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An improved web caching system with locally normalized user intervals
Caching is one of the most promising areas in the field of future internet architecture like Information-centric Networking, Software Defined Networking, and IoT. In Web caching, most of the web content is readily available across the network, even if the webserver is not reachable. Several existing traditional caching methods and cache replacement strategies are evaluated based on the metrics like hit ratio and byte hit Ratio. However, these metrics have not been improved over the period because of the traditional caching policies. So, in this paper, we have used an intelligent function like locally normalized intervals of page visit, website duration, users' interest between user groups is proposed. These intervals are combined with multiple distance metrics like Manhattan, squared Euclidean, and 3-,4-,5-norm Minkowski. In order to obtain significant common user navigation patterns, the clustering relation between the users using different intervals and distances is thoroughly analyzed. These patterns are successfully coupled with greedy web cache replacement strategies to improve the efficiency of the proposed web cache system. Particularly for improving the caching metrics more, we used an AI-based intelligent approach like Random Forest classifier to boost the prefetch buffer performance and achieves the maximum hit rate of 0.89, 0.90, and byte hit rate of 0.87, 0.89 for Greedy Dual Size Frequency and Weighted Greedy Dual Size Frequency algorithms, respectively. Our experiments show good hit/byte hit rates than the frequently used algorithms like least recently used and least frequently used. 2013 IEEE. -
Organization is an Incubator to Develop Intrapreneurship
Global Journal of Arts and Management, Vol. 2, No.3, pp 216-218, ISSN No. 2249-2658 -
An Understanding of Knowledge Management Perception and Implementation in Higher Education
Global Journal of Arts and Management, Vol. 2, No.3, pp 204-206, ISSN No. 2249-2658 -
Effects of Processing Parameters on Microstructure Evolution of Al-7Si-Mg Alloy by Cooling Slope Casting
This work investigates the effects of pouring temperature, slope length, and slope temperature in cooling slope casting on the formation of globular microstructure of Al-7Si-Mg alloy. The remnant alloy on the slope during casting was quenched and characterized at different stages of flow to evaluate the microstructure features developed in cooling slope casting. The primary ?-Al dendritic phase found in conventional cast alloy was transformed into globular shape in slope-processed cast alloy. Finer and more homogenous primary ?-Al phase was formed at lower pouring temperature (625C). The effect of slope length on microstructure of Al-7Si-Mg alloy was significant at high pouring temperatures (640 and 660C) but was not visible at low pouring temperature (625C). The microstructure of alloy became coarser with increasing slope temperature. 2015, ASM International. -
Polymer Nanocomposite Graphene Quantum Dots for High-Efficiency Ultraviolet Photodetector
Influence on photocurrent sensitivity of hydrothermally synthesized electrochemically active graphene quantum dots on conjugated polymer utilized for a novel single-layer device has been performed. Fabrications of high-performance ultraviolet photodetector by depositing the polypyrrole-graphene quantum dots (PPy-GQDs) active layer of the ITO electrode were exposed to an Ultraviolet (UV) source with 265 and 355 nm wavelengths for about 200 s, and we examined the time-dependent photoresponse. The excellent performance of GQDs was exploited as a light absorber, acting as an electron donor to improve the carrier concentration. PGC4 exhibits high photoresponsivity up to the 2.33 A/W at 6 V bias and the photocurrent changes from 2.9 to 18 A. The electrochemical measurement was studied using an electrochemical workstation. The cyclic voltammetry (CV) results show that the hysteresis loop is optically tunable with a UV light source with 265 and 355 nm at 0.1 to 0.5 V/s. The photocurrent response in PPy-GQDs devices may be applicable to optoelectronics devices. 2022 by the authors. -
Getting Back to Work: Cognitive-Communicative Predictors for Work Re-entry Following Traumatic Brain Injury
Return to work following a Traumatic Brain Injury (TBI) is affected by deficits across the cognitive, psycho-social and physical domains. The specific role of cognitive -communicative abilities influencing work re-entry is understudied. This study aimed at identifying the cognitive-communicative predictors for work re-entry following TBI. Thirty patients with TBI employed pre morbidly were categorized into two groups- 14 employed and 16 unemployed post TBI. Those having sustained mild, moderate or severe head injury and in the post injury period of 648months were recruited and majority belonged to skilled/ professional type of premorbid occupational status. They underwent a detailed assessment of cognition, language and communication using NIMHANS Neuropsychology Battery, Indian adapted versions of Western Aphasia Battery and La Trobe Communication Questionnaire (LCQ) respectively. Patients employed post TBI had better Aphasia Quotient (AQ) and better performance on all the cognitive domains and few domains of LCQ than those who remained unemployed. On step-wise Discriminant Function Analysis (DFA), injury severity and AQ could significantly differentiate between the two groups with an overall accuracy of 80%. Severity of head injury is a significant predictor for employability post TBI and evaluation of language along with cognitive abilities is crucial for patients with TBI for work re-entry. The study highlights the importance of a multi-disciplinary team in the assessment and management of cognitive-communication impairments following a TBI. 2022, The Author(s), under exclusive licence to Springer Nature India Private Limited. -
An Efficient Deep Learning Model Using Harris-Hawk Optimizer for Prognostication of Mental Health Disorders
Mental health disorders are primarily life style driven disorders, which are mostly unidentifiable by clinical or direct observations, but act as a silent killer for the impacted individuals. Using machine learning (ML), the prediction of mental ailments has taken significant interest in medical informatics community especially when clinical indicators are not there. But, majority studies now focus on usual machine learning methods used to predict mental disorders with few organized health data, this may give wrong signals. To overcome the drawbacks of the conventional ML prediction models, this work presents Deep Learning (DL) trained prediction model for automated feature extraction to realistically predict mental health disorders from the online textual posts of individuals indi cating suicidal and depressive contents. The proposed model encompasses three phases named pre-processing, feature extraction and optimal prediction phase. The developed model utilizes a novel Sparse Auto-Encoder based Optimal Bi-LSTM (SAE-O-Bi-LSTM) model, which integrates Bi-LSTM and Adaptive Harris-Hawk Optimizer (AHHO) for extracting the most relevant mental illness indicating features from the textual content in the dataset. The dataset utilized for training consist of 232074 unique posts from the "SuicideWatch" and "Depression" subreddits of the Reddit platform during December 2009 to Jan 2021 downloaded from Kaggle. In-depth comparative analysis of the testing results is conducted using accuracy, precisions, F1 score, specificity, and Recall and ROC curve. The results depict considerable improvement for our developed approach with an accuracy of 98.8% and precision of 98.7% respectively, which supports the efficacy of our proposed model. The Author(s) 2024. -
Physical ageing in Se-Te-Sb glasses
Bulk Se60-xTe40Sbx glasses in the composition range 0?x?14 were prepared by the melt quenching method. Differential Scanning Calorimetric (DSC) and thermal crystallization studies were performed to understand the thermodynamic property like glass transition and structural transformations. These glasses exhibit sharp endothermic peak at the glass transition (Tg). Disappearance of the endothermic peak at Tg in the rejuvenated samples clearly indicates the ageing effect in these glasses. Addition of Sb to Se-Te increases the connectivity of the structural network which is evidenced from the increase in Tg. A distinct change in the slope of the Tg at x=6, indicates a major change in the way the network is connected. The glass forming ability and the thermal stability also exhibit a maximum at x=6. Tg increases with the ageing time and the corresponding fictive temperature (Tf) calculated from the specific heat curves shows a decreasing trend. The molecular movements along the polymeric Se chains might cause the structural relaxation and the physical ageing. The physical ageing effect has been understood on the basis of the Bond Free Solid Angle (BFSA) model proposed by Kastner. Thermally crystallized samples show the formation of rhombohedral Sb2Te 3, rhombohedral Sb2Se3 and hexagonal Te phases. 2013 Elsevier Ltd. -
The usage of gold and the investment analysis based on gold rate in India
Gold is one of the main commodities where the customers invest their money comparatively with bank for better interest. In the Indian context people purchase gold for their children's marriages for later period. The investment in gold is better suits for easy conversion into money with quickest possible time from the bank and gold merchants. The appreciation or depreciation of gold based on other investment options like fixed deposit, provident fund, international crude oil price, stock market, mutual fund etc. The comparative analysis of gold with other investment options give an edge to the customer to clearly understand the investment pattern for their hard-earned money expected to give good returns in the future. Copyright 2019 Institute of Advanced Engineering and Science. All rights reserved. -
Electrocatalytic oxidation and determination of morin at a poly(2,5-dimercapto-1,3,4-thiadiazole) modified carbon fiber paper electrode
Voltammetric determination of morin on carbon fiber paper (CFP) electrode modified by electropolymerization of 2,5-dimercapto- 1,3,4-thiadiazole (DMTD) in phosphate buffer solution (PB, pH 9.0) have been studied. This modified electrode showed strong electrocatalytic activity toward the oxidation of morin, a flavonoid at physiological pH (PB, pH 7.0). Morin gave a sensitive anodic peak at 0.245 V (vs. SCE). The parameters influencing the anodic peak of morin such as effect of pH, effect of scan rate and concentration have been optimized. The electrochemical process was found to be irreversible and adsorption-controlled. Under the optimum conditions, the anodic peak current was linear to concentration of morin in the range of 2.5 10-10-2.75 109 M and detection limit was found to be 8.3 10-11 M. The practical application of the modified electrode was successfully demonstrated for the determination of morin in mulberry leaves. 2016 The Electrochemical Society. All rights reserved. -
Tailoring a Multifunctional PEDOT/Co3O4-CeO2 Composite for Sustainable Energy Applications
Energy sources play a crucial role in the development of the society. The gargantuan depletion of fossil fuels creates new glitches in the routine activities of human beings. Electrocatalysts can efficiently produce and store energy and, therefore, have the potential to alleviate this situation. A multifunctional electrocatalyst, Poly (3,4-ethylenedioxythiophene)/cobalt oxide-cerium oxide(PEDOT/Co3O4-CeO2), is synthesized by incorporating mixed metal oxide to 3,4-ethylenedioxythiophene (EDOT) using the in situ chemical oxidative polymerization method and is employed for both energy production and storage applications. The successful synthesis of the catalyst is confirmed through various characterization techniques. The composite shows a specific capacity of 617.8Cg?1 and a specific capacitance value of 1298.1Fg?1. The hydrogen evolution reaction (HER) analysis shows that the composite requires a low overpotential of 163.1mV at a current density of 10mAcm?2. Synthesized electrocatalysts can effectively handle the energy related issues prevailing in the society. 2024 Wiley-VCH GmbH. -
Rational design of PANI incorporated PEG capped CuO/TiO2 for electrocatalytic hydrogen evolution and supercapattery applications
Synthesis of efficient electrocatalysts for energy applications is a major area scientists are currently focusing on to address the twin challenges of energy shortfall and the production of clean energy. Herein, an efficient electrocatalyst, polyaniline incorporated with polyethylene glycol capped CuO/TiO2 is prepared, which is effective in hydrogen evolution reactions and energy storage applications. The characterizations like XPS, XRD, FT-IR, FE-SEM, HR-TEM, and BET have been carried out to confirm the successful formation of the synthesized PANI/CuO/TiO2 composite. At 10 mA/cm2 current density, the prepared composite exhibits a lesser overpotential of 536 mV and 1587.2 C/g at 1 A/g as the specific capacity. The electrode prepared using the PANI/CuO/TiO2 composite also shows cyclic stability up to 2000 cycles. The synthesized composite is an efficient electrocatalyst for energy related applications. 2023 Hydrogen Energy Publications LLC -
Molecular architecture of PANI/V2O5/MnO2 composite designed for hydrogen evolution reaction
An ever increasing demand for energy has mandated scientists towards exploring innovative and environmentally friendly energy production techniques that can meet the needs of human beings and the world at large. Among the various techniques, hydrogen evolution reaction (HER) is a cost-effective and efficient method that produces hydrogen, a better fuel, for meeting our energy requirements. The large surface area, good redox capacity, high electroactivity, and tunable bandgap of polyaniline (PANI) makes it a preferred candidate for various energy-related applications. Incorporating mixed metal oxides into a polymer enhances its catalytic activities and can be used as an electrocatalyst for HER. In situ chemical oxidative polymerization method has been carried out to synthesize PANI/V2O5/MnO2 composite. The characterization studies of PANI/V2O5/MnO2 composite are done using XRD, FT-IR, BET, XPS, and FE-SEM analysis. The PANI/V2O5/MnO2 composite is used for linear sweep voltammetry studies and shows that it acts as an efficient electrocatalyst which gives an overpotential of 130 mV at 10 mA/cm2. The high electrocatalytic activity of the composite is due to the better surface phenomenon that is enhanced by the high porosity and surface area. The electrochemical impedance spectroscopy also shows lower charge transfer resistance for the PANI/V2O5/MnO2, confirming its excellent electroactivity. 90% of the current density is retained even after 7200 seconds, validating its stability. 2023 Elsevier B.V. -
Simultaneous first order derivative spectrophotometric determination of vanadium and zirconium in alloy steels and minerals
A simple, selective and sensitive spectrophotometric method has been developed for the individual and simultaneous determination of trace amounts of vanadium(V) and zirconium(IV) in acetic acid medium using a newly synthesised reagent diacetylmonoxime salicyloylhydrazone (DMSH), without any prior separation. The molar absorptivity and Sandell's sensitivity of the coloured species are 1.30 x 10 4 and 1.82 x 10 4 Lmol -1cm -1 and 3.9 and 2.5 ng cm -2 for V(V) and Zr(IV), respectively. Beer's law is obeyed between 0.26-2.80 and 0.30-3.20 ?g mL -1 concentration of vanadium (V) and zirconium (IV) at 405 and 380 nm respectively. The stoichiometry of the complex was found to be 1:1 (metal:ligand) for V(V) and 1:2 for Zr(IV) complexes. These metal ions interfere with the determination of each other in zero order spectrophotometry. The first derivative spectra of these complexes permitted a simultaneous determination of V(V) and Zr(IV) at zero crossing wavelengths of 445 nm and 405 nm, respectively. The optimum conditions for maximum colour development and other analytical parameters were evaluated. The proposed method has been successfully applied for the determination of zirconium and vanadium in standard alloy steel samples, mineral and soil samples. 2012 Elsevier B.V. All rights reserved. -
Adsorptive removal studies of Rhodamine B by PEG capped polyaniline/TiO2/CuO composite
The availability of pure and fresh water is the prime need of human beings for survival. The fact that the rate of water pollution is alarmingly increasing is making scientists think of ways to minimize the pollution effects. Among the numerous techniques, adsorption is the most cost-effective and easy method for removing pollutants from water bodies. In this study, a ternary PEG capped polyaniline/TiO2/CuO composite with excellent surface area is synthesized, and its adsorption studies carried out using Rhodamine B, one of the strongest organic pollutants. The characterization studies of the prepared composites have been done using XRD, FT-IR, HR-TEM, DLS, zeta potential, BET, and XPS analyses. Isotherm, kinetics, and thermodynamic studies of adsorption have been done for the prepared composite to evaluate its adsorptive efficiency. The adsorption studies of RhB dye using the synthesized composite followed the Langmuir adsorption isotherm. The kinetics study for the adsorption process indicates that pseudo second order kinetics fits best with the adsorption process taking place on the PANI/TiO2/CuO composite. The thermodynamic studies reveal the spontaneity of the process and the exothermic behavior at lower temperatures. The results prove the efficiency of the synthesized adsorbent towards environmental remediation studies. 2023 Elsevier Ltd -
Highly selective derivative spectrophotometric determination of palladium(II) in hydrogenation catalysts and alloy samples
A simple, selective and sensitive derivative spectrophotometric method has been developed for the determination of palladium(II) using a newly synthesised reagent diacetylmonoxime-(p-anisyl)-thiosemicarbazone in acetic acid medium. The molar absorptivity and Sandell's sensitivity of the coloured species are 3.8 104 L mol-1 cm-1 and 2.8 ng cm-2, respectively. Beer's law is obeyed between 0.2-2.0 ?g mL-1 of Pd(II) at 440 nm. The stoichiometry of the complex is found to be 1:2 (metal:ligand). Calibration graph for the first order derivative spectrophotometric determination of palladium(II) is derived by measuring derivative amplitudes at 480 nm with a linear range 0.15-2.6 ?g mL-1. The metal ions, which are normally associated with palladium in mineral and alloy samples, do not interfere. The proposed method has been successfully applied for the trace level determination of palladium in hydrogenation catalysts and some synthetic mixtures. -
Electrochemical investigations of chitosan/ZrO2-Bi2O3 composite for advanced energy and environmental applications
Energy needs are on the rise, and the need for effective corrosion resistance measures are also vital to meet the requirements prevailing in society. A multifunctional Chitosan/ZrO2-Bi2O3 composite is synthesized, keeping electrochemical analysis of energy and environmental applications in mind. Various physicochemical methods confirm the impact of integrating ZrO2-Bi2O3 into chitosan, resulting in improved efficacy across applications. The electrocatalytic supercapacitance, hydrogen evolution reaction, and corrosion inhibition studies are carried out to evaluate the efficiency of the synthesized composite. The composite shows a specific capacitance of 636.5 F/g, ensuring the effective utility for supercapacitance applications. The lower overpotential of 135.2 mV is shown by the composite in the electrocatalytic hydrogen evolution reaction. The synthesized composite also shows 96.2 % efficacy in corrosion inhibition studies. The studies conducted demonstrate the increased effectiveness of chitosan when combined with bimetal oxide. The chitosan composite is therefore a competent catalyst for energy and environmental applications. 2024 Elsevier Ltd -
Investigations on the electronic properties and effect of chitosan capping on the structural and optical properties of zinc aluminate quantum dots
Quantum confined uncapped and chitosan capped nanoparticles of ZnAl2O4 synthesized by microwave-assisted solgel method were investigated by structural analysis and optical techniques. X-ray diffraction studies confirmed the formation of cubic spinels with crystallite size 4.5 nm and 3.4 nm, respectively for uncapped and chitosan capped ZnAl2O4 nanoparticles. Chitosan capping produced a blue shift in bandgap energy (3.84 to 3.94 eV) agreeing with size effects according to the Brus equation. A blue shift in emission peak and enhancement in photoluminescence intensity was also observed upon chitosan capping. The electronic band structure and the density of states of the bulk spinel were also calculated using density functional theory. The effective masses of electrons and holes estimated based on the band structure were used to extract the excitonic Bohr radius. 2021 Elsevier B.V. -
Abjection and Intersecting Trans Women Identities: Examining Doing Gender through Malayalam Movies Ardhanaari and Njan Marykutty; [Abjeo e Identidades de Mulheres Trans Interseccionadas: Examinando Fazendo Gero atrav dos Filmes em Malayalam Ardhanaari e Njan Marykutty]; [Examinando hacer gero a trav de las pelulas en malayalam Ardhanaari y Njan Marykutty]
The non-confirmation to vexed societal gender norms places trans identities in an abjected state. Media, mainly cinema, plays an indispensable role in shaping, shunning, and promulgating such ideologies. To understand this discourse, the Malayalam films Ardhanaari (2015) and Njan Marykutty (2018) are taken to examine the question of abjection, a concept by Kristeva, and doing gender, by West and Zimmerman. The study argues that the abjection trans identities face forces them to perform their gender in accordance with cisnormative femininity. The study further argues that trans identities should embrace abjection and employ it as a political tool to disrupt the established hegemonic traditional gender structure and its definitions. 2023 Universidad de Guadalajara. All rights reserved. -
First Order Derivative Spectrophotometric Determination of Thorium in Geological Samples Using Diacetylmonoxime p-hydroxybenzoylhydrazone
Mapana Journal of Sciences, Vol-12 (1), pp. 15-30.