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Catalytic potential of fluorescein under visible light irradiation: Enabling single-pot open flask synthesis of novel pyrazolyl methanesulfonamides
This groundbreaking study introduces a novel and efficient method for synthesizing a range of substituted pyrazolyl methanesulfonamides through a five-component cyclocondensation reaction. This reaction incorporates five different components, such as ethyl acetoacetate, hydrazine, dimedone, benzaldehydes, substituted phenyl acetonitriles, and methyl sulfonyl chloride was made to react under visible light irradiation, with fluorescein serving as an effective catalyst and ethanol as solvent for 30 mintues. This method offers significant advantages, including simplified handling, higher yields of target products with shorter reaction times, and easier purification processes. We successfully synthesized around 15 novel pyrazolyl methanesulfonamide derivatives with high efficiency. Comprehensive spectral characterization confirmed the structural integrity and purity of these derivatives, demonstrating the robustness and versatility of this approach. Facilitated by visible light and utilizing fluorescein as a bio-friendly catalyst, this methodology is both green and sustainable. This innovative approach not only streamlines the synthesis of pyrazolyl methanesulfonamides but also holds considerable promise for advancing research and applications in fields such as medicinal chemistry and materials science. 2024 The Author(s) -
Catalyzing the Affordability of Perovskite Solar Cells with Aluminum-Modified Cubic Titania
As a key component of perovskite solar cells (PSCs), the electron transport layer (ETL) extracts charges efficiently. While TiO2 is widely recognized as a superior electron transport material (ETM) for its numerous advantages, the morphological limitations of spherical TiO2 nanoparticles (NPs) lead to significant electron losses. Therefore, as an alternative to nanospheres, TiO2 nanocubes are synthesized through a solvothermal route and employed as ETM in the low-cost carbon electrode-based perovskite solar cells (CPSCs). The structural, morphological, and optical properties of the TiO2 nanocubes (NCs) are studied and compared with TiO2 nanospheres (NSs) in detail. The device possessing cubic TiO2 achieved a power conversion efficiency (PCE) of 10.6% with a current density (Jsc) of 21.79 mA/cm2. Recognizing that the oxygen vacancies in cubic TiO2 are lower than in spherical TiO2, it is inferred that further reduction of oxygen vacancies in cubic TiO2 could enhance the current collection. Hence, to get rid of the oxygen vacancy (which acts as an electron trap) in the cubical TiO2, aluminum (Al3+) is incorporated into its matrix. A comprehensive analysis of its impact on structural and optical behavior follows. In addition to its cost-effectiveness and conductive nature, it has been observed that the stable form of Al3+ replaces the unstable Ti3+ (which acts as a trap state), thereby reducing the recombination rate. With the highest current collection of 22.85 mA/cm2, a PCE of 11.3% has been recorded for the solar cell that possessed 1% Al-doped TNC. Furthermore, the ambient stability of the respective device shows ?85% of its initial PCE. The effect of the TiO2 nanostructure and Al3+ doping in TiO2 nanocubes is discussed elaborately in this work. 2024 American Chemical Society -
Cation-controlled wetting properties of vermiculite membranes and its promise for fouling resistant oilwater separation
Manipulating the surface energy, and thereby the wetting properties of solids, has promise for various physical, chemical, biological and industrial processes. Typically, this is achieved by either chemical modification or by controlling the hierarchical structures of surfaces. Here we report a phenomenon whereby the wetting properties of vermiculite laminates are controlled by the hydrated cations on the surface and in the interlamellar space. We find that vermiculite laminates can be tuned from superhydrophilic to hydrophobic simply by exchanging the cations; hydrophilicity decreases with increasing cation hydration free energy, except for lithium. The lithium-exchanged vermiculite laminate is found to provide a superhydrophilic surface due to its anomalous hydrated structure at the vermiculite surface. Building on these findings, we demonstrate the potential application of superhydrophilic lithium exchanged vermiculite as a thin coating layer on microfiltration membranes to resist fouling, and thus, we address a major challenge for oilwater separation technology. 2020, The Author(s). -
Cattaneo-Christov heat flux on UCM nanofluid flow across a melting surface with double stratification and exponential space dependent internal heat source
Melting and exponential space dependent internal heat source effects on magnetohydrodynamic of upper convected Maxwell liquid towards a horizontal flat surface are addressed. The combined effect of Brownian motion and thermophoresis in nanofluid modeling are retained. The Cattaneo-Christov heat flux model is imposed. Impacts of thermal and solutal stratifications are also accounted. A set of similarity variables are utilized to form ordinary differential system from the prevailing partial differential equations. The problem of ordinary differential system is analyzed numerically through Runge-Kutta-Fehlberg based shooting method. Graphical results of pertinent parameters on the velocity, temperature and nanoparticle concentration are studied. Skin friction coefficient, local Nusselt number and Sherwood number are also addressed. 2017 -
Cattaneo-Christov Theory to model heat flux effect on nanoliquid slip flow over a spinning disk with nanoparticle aggregation and Hall current
The heat transport of a nanoliquid on a spinning disk with velocity slip and thermal jump boundary conditions is modeled. The effects of external magnetism and the aggregation of nanoparticles are analyzed. The Cattaneo-Christov heat flux model and the Joule heating phenomenon are incorporated in the thermal analysis. The central composite design (CCD) of the response surface methodology is implemented to optimize heat transfer in the nanoliquid. The sensitivity of the heat transport is analyzed. The partial differential governing model is converted into a system of ordinary differential equations using a novel von Karmans transformation, the consequent system is solved numerically. The significance of physical operating parameters is analyzed through a detailed parametric study. Optimal levels of Hall parameter, Hartmann number, and Eckert number, that optimize the heat transport are determined. The Lorentz force expands the structure of the thermal layer and subsequently reduces the heat transport of the system. The Hall current improves the thickness of the velocity layer in the radial direction, while the thickness of the thermal layer is reduced. Viscous dissipation improves the thickness of the thermal boundary layer. The isothermal boundary condition causes less heat transport in the system than the temperature jump condition. 2022 Informa UK Limited, trading as Taylor & Francis Group. -
Causal relationship among various development indices: A panel study
The concept of development has been regarded as a broader phenomenon encompassing various interrelated factors leading to improvement in the overall human wellbeing. So, it is important to understand the interlinkages between various dimensions of development. The present study was an attempt to analyze the causal relationship between the four aspects of development measured by the indices, namely the Economic Development Index (EDI), Social Development Index (SDI), Environment Development Index (ENDI), and Institutional Development Index (IDI) for a panel of 102 counties from 1996 to 2015. The long?run relationship between these indices through the panel ARDL model were also examined. The results indicated that there existed a bidirectional causal relationship between EDI and SDI, IDI and SDI, ENDI and SDI, and between IDI and ENDI. The one-way causality runs from IDI to EDI and ENDI to EDI. Further, given the nature of the variables considered here, panel autoregressive distributed lag models were used to examine the long?run relationship between the indices of development. The results showed that the impact of development indices with one another was statistically significant in the long run. 2021 The Society of Economics and Development, except certain content provided by third parties. -
Causal relationship between leverage and performance: Exploring Dhaka Stock Exchange
To magnify shareholders' returns, managers employ the use of debt in the firms' capital structure. However, excessive debt financing can often cause financial distress for the firms. In fact, various debt equity ratio levels may lead to different financial performance when compared for high levered and low levered firms. Thus, the aim of this paper is to examine the cause and effect relationship between financial leverage and financial performance of firms. To pursue the purpose, a purposive sample of 163 non-financial firms listed on the Dhaka Stock Exchange (DSE) was selected to conduct this study. Findings indicate that there was no significant difference in the financial performance between high levered and low levered firms, neither in terms of their size nor growth rates. A negative relationship therefore persists between leverage and performance of such firms. Implications of these findings can provide policy guidelines for managers and directions for any further work in this context. Copyright 2018 Inderscience Enterprises Ltd. -
Causal relationship between leverage and performance: Exploring Dhaka Stock Exchange
To magnify shareholders' returns, managers employ the use of debt in the firms' capital structure. However, excessive debt financing can often cause financial distress for the firms. In fact, various debt equity ratio levels may lead to different financial performance when compared for high levered and low levered firms. Thus, the aim of this paper is to examine the cause and effect relationship between financial leverage and financial performance of firms. To pursue the purpose, a purposive sample of 163 non-financial firms listed on the Dhaka Stock Exchange (DSE) was selected to conduct this study. Findings indicate that there was no significant difference in the financial performance between high levered and low levered firms, neither in terms of their size nor growth rates. A negative relationship therefore persists between leverage and performance of such firms. Implications of these findings can provide policy guidelines for managers and directions for any further work in this context. Copyright 2018 Inderscience Enterprises Ltd. -
Causality among Energy Consumption, CO2 Emission, Economic Growth and Trade: A Case of India
The present study attempts to examine the causal nexus between energy consumption, CO2 emissions, economic growth and trade in India using the Perron (1989) unit root test, Gregory and Hansen (1996) cointegration test and vector error-correction model (VECM). The study results exhibit a long-run relationship between energy consumption, CO2 emissions, economic growth and trade in India. The empirical results confirm that energy consumption influences the economic activity in the short run, implying that higher rate of economic growth is driven by consumption demand for energy in the economy. This is also well in consistence with the findings of Paul and Bhattacharya (2004) in the Indian context. Further, the study detects one-way causation that exists from energy use to CO2 emission and trade, and CO2 emissions to economic growth in the short run. 2015 Indian Institute of Foreign Trade. -
Causality and volatility spillovers of banks' stock price returns on BSE Bankex returns
This paper investigates the causal relationships and volatility spillovers between the BSE Bankex index and the stock prices of five major Indian banks (Axis Bank, HDFC Bank, ICICI Bank, Kotak Bank, and SBI). Daily data from January 2, 2018 to March 8, 2023 are used, and statistical techniques such as descriptive statistics, Unit Root test, Cointegration test, Ganger Causality test, OLS regression, and GARCH model are employed. The study finds bidirectional causal relationships between the bank stocks and BSE Bankex returns, suggesting that the movement of the bank stocks significantly affects the overall market returns and vice versa. The study also finds significant volatility spillovers between the bank stocks and BSE Bankex returns, implying that the shocks in the bank stocks affect the market returns and vice versa. The study's outcomes have practical implications for investors and policymakers. Investors can use the results to make informed investment decisions in the Indian stock market, while policymakers can use the findings to monitor the financial stability of the banking sector and design appropriate policy interventions to address any potential financial crises. Overall, the study's findings suggest that policymakers should proactively monitor and manage market risks to safeguard overall financial stability. 2023 Wiley Periodicals LLC. -
Causality between public expenditure and economic growth: The indian case
This study investigates the causal nexus between public expenditure and economic growth in India using cointegration approach and error correction model. The analysis was carried out over the period 1973 to 2012. The Cointegration test result confirms the existence of long-run equilibrium relationship between public expenditure and economic growth in India. The empirical results based on the error-correction model estimate indicates one-way causality runs from economic growth to public expenditure in the short-run and long-run, supporting the Wagner's law of public expenditure. -
Celebration of christmas as a symphony of interfaith in ?tm?nut?pam of St Chavara
This article is an attempt to reflect on the interfaith consciousness of St Kuriakose Elias Chavara, by making an Indian reading of his classical work ?tm?nut?pam, specifically focusing on how the incarnation of Christ is presented and celebrated with an open and inclusive approach. In ?tm?nut?pam, while explaining the episode of the Infancy Narrative, St Chavara addresses Child Jesus with the significant Indian name, Brahman?than, and Jesus is being worshipped by Brahmac?rinis with unique Indian offerings. The addition of an Indian character called S?nti as an aged shepherdess making conversation with Mother Mary makes the narrative Indian. Because of his deep and affective knowledge of Indian culture and religion, and having a moving openness and a dialogical approach to them, St. Chavara could develop a relevant cultural modification of his faith, which will have its unique stamp in the Indian Christian Theology. 2017 Journal of Dharma: Dharmaram Journal of Religions and Philosophies. -
Celebrity endorsements the interplay between intellectual property law and the consumer protection act, 2019
The ambit of Copyright law has expanded over time, leading to development of newer concepts such as, Personality Rights. These rights are vested in individuals who have acquired an identifiable persona in the eyes of the public. There are two important facets to personality rights-Right to Publicity &Right to Privacy. When such identifiable identities use their acquired celebrity status to promote goods and services of a company to attract more consumers, it can be understood as Celebrity Endorsements. This is the most common source of marketing used by major companies to increase sales and garner goodwill and reputation. However, this source of communicating necessary information to the public becomes dangerous when celebrities promote false or misleading advertisements. To counter such issues, the Consumer Protection Act, 2019 introduced provisions tohold celebrities endorsing such products or services to be liable for injury suffered by consumers. The Law mandates that in order to ensure that such misleading advertisements arent promoted, the celebrities must conduct due diligence of the products before endorsing them. However, the question remains that to what extent can celebrities, who are not directly involved in production or manufacturing, be held liable for exploiting their personality rights? This paper aims at addressing the newly created legal interlink between personality rights via celebrity endorsements and protection of consumer interests. 2020, National Institute of Science Communication and Information Resources. All rights reserved. -
Cellular agriculture research progress and prospects: Insights from bibliometric analysis
World agriculture is facing a daunting task to feed the burgeoning population against multiple production and environmental threats. The alarming growth in population vis-vis current food production is expected to increase the global food insecurity levels. Inter alia, cellular agriculture an incipient technology is being considered as a potential alternative to cater for the growing demand for food and nutrition. The technology aims to develop edible agricultural products including meat with reduced environmental footprint against conventional farm production. In this context, an attempt has been made to review the progress of cellular agriculture research in four decades (19812020) through a bibliometric analysis and to suggest a roadmap for future research. The study sourced data from the Web of Science during October 2020. Using keywords, the database showed 212 searches pertaining to cellular agriculture from 135 journals worldwide. Of the journals, seven had at least five published articles and 33 had two articles each. Subsequently, the bibliographic coupling among the identified journals was carried out. It is found that the Journals: Appetite, Meat Science, and Journal of Agricultural and Environmental Ethics had the largest circles corresponding to their respective number of publications coupled with notable linkages with other journals. Also, a detailed analysis was performed on categories, growth trend, keywords, institutions, regions and leading researchers of cellular agriculture. The findings indicate that the Appetite Journal followed by the Journal of Agricultural and Environmental Ethics had published a significant percentage of articles on cellular agriculture, and Environmental Science and Technology was identified as the highly cited journal. The USA, England and the Netherlands were identified as the progressive regions in cellular agriculture research. The bibliometric analysis points to sluggish progress in cellular agriculture research and production despite its potential benefits. Future research should focus on the cost-effectiveness of the technology, consumer willingness to buy, development of food safety protocols on its merit and regional policy governance coupled with popularising its paybacks in the context of ensuring food security. 2021 The Author(s) -
Centrality measures-based sensitivity analysis and entropy of nonzero component graphs
The nonzero component graph of a finite-dimensional vector space over a finite field is a graph whose vertices are the nonzero vectors in the vector space, and any two vertices are adjacent if the corresponding linear combination contains a common basis vector. In this paper, we discuss the centrality measures and entropy of the nonzero component graph and also analyze the sensitivity of the graph using the centrality measures. 2024 World Scientific Publishing Company. -
Ceramic-Polymer-Carbon Composite Coating on the Truncated Octahedron-Shaped LNMO Cathode for High Capacity and Extended Cycling in High-Voltage Lithium-Ion Batteries
Long-term electrochemical cycle life of the LiNi0.5Mn1.5O4 (LNMO) cathode with liquid electrolytes (LEs) and the inadequate knowledge of the cell failure mechanism are the eloquent Achilles heel to practical applications despite their large promise to lower the cost of lithium-ion batteries (LIBs). Herein, a strategy for engineering the cathode-LE interface is presented to enhance the cycle life of LIBs. The direct contact between cathode-active particles and LE is controlled by encasing sol-gel-synthesized truncated octahedron-shaped LNMO particles by an ion-electron-conductive (ambipolar) hybrid ceramic-polymer electrolyte (IECHP) via a simple slot-die coating. The IECHP-coated LNMO cathode demonstrated negligible capacity fading in 250 cycles and a capacity retention of ?90% after 1000 charge-discharge cycles, significantly exceeding that of the uncoated LNMO cathode (a capacity retention of ?57% after 980 cycles) in 1 M LiPF6 in EC:DMC at 1 C rate. The difference in stability between the two types of cathodes after cycling is examined by focused ion beam scanning electron microscopy and time-of-flight secondary ion mass spectrometry. These studies revealed that the pristine LNMO produces an inactive layer on the cathode surface, reducing ionic transport between the cathode and the electrolyte and increasing the interface resistance. The IECHP coating successfully overcomes these limitations. Therefore, the present work underlines the adaptability of IECHP-coated LNMO as a high-voltage cathode material in a 1 M LiPF6 electrolyte for prolonged use. The proposed strategy is simple and affordable for commercial applications. 2024 The Authors. Published by American Chemical Society. -
Cerium-doped Co3O4 spinel structures synthesized by modified combustion route as an excellent material for electrochemical applications
This work shed light on the impact of cerium doping on the structural and electrochemical features of Co3-xCexO4(x = 0, 0.02, 0.04) synthesized via a facile and cost-effective modified combustion route. The structural, morphological and compositional investigations unveiled the formation of nanocrystalline structures with promising morphologies. BET and XPS methodologies explored the materials' porosity and electronic state of the materials. The electrochemical performance of the synthesized materials was evaluated by Cyclic Voltammetry (CV) at various scan rates, Galvanostatic Charge-Discharge (GCD) at different current densities, and Electrochemical Impedance Spectroscopic (EIS) techniques. GCD studies depicted an exquisite specific capacitance of 498 Fg-1 for Co2.98Ce0.02O4 at a current density of 1 Ag-1 and it displayed a capacitance retention of 95 % for over 2000 GCD cycles further it retains up to 90 % even after 3000 GCD cycles at a current density of 1Ag-1 juxtapose to other compositions. Our work emphasizes the importance of the material for energy storage applications. 2024 Elsevier Ltd and Techna Group S.r.l. -
Certain results on trans-paraSasakian 3-manifolds
Let M be a trans-paraSasakian 3-manifold. In this paper, the necessary and sufficient condition for the Reeb vector field of a trans-paraSasakian 3-manifold to be harmonic is obtained. Also, it is proved that the Ricci operator of M is invariant along the Reeb flow if and only if M is a paracosymplectic manifold, an ?-paraSasakian manifold or a space of negative constant sectional curvature. 2022 Walter de Gruyter GmbH, Berlin/Boston. -
Certain types of metrics on almost coKler manifolds
In this paper, we study an almost coKler manifold admitting certain metrics such as ? -Ricci solitons, satisfying the critical point equation (CPE) or Bach flat. First, we consider a coKler 3-manifold (M,g) admitting a ? -Ricci soliton (g,X) and we show in this case that either M is locally flat or X is an infinitesimal contact transformation. Next, we study non-coKler (?, ?) -almost coKler metrics as CPE metrics and prove that such a g cannot be a solution of CPE with non-trivial function f. Finally, we prove that a (?, ?) -almost coKler manifold (M,g) is coKler if either M admits a divergence free Cotton tensor or the metric g is Bach flat. In contrast to this, we show by a suitable example that there are Bach flat almost coKler manifolds which are non-coKler. 2021, Fondation Carl-Herz and Springer Nature Switzerland AG. -
Challenges and concerns of assisted reproductive treatments: A systematic review
India, once a highly populated country with a Total fertility rate of 5.7 1(year 1960) now has one of the least fertility rates of the world around 2.3 1 (year 2015). In just one decade, with the rising economy, improving life expectancy and lifestyle, we have embraced a new disease Infertility 2. There are numerous reasons for rising infertility amongst Indians, some related to life style changes, some infections and some are occupational hazards. As a remedy to this new disease, hospitals in India were quick enough to learn Assisted Reproductive Technologies from foreign countries and practice the same in our home country. There are many ART clinics in every city however; this solution to the problem of infertility is a problem in itself. The paper uses a systematic review process to unravel the causes of infertility and highlights the concerns revolving around infertility treatments and finally presents suggestions to policy makers. 2019, Institute of Advanced Scientific Research, Inc.. All rights reserved.