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Education for All: How Schooling Is Creating Social Changes for Lowered-Caste Girls in Rural India
Arguments for the expansion of formal schooling have long focused on individual outcomes from schooling, including increasing income, reducing poverty, delaying marriage, and improving health, particularly for girls and women. For nearly three decades now, global education agendas have supported girls education in an effort to achieve these outcomes. A large body of research analyzes girls individual empowerment from schooling, but less attention is given to how schooling is creating change in families and communities, particularly for lowered-caste girls in India. This article places longitudinal data from a three-year qualitative interview study of schoolgirls in Rajasthan alongside qualitative life-history interviews of girls who completed secondary school in Uttarakhand to understand how schooling affects social changes for lower castes. The analysis, using an intersectional and relational approach, illustrates how girls schooling shifts kin and caste relations connected to marriage and work but in ways that do not transform the stickiness of caste and gender norms. We argue that educational policies and programs must attend to the ways in which caste is implicated in achieving outcomes of delayed marriage and formal employment for lowered-caste girls in Indian communities if schooling is to create positive social change. 2020 by The Author(s). -
An efficient hybrid approach for numerical study of two-dimensional time-fractional Cattaneo model with Riesz distributed-order space-fractional operator along with stability analysis
In this article, we study and analyze the two-dimensional time-fractional Cattaneo model with Riesz space distributed-order. To obtain approximate solutions of this type of fractional model the combined and effective numerical approach based on the ADI Galerkin method and the Legendre spectral method used the ADI Galerkin numerical method uses the finite difference approach. The ADI Galerkin numerical method is used to approximate the proposed model in terms of the time variable, and the Legendre spectral method is applied to discretize the fractional model with respect to the space variable. Also, the convergence analysis and stability of the proposed method are discussed and reviewed in this manuscript. In the end, some numerical examples are tested for the effectiveness and accuracy of the proposed method. As well as, in the numerical examples section, the presented numerical approach is compared with two numerical methods and the results are reported in a table. 2024 IOP Publishing Ltd. All rights, including for text and data mining, AI training, and similar technologies, are reserved. -
Unveiling the potential: iodide-infused nickel-enhanced MXene composite for high-performance sodium ion hybrid capacitors
2D-MXenes have gained much popularity for energy storage applications such as hybrid capacitors, and they have shown very competitive performance, especially as electrode materials for sodium ion hybrid capacitors. However, they suffer from various problems, such as morphology distortion and fast capacity fading, which results in the poor performance of the battery. As a result, researchers have focused more on MXene-based composite materials to address these issues. In this work, we report a sodium iodide and nickel-decorated MXene-based composite (Ti2C/Ni/NaI) material as an electrode for a sodium ion hybrid capacitor. Ti2C MXene and Ni were able to provide physical and mechanical strength, and iodine was able to produce redox activity. The composite had a rough surface with readily aggregated 2D-MXene sheets and was uniformly covered with Ni, Na, and I atoms. Several vibrational bands and peaks associated with Ti, Ni, Na, C and O in the Raman while XPS spectra confirmed the effective incorporation of dopants into the MXene sheets and successful synthesis of the Ti2C/Ni/NaI composite. The fabricated hybrid capacitor exhibited good capacity retention of 59% after 10,000 cycles at a current density of 0.5 mA g?1; thus, the Ti2C/Ni/NaI composite can be a promising electrode material for sodium-based hybrid capacitors. 2025 The Author(s). Published by IOP Publishing Ltd. -
Electrochemical sensor based on PVP coated cobalt ferrite/graphite/PANI nanocomposite for the detection of hydrazine
In this study, we developed a multi-layered electrode as an efficient nanocomposite electrochemical sensor for detecting carcinogenic hydrazine in water. Nano-cobalt ferrite (CoFe2O4) was prepared using poly (vinylpyrrolidone) (PVP), mixed with an optimum quantity of graphite and pasted on a stainless-steel current collector. The nanocomposite was further hybridised by electrodepositing with polyaniline (PANI). The obtained composite was characterized using XRD, FTIR, SEM, and electrochemical techniques. XRD analysis shows the successful formation of composite from individual precursors. According to SEM, wrinkled and layered morphology for graphite and aggregate clusters for cobalt with spike or tubular structure for polyaniline were observed. When subjected to amperometry current, the prepared electrode showed different peaks for different concentrations of hydrazine, such as 1 ?M to 100 ?M. Cyclic voltammetry studies showed an increase in oxidation and reduction peaks. These studies will lead to a new platform for their potential applications in detecting toxic materials in real samples such as water, plastic bottle, water etc., 2023 The Author(s). Published by IOP Publishing Ltd. -
Taxonomic studies in the genus Haplanthodes (Acanthaceae)
The endemic Indian genus Haplanthodes (Acanthaceae) is revised. Four species, viz. H. neilgherryensis, H. plumosa, H. tentaculata and H. verticillata and a new variety, H. neilgherryensis var. toranganensis are recognized. Lectotype is designated for Haplanthodes, Haplanthus plumosus and H. verticillaris. The nomenclature of the Linnaean name Ruellia tentaculata is also discussed. Micromorphology of seed using light microscope (LM) and scanning electron microscope (SEM) is observed for the first time, and two types, reticulate and micro papillate, have been recognized based on surface sculpturing pattern. The genus differs from the related genera Andrographis and Haplanthus by distinctly two grooved seeds with hygroscopic hairs. Pollen grains of the genus are oblate or prolate spheroidal, distinctly triangular, trizonocolporate with reticulate exine ornamentation. Copyright 2021 Magnolia Press -
On an anti-torqued vector field on riemannian manifolds
A torqued vector field ? is a torse-forming vector field on a Riemannian manifold that is orthogonal to the dual vector field of the 1-form in the definition of torse-forming vector field. In this paper, we introduce an anti-torqued vector field which is opposite to torqued vector field in the sense it is parallel to the dual vector field to the 1-form in the definition of torse-forming vector fields. It is interesting to note that anti-torqued vector fields do not reduce to concircular vector fields nor to Killing vector fields and thus, give a unique class among the classes of special vector fields on Riemannian manifolds. These vector fields do not exist on compact and simply connected Riemannian manifolds. We use anti-torqued vector fields to find two characterizations of Euclidean spaces. Furthermore, a characterization of an Einstein manifold is obtained using the combination of a torqued vector field and FischerMarsden equation. We also find a condition under which the scalar curvature of a compact Riemannian manifold admitting an anti-torqued vector field is strictly negative. 2021 by the authors. Licensee MDPI, Basel, Switzerland. -
How Offensive is offensive? A Closer Look at Controversial Advertisements
We live in a world inundated with messages that seek to promote products varied and eclectic in their feel and purpose. Capitalism has rooted itself in many societies; corporate enterprises enthusiastically advertise their products around the world. Over the years we have had countless advertisements bombard us through our TV sets, newspapers, billboards and now through our smartphones. While attention-grabbing, these advertisements are unfortunately often considered questionable. Rising competition among advertisers for consumer attention has led to the production of advertisements that are increasingly risquand frequently downright offensive. There have been growing concerns about the increasingly low standards of advertisements. Be it excessive sexual content, discrimination on grounds of gender, or propagating regressive philosophies, advertisements seek attention for the wrong reasons. While some advertisements were once downright discriminative towards the female population, things seem to have gradually gotten better over the past few years. However, that is not to say that stereotyping and sexism have been wholly eradicated from advertising; these issues are still prevalent today. Though some consumers watch advertisements through a critical lense and critique unethical advertisements, many offensive and discriminative advertisements have still become widely known and popular among viewers. The present paper seeks to explore the idea of offensiveness in advertisements through an analysis of advertising content on the basis of gender discrimination and stereotypical portrayals of gender. Further, a focused group discussion adds audience perspective to the issue as well. Straddled by Uses and Gratification Theory, Social Responsibility Theory, and Self-Construal Theory, this study attempts to explore the concept of the offensiveness of controversial advertisements and to determine the reasons why an advertisement is deemed offensive. It is never too late to question How Offensive is offensive? 2021 Journal of International Womens Studies. -
Brinkman-Bard convection in a box with temperature modulation
A bounded porous box saturated with Newtonian fluid and subjected to a sinusoidal temperature gradient has various practical applications, such as solar energy storage, groundwater remediation, food processing, and chemical reactors. We address the generalization of the classical Rayleigh-Bard convection problem in a horizontal fluid layer in an infinitely large domain heated from below to a finite three-dimensional box. We also look into a more intricate form of the modulated Rayleigh-Bard problem in which the temperature at the bottom boundary varies sinusoidally. The Rayleigh number quantifies the non-sinusoidal part of the temperature gradient, while the amplitude and frequency of modulation describe the sinusoidal one. The critical Rayleigh number is determined using linear and nonlinear stability analyses; for the latter, the energy method is used. There is a possibility of subcritical instabilities, as evidenced by the energy stability estimates being lower than the linear ones. Furthermore, eigenvalues are obtained as a function of aspect ratios, modulation amplitude, and frequency for varying Darcy numbers. Modulation amplitude more significantly triggers a change in flow patterns at the onset of convection compared to the effect of other parameters. Considering water-saturated porous media made up of different materials, we report the critical temperature difference between lower and upper surfaces required for the onset of convection. In addition, a comparison between such a temperature difference obtained from linear theory and the energy method is also provided in the same manner. It is observed that subharmonic instability occurs for all considered porous media packed densely or sparsely. 2024 Author(s). -
Homosexuality as a Dominant Narrative in Class
[No abstract available] -
Is it morally justified to create disabled designer babies?
This research paper explores the questionwhether it is morally permissible for an auditory impaired parent to create an auditory impaired offspring? It makes an epistemological inquiry into the experiences of persons with auditory impairments to make an informed decision on the question at stake. There is a general attitudinal bias against the disability. On the contrary, arguments have been raised that a parent with auditory impairment may have a moral right and a liberty to have a specially designed deaf baby. It is argued that a deaf parents desire to have a deaf child, stems from their need to relate linguistically and culturally with the child. It is also in the best interest of the child and the parent. Such arguments seem grossly misguided and are often countered with arguments of open future, and the costs of disability. This research paper seeks to inquire into the epistemic challenges in examining the validity and the soundness of these arguments. It engages into the arguments and counter arguments with respect to whether auditory impairment is a disadvantageous condition to find that deafness does involve an element of harm though it is not only and only harm. It argues against the proposition that laws permitting abortion in case of foetal anomaly are eugenic. It uses Kantian theory to delve into the moral permissibility of the use of genetic engineering for the creation of impairment and enhancement. In the light of moral, ethical and jurisprudential considerations it finds that it is morally impermissible to use genetic interventions to create impairments or enhancements, as it strikes at the humanity in the designer babies and uses them as a means for the satisfaction of desires. 2021, The Author(s), under exclusive licence to O.P. Jindal Global University (JGU). -
Jurisprudential basis of the right to clean and healthy environment
Examining the basis of the right to a clean and healthy environment helps in an increased understanding of the nature of the right which in turn will further the job of devising effective strategies and policies to meet the interests of the environment and make the right a reality. This paper examines four strategies: Firstly protect environment rights by declaring it to be a right. This would protect it from mutilation at the hands of political processes, and thus would be a safer option, but its dimensions have not yet been crystallised. Secondly, it can be protected by making it part and parcel of human rights. Thirdly, the Interest Theory suggests that the interest of the environment must be protected for its own sake by creating such an interest. Fourthly, the notion of Intergenerational Responsibility which establishes that the present generation has an obligation/duty to preserve and protect the environment for a correlative similar right which the future generation enjoys. The article also examines the conflict between environment protection and developmental needs of humanity. Indian courts have referred to traditional Indian philosophy of 'Dharma' and have tried to adopt a balancing approach by integrating environment values with developmental values. Any theory that does not resolve the above conflict would clearly be insufficient. 2013 Journal of Dharma: Dharmaram Journal of Religions and Philosophies (DVK, Bangalore). -
Reflection of Public Policy on Environment
International Journal of Research in Social Sciences Vol.3, Issue 1, pp.184-196. ISSN No. 2249-2496 -
Study of X-Ray Intraday Variability of HBL Blazars Based on Observations Obtained with XMM-Newton
We present an extensive study on the X-ray intraday variability of 10 teraelectronvolt-emitting high synchrotron peaked blazars (HBLs): 1ES 0229+200, 1ES 0414+009, PKS 0548-322, 1ES 1101-232, 1H 1219+301, H 1426+428, Mrk 501, 1ES 1959+650, PKS 2005-489, and 1ES 2344+514 made with 25 XMM-Newton pointed observations during its operational period. Intraday variability has been estimated in three energy bands: soft (0.3-2 keV), hard (2-10 keV), and total (0.3-10 keV). Although seven out of 10 teraelectronvolt HBLs exhibited some intraday variability at 3? levels, no major variations exceeding 6% were detected. We explored the spectral properties of the sample by extracting the hardness ratio from the soft and hard bands; no significant variations in the hardness ratio were observed in any source. We performed power spectral density analyses on the variable light curves by fitting power laws, yielding slopes lying in the range of 1.11-2.93 for different HBLs. We briefly discuss possible emission mechanisms and carry out rough estimates for magnetic fields, electron Lorentz factors, and emission region sizes for seven of these HBLs. 2022. The Author(s). Published by the American Astronomical Society. -
UVIT Observations of the Small Magellanic Cloud: Point-source Catalog
Three fields in the outskirts of the Small Magellanic Cloud were observed by the UltraViolet Imaging Telescope (UVIT) on board AstroSat, between 2017 December 31 and 2018 January 1. The observations were carried out on a total of seven filters, three in the far-ultraviolet (FUV; 1300-1800 band and four in the near-ultraviolet (NUV; 2000-3000 band. We carried out photometry of these observations that have a spatial resolution better than 1.?5. We present here the first results of this work, which is a matched catalog of 11,241 sources detected in three FUV and four NUV wavelengths. We make the catalog available online, which would be of use to the astronomical community to address a wide variety of astrophysical problems. We provide an expression to estimate the total count rate in the full point-spread function of UVIT that also incorporates the effect of saturation. 2023. The Author(s). Published by the American Astronomical Society. -
Molecular Simulation Prediction on SO2 Gas Adsorption in Bipyridine Ligand-Based Square-Pillared MOFs
Increasing concentrations of toxic gases caused by the burning of fossil fuels necessitates the development of efficient porous materials for gas capture. Metal-organic frameworks (MOFs) have attracted a lot of attention as potential porous materials due to their effectiveness in adsorption of toxic gases. In particular, square-pillared metal-organic frameworks stand out for their exceptional potential toward gas adsorption, attributed to their remarkable surface area, thermal and chemical stabilities, and tunable properties. In this context, molecular simulations have been executed to observe and analyze the adsorption process of toxic flue gases such as SO2 and CO2 on MOFs. The present work deals with two different stable fluorinated MOFs named [Ni(4,4?-bipyridine)2(AlF5)]n (ALFFIVE-Ni-bipy) and [Ni(4,4?-bipyridine)2(NbOF5)]n, (NBOFFIVE-Ni-bipy) featuring AlF52- and NbOF52- anion pillars, respectively, comprising 4,4?-bipyridine as organic ligand and nickel as the central metal. The significance of utilizing the 4,4?-bipyridine ligands in these fluorinated MOFs enhances the SO2 gas adsorption and selectivity in the framework. Density functional theory has been implemented for geometry optimization, and Grand Canonical Monte Carlo simulations have been performed to forecast the adsorption isotherms. Both ALFFIVE-Ni-bipy (11.4 mmol/g) and NBOFFIVE-Ni-bipy (8.7 mmol/g) showed high SO2 adsorption capacity at 1 bar pressure, but ALFFIVE-Ni-bipy showed very good adsorption than other square-pillared MOFs and also unveiled good selectivity of SO2 gas. The coadsorption of binary SO2/CO2 and ternary SO2/CO2/N2 gas mixtures at ambient conditions indicated that the cost-effective aluminum (Al)-based square-pillared ALFFIVE-Ni-bipy is particularly suitable for acid gas adsorption. 2024 American Chemical Society -
Discontinuities in the trajectory of solar photovoltaic (SPV) technology development in India
The objective of this paper is to understand different phases of solar photovoltaic (SPV) technology in India and the interplay of scientific, technological, economic, and political factors in each of the phases. There are four distinct phases. In the first-phase (1947-1970), SPV technology was recognized as an important source of energy for countries like India. In the second phase (1971-1990), the oil crisis led to the formulation of new scientific and technological initiatives and programs in SPV, but due to a lack of political commitment the initiatives disintegrated. In the third phase (1991-2003), several factors seemed to have undermined the development of SPV sector. Currently in the fourth phase (2003 to the present), India has virtually lost the race for development of photovoltaic technology. Within the context of climate change and resource constraint, India has reformulated its strategy which has taken the form of the Jawaharlal Nehru National Solar Mission Plan (JNNSM).This paper examines how JNNSM influences indigenous attempts in photovoltaic technology development. The paper shows how scientific, technological, economic and political factors have contributed to discontinuities in the development of the technology. Koninklijke Brill Nv, Leiden 2015. -
ESIPT-AIE Active Schiff BaseFluorescent Organic Nanoparticles Based on 2-(2-(4-(4-bromo Phenyl) Thiazol-2-yl)Vinyl)Phenol (BTVP) Utilized as a Multi-Functional Fluorescent Probe
The present study reports the synthesis and characterization of Aggregation-Induced Emission (AIE) Excited-state intramolecular proton transfer (ESIPT) active 2-(2-(4-(4-bromo phenyl) thiazol-2-yl)vinyl)phenol (BTVP). The AIE properties of BTVP in Acetone/Water solution are investigated, and fluorescent organic nanoparticles (FONs) (sizes ranging from 150200nm) are preparedin various water fractions (fH2O). The established visco-chromic property suggests that the restriction of intramolecular rotation is responsible for the AIE-ESIPT behavior of the molecule, providing a means to sense viscosity. The synthesized FONs act as fluorescence chemosensors to detect Al3+ ions via a photoinduced electron transfer (PET) mechanism. Job's, BenesiHildebrand method, and 1HNMR titration confirm the 1:1 binding of BTVP with the metal ion. Studies on the emission concerning pH reveal the high stability of FONs over a broad range of pH, and a gradual change in the emission wavelength for the BTVP-Al3+ complex (BTVP-Al) is observed, providing a means to sense pH ranging from 28. The solid-state photoluminescence of BTVP is used for latent fingerprint detection, demonstrating its efficiency in detecting both primary and secondary information. Additionally, both BTVP FNOs and BTVP-Al are used in cell imaging, where specific nuclear staining with BTVP-Al and cytoplasm staining with BTVP are observed. 2023 Wiley-VCH GmbH. -
Synthesis, DFT and In Silico Anti-COVID Evaluation of Novel Tetrazole Analogues
A new series of 3-aryl/heteroaryl-2-(1H-tetrazol-5-yl) acrylamides have been synthesized through catalyst-free, one-pot cascade reactions, utilizing click chemistry approach and evaluated for their anti-COVID activities against two proteins in silico. The structural properties of the synthesized molecules were evaluated based on DFT calculations. Total energy of the synthesized tetrazole compounds were obtained through computational analysis which indicate the high stability of the synthesized compounds. The Frontier Molecular Orbitals (FMO) and associated energies and molecular electrostatic potential (MEP) surfaces were generated for the compounds. Spectral analysis by DFT gave additional evidence to the structural properties of the synthesized molecules. All tetrazole analogues come under good ADMET data as they followed the standard value for ADMET parameters. Docking studies offered evidence of the molecules displaying excellent biological properties as an anti-Covid drug. Compound 4 g exhibited excellent anti-COVID-19 properties with four hydrogen binding interactions with amino acids GLN 2.486 GLN 2.436 THR 2.186 and HSD 2.468 with good full-fitness score (1189.12) and DeltaG (7.19). Similarly, compound 4d shown potent activity against anti-COVID-19 mutant protein (PDB: 3K7H) with three hydrogen binding interactions, i.e., SER 2.274 GLU 1.758 and GLU 1.853 with full-fitness score of 786.60) and DeltaG (6.85). The result of these studies revealed that the compounds have the potential to become lead molecules in the drug discovery process. 2022 Taylor & Francis Group, LLC. -
A Selective Excited-State Intramolecular-Proton-Transfer (ESIPT) Sensor for Copper(II) Based on Chelation-Enhanced Quenching and Off-On Detection of Amino Acids
We report the synthesis of 2-(4,5-diphenyl-1H-imidazole-2-yl)phenol (TPI-9) as an interesting fluorescent molecule displaying Excited-State Intramolecular-Proton-Transfer (ESIPT) with stokes shift of 120 nm. Phenolic compounds with the ability to form intramolecular hydrogen bonds and subsequent proton transfer are known as ESIPT fluorophores. Proton accepting ability can increase significantly by tailoring electron-donating groups. With the assistance of an environment-friendly organocatalyst, 10-camphor sulfonic acid (10-CSA), TPI-9 was synthesized to introduce substituents with electron-donating abilities to develop an efficient ESIPT mechanism. Factors influencing the emission, such as solvent, pH, and metal ions, are investigated. Quenching of fluorescence by Cu2+ through chelation enhancement quenching effect with a high selectivity allowed the establishment of a Cu2+ sensor with an LoD of 0.57 ppm and a ratiometric estimation with an LoD of 0.73 ppm. Metal binding (2 : 1) stoichiometry and quenching constant (0.0072 mol?1s?1) are calculated from Job's and Stern-Volmer plots. Density functional theory (DFT) calculations are in accordance with the experimental results. Competitive replacement of TPI-9 by amino acids restores ESIPT, consequently, the fluorescence. Thus, an off-on fluorescence sensor for amino acid estimation is developed under 1 minute incubation. A linear relationship between amino acid concentration and fluorescence intensity is in 0-20 ?g/mL range, and the LoD is less than 2.2 ?g/mL. 2023 Wiley-VCH GmbH. -
A concise route to fused tetrazolo scaffolds through 10-camphor sulfonic acid auto-tandem homogeneous catalysis and mechanistic investigation
10-Camphor sulfonic acid (10-CSA) as an organo-catalyst has gained interest due to its versatile solubility and easiness of handling. This work reports a simple synthetic method through non-classical Biginelli for the construction of tetrazolo pyrimidine (4a-m) and quinazolines (4a?-o?). Azolopyrimidines and quinazolines are of great pharmaceutical importance. Numerous compounds are currently in use for the treatment of different diseases. Therefore their synthesis is industrially inevitable. Employing aldehydes, 1,3-dicarbonyls, and 5-Aminotetrazole, we report eco-friendly, cost-effective catalysis through a tandem reaction catalyzed by the 10-CSA that gave excellent yields, 7095 % for tetrazolo quinazoline and 4576 % tetrazolo pyrimidines respectively. The homonuclear NOESY analysis confirms the selective formation of one isomer. All the compounds are characterised by 1H NMR, 13C NMR, and MS. Investigation of the reaction mechanism by both experimental and theoretical studies provides evidence. Mechanism of the reaction was also explained utilizing the information from mass spectrometry monitoring. DFT calculation carried out at PBEPBE (Perdew-Burke-Ernzerhof) functional and 6-31G (d,p) basis set level of theory of the various intermediates observed supports the experimental evidence. 2023 Elsevier B.V.