining the mechanisms behind their immunostimulatory effects were suggested by various researchers, genetic and molecular bases underlying these phenomena are yet to be explored. Further research and development in this area can introduce these biopolymers as the most promising eco-friendly alternatives for antibiotics in aquaculture. Conflict of interest: The authors declare no conflict of interest. 2021. All Rights Reserved. -
A strong technique for solving the fractional model of multi-dimensional Schnakenberg reaction-diffusion system
In recent times, researchers have increasingly directed their focus toward Reaction-Diffusion models, attracted by their versatile applications across various scientific domains. Within these models, the Schnakenberg Reaction-Diffusion System (SRDS) has gained significant attention for its ability to explain intricate phenomena such as oscillatory behavior, limit cycles, pattern formations and diffusion in biochemistry. This paper specifically delves into the Fractional Schnakenberg Reaction Diffusion System (FSRDS), an extension of SRDS that incorporates principles of fractional calculus. This extension provides a more comprehensive framework for understanding complex dynamics. The unique aspect of this work lies in the innovative approach used to derive an analytical solution for FSRDS - the Residual Power Series Method with Laplace Transform (L.T.)/Laplace Residual Power series Method (LRPSM). By employing LRPSM and considering the provided initial conditions, our objective is to unveil an analytical solution for FSRDS. 2025 World Scientific Publishing Company. -
A structural approach towards reinvigorating student satisfaction in industrial training institutes a contemplating outlook
The research paper focused to conceptualize and empirically test the conceptual model of student satisfaction proposed for Indian vocational education and training (VET), precisely industrial training institutes (ITIs). Even though the upgradation of ITIs through public-private partnership (PPP) is emphasized from the previous decade, little empirical evidence exists about the quality of the institutes. Improved quality in ITIs helps in increased employability of the students and would help in meeting Indias projected skill demand of 191 million youths by 2022. Empirical data were collected from upgraded ITIs of Andhra Pradesh and Telangana states to assess student satisfaction. Student satisfaction gives the measure of student feedback on the quality of the courses. PLS-SEM was applied to develop measurement and structural models. Subsequently, statistical values were used to estimate the validity and reliability of the models. Besides, the predictive accuracy of the model was also tested. The data analysis assisted to ascertain whether to accept or reject the hypothesized relations proposed based on the conceptual model. The results proved that institute quality factors were positively correlated with student satisfaction. Eventually, it was observed that industry exposure was a significant determinant of student satisfaction followed by training facilities & equipment, trainer credibility, learning environment, and placement and counseling services. Above all being said, it can be posited that focusing on the above all quality factors would help in enhancing the quality of ITIs. 2021, Associated Management Consultants Pvt. Ltd.. All rights reserved.