Surface tuning of nanostructured graphitic carbon nitrides for enhanced electrocatalytic applications: a review
Doping; Functionalization; Graphitic carbon nitride; Nanocomposites; Synthesis
The precursors for developing sustainable and environment-friendly energy conversion and storage devices requires the utilization of advanced, highly efficient, and economical nano-structured electrocatalysts instead of conventional and expensive noble metals. Therefore, graphitic carbon nitride (g-C3N4) as a material has gained wide attention due to its relative ease of synthesis, high nitrogen content, conductivity, and tuneable band gap energy. In recent years, their tunable electronic properties along with physicochemical stability have given rise to numerous research delving into their diverse range of applications. With the advancement in the tuning of their electrochemical performance, the electrical conductivity of g-C3N4 can be enhanced by structurally modifying the g-C3N4 framework accordingly. This review focuses on various structural modifications of g-C3N4 by functionalization, elemental doping, and hybridizing techniques for ameliorating the number of active sites resulting in enhanced electrocatalytic performance. Herein, the prospective researchers are given a concise perspective regarding the surface tuning of g-C3N4 for improving their electrocatalytic applications. 2023 Elsevier Ltd
Mrinalini Kalyani A.K.; Rajeev R.; Benny L.; Cherian A.R.; Varghese A.
https://doi.org/10.1016/j.mtchem.2023.101523 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85152238204&doi=10.1016%2fj.mtchem.2023.101523&partnerID=40&md5=b20475d48001f60fa710433719fc735c
Mrinalini Kalyani A.K., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India; Rajeev R., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India; Benny L., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India; Cherian A.R., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India; Varghese A., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India
Recent Advances in Analytical Techniques for Antidepressants Determination in Complex Biological Matrices: A Review
analytical; antidepressant; biological matrices; chromatography; determination
Depression is one of the most prevalent but severe of mental disorders, affecting thousands of individuals across the globe. Depression, in its most extreme form, may result in self-harm and an increased likelihood of suicide. Antidepressant drugs are first-line medications to treat mental disorders. Unfortunately, these medications are also prescribed for other in- and off-label conditions, such as deficit/hyperactivity disorders, attention disorders, migraine, smoking cessation, eating disorders, fibromyalgia, pain, and insomnia. This results in an increase in the use of antidepressant medications, leading to clinical and forensic overdose cases that could be either accidental or deliberate. The findings revealed that people who used antidepressants had a 33% greater chance of dying sooner than expected, compared to those who did not take the medications. Analytical techniques for precisely identifying and detecting antidepressants and their metabolic products in a variety of biological matrices are greatly needed to be developed and made available. Hence, this study attempts to discuss various analytical techniques used to identify and determine antidepressants in various biological matrices, which include urine, blood, oral fluid (saliva), and tissues, which are commonly encountered in clinical and forensic science laboratories. The Author(s) 2023.
International Journal of Toxicology, Vol-42, No. 4, pp. 352-364.
ISSN: 10915818; PubMed ID: 36630687; CODEN: IJTOF
Kumar S., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, India; Darshan S., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, India; Baggi T.R., Central Forensic Science Laboratory, Ministry of Home Affairs, Govt. of India, Ramanthapur, Hyderabad, India, University College of Science, Osmania University, Hyderabad, India
Understanding the Role of Antimicrobial Peptides in Neutrophil Extracellular Traps Promoting Autoimmune Disorders
antimicrobial peptides; autoimmune disorders; cathelicidins; cytokines; defensins; neutrophil
AMPs are small oligopeptides acting as integral elements of the innate immune system and are of tremendous potential in the medical field owing to their antimicrobial and immunomodulatory activities. They offer a multitude of immunomodulatory properties such as immune cell differentiation, inflammatory responses, cytokine production, and chemoattraction. Aberrancy in neutrophil or epithelial cell-producing AMPs leads to inflammation culminating in various autoimmune responses. In this review, we have tried to explore the role of prominent mammalian AMPsdefensins and cathelicidins, as immune regulators with special emphasis on their role in neutrophil extracellular traps which promotes autoimmune disorders. When complexed with self-DNA or self-RNA, AMPs act as autoantigens which activate plasmacytoid dendritic cells and myeloid dendritic cells leading to the production of interferons and cytokines. These trigger a series of self-directed inflammatory reactions, leading to the emergence of diverse autoimmune disorders. Since AMPs show both anti- and pro-inflammatory abilities in different ADs, there is a dire need for a complete understanding of their role before developing AMP-based therapy for autoimmune disorders. 2023 by the authors.
Biswas S.; Sarojini S.; Jayaram S.; Philip I.; Umesh M.; Mascarenhas R.; Pappuswamy M.; Balasubramanian B.; Arokiyaraj S.
All Open Access; Gold Open Access; Green Open Access
https://doi.org/10.3390/life13061307 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85163758647&doi=10.3390%2flife13061307&partnerID=40&md5=0e9348eb63472ec53eaa93bff87beab4
Biswas S., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, 560029, India; Sarojini S., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, 560029, India; Jayaram S., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, 560029, India; Philip I., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, 560029, India; Umesh M., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, 560029, India; Mascarenhas R., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, 560029, India; Pappuswamy M., Department of Life Sciences, CHRIST (Deemed to be University), Bengaluru, 560029, India; Balasubramanian B., Department of Food Science and Biotechnology, College of Life Science, Sejong University, Seoul, 05006, South Korea; Arokiyaraj S., Department of Food Science and Biotechnology, College of Life Science, Sejong University, Seoul, 05006, South Korea
Plant Secondary Metabolites: The Weapons for Biotic Stress Management
aposematic signals; biopesticides; biotic stress; companion farming; feeding deterrents; metabolomics engineering; plant secondary metabolites
The rise in global temperature also favors the multiplication of pests and pathogens, which calls into question global food security. Plants have developed special coping mechanisms since they are sessile and lack an immune system. These mechanisms use a variety of secondary metabolites as weapons to avoid obstacles, adapt to their changing environment, and survive in less-than-ideal circumstances. Plant secondary metabolites include phenolic compounds, alkaloids, glycosides, and terpenoids, which are stored in specialized structures such as latex, trichomes, resin ducts, etc. Secondary metabolites help the plants to be safe from biotic stressors, either by repelling them or attracting their enemies, or exerting toxic effects on them. Modern omics technologies enable the elucidation of the structural and functional properties of these metabolites along with their biosynthesis. A better understanding of the enzymatic regulations and molecular mechanisms aids in the exploitation of secondary metabolites in modern pest management approaches such as biopesticides and integrated pest management. The current review provides an overview of the major plant secondary metabolites that play significant roles in enhancing biotic stress tolerance. It examines their involvement in both indirect and direct defense mechanisms, as well as their storage within plant tissues. Additionally, this review explores the importance of metabolomics approaches in elucidating the significance of secondary metabolites in biotic stress tolerance. The application of metabolic engineering in breeding for biotic stress resistance is discussed, along with the exploitation of secondary metabolites for sustainable pest management. 2023 by the authors.
Al-Khayri J.M.; Rashmi R.; Toppo V.; Chole P.B.; Banadka A.; Sudheer W.N.; Nagella P.; Shehata W.F.; Al-Mssallem M.Q.; Alessa F.M.; Almaghasla M.I.; Rezk A.A.-S.
https://doi.org/10.3390/metabo13060716 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85163707067&doi=10.3390%2fmetabo13060716&partnerID=40&md5=f8c5072a3e531b28ff938ff32c2a1241
Al-Khayri J.M., Department of Agricultural Biotechnology, College of Agriculture and Food Sciences, King Faisal University, Al-Ahsa, 31982, Saudi Arabia; Rashmi R., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bangalore, 560 029, India; Toppo V., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bangalore, 560 029, India; Chole P.B., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bangalore, 560 029, India; Banadka A., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bangalore, 560 029, India; Sudheer W.N., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bangalore, 560 029, India; Nagella P., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bangalore, 560 029, India; Shehata W.F., Department of Agricultural Biotechnology, College of Agriculture and Food Sciences, King Faisal University, Al-Ahsa, 31982, Saudi Arabia; Al-Mssallem M.Q., Department of Food Science and Nutrition, College of Agriculture and Food Sciences, King Faisal University, Al-Ahsa, 31982, Saudi Arabia; Alessa F.M., Department of Food Science and Nutrition, College of Agriculture and Food Sciences, King Faisal University, Al-Ahsa, 31982, Saudi Arabia; Almaghasla M.I., Department of Arid Land Agriculture, College of Agriculture and Food Sciences, King Faisal University, Al-Ahsa, 31982, Saudi Arabia, Plant Pests, and Diseases Unit, College of Agriculture and Food Sciences, King Faisal University, Al-Ahsa, 31982, Saudi Arabia; Rezk A.A.-S., Department of Agricultural Biotechnology, College of Agriculture and Food Sciences, King Faisal University, Al-Ahsa, 31982, Saudi Arabia, Department of Virus and Phytoplasma, Plant Pathology Institute, Agricultural Research Center, Giza, 12619, Egypt
Prospective applications of two-dimensional materials beyond laboratory frontiers: A review
Materials application; Materials science; Nanomaterials
The development of nanotechnology has been advancing for decades and gained acceleration in the 21st century. Two-dimensional (2D) materials are widely available, giving them a wide range of material platforms for technological study and the advancement of atomic-level applications. The design and application of 2D materials are discussed in this review. In order to evaluate the performance of 2D materials, which might lead to greater applications benefiting the electrical and electronics sectors as well as society, the future paradigm of 2D materials needs to be visualized. The development of 2D hybrid materials with better characteristics that will help industry and society at large is anticipated to result from intensive research in 2D materials. This enhanced evaluation might open new opportunities for the synthesis of 2D materials and the creation of devices that are more effective than traditional ones in various sectors of application. 2023 The Authors
Kumbhakar P.; Jayan J.S.; Sreedevi Madhavikutty A.; Sreeram P.R.; Saritha A.; Ito T.; Tiwary C.S.
https://doi.org/10.1016/j.isci.2023.106671 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85153801927&doi=10.1016%2fj.isci.2023.106671&partnerID=40&md5=8230b96bdff9dee8c7c6a8b073e009c5
Kumbhakar P., Metallurgical and Materials Engineering, Indian Institute of Technology, West Bengal, Kharagpur, 721302, India, Department of Physics and Electronics, CHRIST (Deemed to Be University), Bangalore, 560029, India; Jayan J.S., Department of Chemistry, National Institute of Technology Calicut, Kerala, Calicut, India, Department of Chemistry, Amrita Vishwa Vidyapeetham, Amritapuri, Kerala, Kollam, India; Sreedevi Madhavikutty A., Department of Chemical System Engineering, The University of Tokyo, Tokyo, 113-0033, Japan; Sreeram P.R., Metallurgical and Materials Engineering, Indian Institute of Technology, West Bengal, Kharagpur, 721302, India; Saritha A., Department of Chemistry, Amrita Vishwa Vidyapeetham, Amritapuri, Kerala, Kollam, India; Ito T., Department of Chemical System Engineering, The University of Tokyo, Tokyo, 113-0033, Japan, Center for Disease Biology and Integrative Medicine, Faculty of Medicine, The University of Tokyo, Tokyo, 113-0033, Japan; Tiwary C.S., Metallurgical and Materials Engineering, Indian Institute of Technology, West Bengal, Kharagpur, 721302, India
Micropollutants characteristics, fate, and sustainable removal technologies for landfill leachate: A technical perspective
Advanced treatment; Bioremediation; Landfill leachate; Micropollutants; Pesticides
Waste disposal in landfills has gained momentum in the last few decades as it is one among the easy and cost-effective method for waste management for the accelerating global population. Heterogenous nature of the waste ending up in landfills makes it difficult to predict the fate of these pollutants making it difficult for its biomonitoring and specific treatment. Among the major issues associated with landfill treatment, liquid percolation from this heterogenous waste substrate collectively referred as leachate poses the greater risk to environment through soil and ground water pollution. The diversity of micropollutants presents in landfill leachates ranging from microbial pathogens, pesticides, microplastics, pharmaceuticals and other harmful chemicals calls for crucial attention towards improving methods used for their treatment and removal. This review summarizes the key components of landfill leachates with specific emphasize on micropollutant content of leachate. Further the features of most recent and advanced technologies that were successfully explored for micropollutant removal from landfill leachates are presented in this review. 2023 Elsevier Ltd
Kumar V.; Sharma N.; Umesh M.; Chakraborty P.; Kaur K.; Duhan L.; Sarojini S.; Thazeem B.; Pasrija R.; Vangnai A.S.; Maitra S.S.
Journal of Water Process Engineering, Vol-53
https://doi.org/10.1016/j.jwpe.2023.103649 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85150059158&doi=10.1016%2fj.jwpe.2023.103649&partnerID=40&md5=249d4a85736a8f37037afe0d399b4795
Kumar V., Ecotoxicity and Bioconversion Laboratory, Department of Community Medicine, Saveetha Medical College, Saveetha Institute of Medical and Technical Sciences (SIMATS), Thandalam, Chennai, 602105, India; Sharma N., Metagenomics and Bioprocess Laboratory, School of Biotechnology, Jawaharlal Nehru University, New Delhi, India; Umesh M., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Chakraborty P., School of Allied Healthcare and Sciences, Jain (Deemed to be) University, Whitefield, Karnataka, Bangalore, 66, India; Kaur K., Department of Chemistry, Punjab Agricultural University, Punjab, Ludhiana, 141004, India; Duhan L., Department of Biochemistry, Maharshi Dayanand University, Rohtak, India; Sarojini S., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Thazeem B., Integrated Rural Technology Centre (IRTC), Mundur, Palakkad, 678592, India; Pasrija R., Department of Biochemistry, Maharshi Dayanand University, Rohtak, India; Vangnai A.S., Center of Excellence in Biocatalyst and Sustainable Biotechnology, Department of Biochemistry, Faculty of Science, Chulalongkorn University, Bangkok, 10330, Thailand; Maitra S.S., Metagenomics and Bioprocess Laboratory, School of Biotechnology, Jawaharlal Nehru University, New Delhi, India
Green synthesis of nanoparticles from biodegradable waste extracts and their applications: a critical review
Biodegradable wastes; Eco-friendly; Green synthesis; Metal and metal oxide nanoparticles; Sustainable environment
The contemporary world is concerned only with non-biodegradable waste management which needs more sophisticated procedures as compared to biodegradable waste management. Biodegradable waste has the potential to become useful to society through a simple volarization technique. The researchers are behind sustainable nanotechnology pathways which are made possible by using biodegradable waste for the preparation of nanomaterials. This review emphasizes the potentialities of biodegradable waste produced as a viable alternative to create a sustainable economy that benefits all humans. Volarization results in the utilization of biowastes as well as provides safer and hazard-free green methods for the synthesis of nanoparticles. Starting from different sources to the application which includes therapeutics, food industry and water treatment. The review hovers over the pros and cons of biowaste-mediated nanoparticles and concludes with possible advances in the application. In the present scenario, the combination of green synthesis and biowaste can bring about a wide variety of applications in nanotechnology once the hurdles of bulk-scale industrial production are resolved. Given these points, the review is focused on the cost-effective synthesis of metal and metal oxide nanoparticles. 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.
Aswathi V.P.; Meera S.; Maria C.G.A.; Nidhin M.
Nanotechnology for Environmental Engineering, Vol-8, No. 2, pp. 377-397.
Springer Science and Business Media Deutschland GmbH
Aswathi V.P., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bangalore, 560029, India; Meera S., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bangalore, 560029, India; Maria C.G.A., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bangalore, 560029, India; Nidhin M., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bangalore, 560029, India
Electrochemical deposition for metal organic Frameworks: Advanced Energy, Catalysis, sensing and separation applications
Electrocatalysis; Electrochemical deposition; Energy storage; Metal-organic framework; Surface modification; Thin film
The advent of metalorganic frameworks has gathered ever-increasing attention owing to their versatility, unparalleled porosity, tuneability, and rich topography. The need for an efficient synthetic method and the trending appeal for thin film MOFs has brought in huge data on electrochemical deposition techniques. Thin films have immense applications in the field of electronics (including energy devices such as batteries and supercapacitors), sensors, catalysis, and as liquid/gas separation devices. Here, the electrodeposition method requires no pre-treatment step, allows miniaturization, a homogeneous film with desirable thickness, and is observed to be an eco-friendly method. The limited number of articles focusing on the supremacy of the technique has motivated the authors to collectively summarize the scattered data. To limit the discussion to reasonable bounds, the article focuses on a critical comparison of electrodeposition techniques with other synthetic methods, and different types of electrodeposition methods, and familiarize them with the various electrodeposited MOF-composite designs. Finally, we discuss extensively the existing as well as future applications. This will encourage future researchers to exploit this electrochemical technique for designing & developing newer MOF films and similar next-generation materials which are energy-efficient, rapid, and accurate while in use. This review article hopes to list out significant advances in the area to the advantage of both commercial and academic aspects. 2023 Elsevier B.V.
Journal of Electroanalytical Chemistry, Vol-937
https://doi.org/10.1016/j.jelechem.2023.117417 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85151733857&doi=10.1016%2fj.jelechem.2023.117417&partnerID=40&md5=a033923ea549d480ee8d2071245084a4
Mariella Babu A., CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Varghese A., CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India
A Systemic Review on Omicron Variant of SARS-CoV-2
Entry mechanism; Omicron; SARS-CoV-2 Variant
As the new strains spread around the world, scientists have been trying to learn more about the different strains, especially Omicron, and how SARS-CoV2 acts in general. Studying historical trends of virus spread and the structure of the virus and its strains, as well as all the mechanisms it needs to survive, can help identify the symptoms and diagnose and treat the disease. The research has shown that the new strains, including Omicron, have a higher rate of mutation and transmissibility. Additionally, due to the rapid spread of the virus, there has not been a significant amount of time to understand the severity of the infection. To better understand the novel variants, a detailed analysis of the basic pathophysiology of the virus is needed. This includes transcriptome analysis for the recombination index to identify variation in the strand. This aided in the diagnostic process, and therapeutics for mutants of the virus could be treated. The Omicron strain is particularly threatening due to its rapid transmission rate and its property of immune evasion, which can make it less vulnerable to vaccination. 2023 Biomedical & Pharmacology Journal.
Biomedical and Pharmacology Journal, Vol-16, No. 2, pp. 661-671.
https://doi.org/10.13005/bpj/2648 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85165652720&doi=10.13005%2fbpj%2f2648&partnerID=40&md5=e82815685760ffcd14f527573ea0675a
Pappuswamy M., Department of Life Sciences, CHRIST (Deemed to Be University), Karnataka, Bangalore, India; Chaudhary A., Department of Life Sciences, CHRIST (Deemed to Be University), Karnataka, Bangalore, India; Shitut A., Department of Life Sciences, CHRIST (Deemed to Be University), Karnataka, Bangalore, India
Processing of nanoreinforced aluminium hybrid metal matrix composites and the effect of post-heat treatment: a review
Heat treatment; Hybrid composites; Manufacturing of nanocomposites; Nanoreinforcements; Powder metallurgy; Precipitation hardening
The demand for cutting-edge materials with a high strength-to-weight ratio and economic considerations is steadily increasing. Lightweight materials such as aluminium (Al) and its alloys are attractive, but some properties such as low thermal stability and high wear rate limit the application of aluminium alloys (AA) to some extent. Many researchers have developed various composites to get around these restrictions and increase the performance of aluminium and its alloy. Metal matrix composites (MMCs) with nanoparticles have revealed greater mechanical and tribological properties compared with micron-sized reinforcements. Most engineering applications require materials with excellent multidimensional properties, which are difficult to achieve using single reinforced MMCs. Hybrid metal matrix composites (HMMCs) with superior properties are the latest trends in composite technology. The choice of reinforcement selection has a vibrant role in the manufacturing of hybrid metal matrix composites. Researchers face a major challenge in finding optimum reinforcement combinations and their corresponding concentrations. The manufacturing of nanocomposites is difficult due to their high surface area and energy. To determine the most effective reinforcement combinations for hybrid composites, this article addresses several nanoreinforcements, their effects, and the appropriate processing methods for aluminium and its alloys. Researchers have paid less attention to the impact of precipitation hardening in aluminium and its alloys; thus, this paper also considers the effect of post-heat treatment ofaluminium composites. 2022, King Abdulaziz City for Science and Technology.
Menachery N.; Thomas S.; Deepanraj B.; Senthilkumar N.
Applied Nanoscience (Switzerland), Vol-13, No. 6, pp. 4075-4099.
Menachery N., Department of Mechanical Engineering, School of Engineering and Technology, CHRIST (Deemed to be University), Bangalore, 560074, India, Department of Mechanical Engineering, Jyothi Engineering College, Kerala, Thrissur, 679531, India; Thomas S., Department of Mechanical Engineering, School of Engineering and Technology, CHRIST (Deemed to be University), Bangalore, 560074, India; Deepanraj B., Department of Mechanical Engineering, Jyothi Engineering College, Kerala, Thrissur, 679531, India, Department of Mechanical Engineering, College of Engineering, Prince Mohammad Bin Fahd University, Al Khobar, 31952, Saudi Arabia; Senthilkumar N., Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Chennai, 602105, India
Photoaligned Liquid Crystalline Structures for Photonic Applications
lenses; liquid crystals; phase modulation; photoalignment; photonics; photopatterning; sensors; waveguides
With the advancement of information display technologies, research on liquid crystals is undergoing a tremendous shift to photonic devices. For example, devices and configurations based on liquid crystal materials are being developed for various applications, such as spectroscopy, imaging, and fiber optics. One of the problems behind the development of photonic devices lies in the preparation of patterned surfaces that can provide high resolution. Among all liquid crystal alignment techniques, photoalignment represents a promising non-contact method for the fabrication of patterned surfaces. In this review, we discuss the original research findings on electro-optic effects, which were mainly achieved at the Department of Electronic and Computer Engineering of the Hong Kong University of Science and Technology and the collaborating research laboratories. 2023 by the authors.
Kudreyko A.; Chigrinov V.; Hegde G.; Chausov D.
https://doi.org/10.3390/cryst13060965 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85163867368&doi=10.3390%2fcryst13060965&partnerID=40&md5=84dea07e2a9513f4e088c734ed014828
Kudreyko A., Department of Medical Physics and Informatics, Bashkir State Medical University, Ufa, 450008, Russian Federation, Department of General Physics, Ufa University of Science and Technology, Ufa, 450076, Russian Federation; Chigrinov V., Laboratory of Molecular Electronics, South Ural State University, Chelyabinsk, 454080, Russian Federation, Department of Electronic and Computer Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, 999077, Hong Kong, Nanjing Jingcui Optical Technology Co., Ltd., Nanjing, 211135, China; Hegde G., Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Hosur Road, Bengaluru, 560029, India; Chausov D., Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, 119991, Russian Federation, Moscow University for Industry and Finance Synergy, Moscow, 105318, Russian Federation
A fast survey on recent developments in designing colorimetric and fluorescent sensors for the selective detection of essential amino acids
Owing to the biological significance of various amino acids, developing accurate and cost-effective sensing techniques for the selective detection of amino acids has recently attracted growing interest. This review discusses the recent advancements of chemosensors in the selective detection of only essential amino acids out of a total of twenty amino acids, which have been applied in chemosensing research, and the mechanism of their action. The focus is directed towards the detection of the most important essential amino acids, like leucine, threonine, lysine, histidine, tryptophan and methionine, since isoleucine and valine are yet to be explored in regard to chemosensing. According to their chemical and fluorescence properties, different sensing techniques, such as the reaction-based approach, DNA-based sensors, nanoparticle formation, coordination ligand binding, host-guest chemistry, the fluorescence indicator displacement (FID) approach, electrochemical sensors, carbon dot-based sensors, MOF-based sensors and metal-based techniques, have been described. 2023 The Royal Society of Chemistry.
Rao N.P.; Vaishnavi C.M.; Kumar M.S.; Vishnu S.; Mukherjee B.; Karthik N.; Dutta G.; Das A.K.
Analytical Methods, Vol-15, No. 21, pp. 2546-2577.
https://doi.org/10.1039/d3ay00155e https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160394884&doi=10.1039%2fd3ay00155e&partnerID=40&md5=ba6528d23b18fe97f94713674539f9e0
Rao N.P., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Karnataka, Bangalore, 560029, India; Vaishnavi C.M., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Karnataka, Bangalore, 560029, India; Kumar M.S., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Karnataka, Bangalore, 560029, India; Vishnu S., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Karnataka, Bangalore, 560029, India; Mukherjee B., Nano-Biosensors and Biodevices Lab, School of Medical Sciences and Technology, Indian Institute of Technology, West Bengal, Kharagpur, India; Karthik N., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Karnataka, Bangalore, 560029, India; Dutta G., Nano-Biosensors and Biodevices Lab, School of Medical Sciences and Technology, Indian Institute of Technology, West Bengal, Kharagpur, India; Das A.K., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Karnataka, Bangalore, 560029, India
Elusive Justice to Dalits in the 'Land of Social Justice'
The recent inhuman incident of mixing human faeces in the overhead tank supplying water to Dalit colony in Vengaivayal village in Pudukkottai district of Tamil Nadu refl ects the perpetuating violence against the Dalits. Locating this brutal violence within the larger framework of violence against Dalits in Tamil Nadu, the lackadaisical attitude of Dravidian parties when dealing with the issues related to Dalits is brought to the fore.. 2023 Economic and Political Weekly. All rights reserved.
Economic and Political Weekly, Vol-58, No. 23, pp. 17-19.
Lakshmanan C., Christ University, Bengaluru, India; Sethuraman V., Christ University, Bengaluru, India
Unveiling Cutting Edge Innovations in the Catalytic Valorization of Biodiesel Byproduct Glycerol into Value Added Products
Glyceric acid; Glycerol carbonate; Glycidol; Lactic acid; Solketal
The increasing production of biodiesel has led to a glut in the production of glycerol, which is a byproduct. This has resulted in the quest for alternative applications using glycerol as a cheap and readily available starting material. One promising approach is the catalytic valorization of glycerol, which converts glycerol into valuable chemicals such as 1,2-propanediol, lactic acid, and acrolein. The glycerol formed affects the efficiency of the biodiesel, and hence it must be removed. Different processes can convert glycerol to various useful products like glycerol carbonate, glycidol, solketal, lactic acid, and glyceric acid. These different products, the processes used for synthesis, and the various catalysts used have been discussed. The most effective methods for the syntheses, the numerous catalyst systems, mechanisms of the reactions, and applications of these products in different fields are discussed in this review. The paper also discusses the challenges and opportunities of glycerol valorization, including the need for improved catalyst selectivity and activity and the potential for integrating glycerol valorization with other biorefinery processes. Overall, the catalytic valorization of glycerol offers a promising pathway for utilizing this abundantly available resource, and this review provides valuable insights for researchers and practitioners working in this area. 2023 Wiley-VCH GmbH.
Mohan K.; Pai S.D.K.R.; Reghunath B.S.; Pinheiro D.
https://doi.org/10.1002/slct.202204501 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85165495210&doi=10.1002%2fslct.202204501&partnerID=40&md5=d27c882557f8739d21d857059d8793dc
Mohan K., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Pai S.D.K.R., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Reghunath B.S., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Pinheiro D., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India
Photocatalytic seawater splitting for hydrogen fuel production: impact of seawater components and accelerating reagents on the overall performance
The future fuel, hydrogen, is a clean, sustainable energy source with a substantial density of energy per unit volume/weight. Breakthroughs in hydrogen production, storage, and transportation are essential to meet the sustainable global energy demands. Solar-to-hydrogen conversion through water-splitting reactions (via photo/electro/photoelectro-processes) is a promising strategy for producing green hydrogen fuel. Specifically, the photocatalytic hydrogen generation reaction, mimicking artificial photosynthesis, is a simple and cost-effective method adopted for solar-hydrogen production. Various semiconductor photocatalysts and hybrid photocatalytic systems have been developed to address the sluggish kinetics and selectivity of pristine water/seawater splitting reactions. Recently, seawater has been used as feedstock for large-scale hydrogen production to advance the field and alleviate the scarcity of freshwater sources. This review article, therefore, aims to highlight the importance of seawater splitting reactions using different photocatalytic systems. A brief introduction to the fundamentals, historical progress, and mechanism of the seawater splitting reaction is presented. The impact of seawater components and accelerating reagents on the intrinsic performance of water splitting catalysts is discussed in detail, followed by an elaborate discussion of natural water and artificial seawater splitting with emphasis on onerous photocatalyst designs. Finally, the current challenges and opportunities of saltwater electrolysis for sustainable hydrogen fuel generation and applications are discussed. 2023 The Royal Society of Chemistry.
Yesupatham M.S.; Augustin A.; Agamendran N.; Honnappa B.; Shanmugam M.; Sagayaraj P.J.J.; Thennarasu G.; Sagaya Selvam N.C.; Sekar K.
Sustainable Energy and Fuels, Vol-7, No. 19, pp. 4727-4757.
https://doi.org/10.1039/d3se00810j https://www.scopus.com/inward/record.uri?eid=2-s2.0-85170237371&doi=10.1039%2fd3se00810j&partnerID=40&md5=fe2c56e710b053bd903a76d27ff5fcc4
Yesupatham M.S., Sustainable Energy and Environmental Research Laboratory, Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, Tamil Nadu, Kattankulathur, 603203, India; Augustin A., Sustainable Energy and Environmental Research Laboratory, Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, Tamil Nadu, Kattankulathur, 603203, India; Agamendran N., Sustainable Energy and Environmental Research Laboratory, Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, Tamil Nadu, Kattankulathur, 603203, India; Honnappa B., Department of Physics and Nanotechnology, SRM Institute of Science and Technology, Tamil Nadu, Kattankulathur, 603203, India; Shanmugam M., Sustainable Energy and Environmental Research Laboratory, Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, Tamil Nadu, Kattankulathur, 603203, India; Sagayaraj P.J.J., Sustainable Energy and Environmental Research Laboratory, Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, Tamil Nadu, Kattankulathur, 603203, India; Thennarasu G., Department of Chemistry, C. Kandaswami Naidu College for Men (A Unit of Pachaiyappa's Trust), Chennai, 600102, India; Sagaya Selvam N.C., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Sekar K., Sustainable Energy and Environmental Research Laboratory, Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, Tamil Nadu, Kattankulathur, 603203, India
A review of cobalt-based catalysts for sustainable energy and environmental applications
CO2 reduction; Cobalt catalyst; Environment purification; Hydrogen evolution reaction; Oxygen evolution reaction
In a bid to tackle the degrading climate conditions, the new age research in catalysis is predominantly focused on sustainable technologies associated with renewable energy conversion and environment purification. One of the primary motivations for the research in catalysis is the use of low-cost, earth-abundant materials that can fulfill the scale-up needs of respective technologies. Cobalt (Co) based catalysts have been an indispensable part of almost all areas of catalysis and they are often looked at as low-cost substitutes for precious metal-based catalysts. In the context of energy and environmental applications, Co-based catalysts are more commonly used for reactions such as hydrogen evolution reaction (HER), oxygen evolution reaction (OER), hydrolysis of chemical hydrides, CO2 reduction reaction (CO2RR) and advanced oxidation processes (AOPs). Co-based catalysts are interesting compounds as Co plays a diverse role in facilitating different reactions. This review provides a brief account of the significance of Co-based catalysts and elaborates their advancement in each of the above-mentioned applications and presents future research directions with the use of Co-based catalysts. An in-depth analysis to gain a deeper understanding of the Co-based systems is highly desired to promote breakthroughs in catalysis. 2023 The Authors
Gupta S.; Fernandes R.; Patel R.; Spreitzer M.; Patel N.
All Open Access; Hybrid Gold Open Access
https://doi.org/10.1016/j.apcata.2023.119254 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85159213230&doi=10.1016%2fj.apcata.2023.119254&partnerID=40&md5=92bdf984155eeb2550109012fd7c6c81
Gupta S., Advanced Materials Department, Joef Stefan Institute, Ljubljana, 1000, Slovenia; Fernandes R., Department of Physics and Electronics, Christ University, Karnataka, Bengaluru, 560029, India; Patel R., Department of Physics and Electronics, Christ University, Karnataka, Bengaluru, 560029, India; Spreitzer M., Advanced Materials Department, Joef Stefan Institute, Ljubljana, 1000, Slovenia; Patel N., Department of Physics and Electronics, Christ University, Karnataka, Bengaluru, 560029, India
Lignin-based nanomaterials for food and pharmaceutical applications: Recent trends and future outlook
Antioxidant activity; Drug delivery; Lignin; Nanolignin; Nutrient delivery
Small particles of size ranging from 1 to 100 nm are referred to as nanoparticles. Nanoparticles have tremendous applications in various sectors, including the areas of food and pharmaceutics. They are being prepared from multiple natural sources widely. Lignin is one such source that deserves special mention due to its ecological compatibility, accessibility, abundance, and low cost. This amorphous heterogeneous phenolic polymer is the second most abundant molecule in nature after cellulose. Apart from being used as a biofuel source, lignin is less explored for its potential at a nano-level. In plants, lignin exhibits cross-linking structures with cellulose and hemicellulose. Numerous advancements have taken place in synthesizing nanolignins for manufacturing lignin-based materials to benefit from the untapped potential of lignin in high-value-added applications. Lignin and lignin-based nanoparticles have numerous applications, but in this review, we are mainly focusing on the applications in the food and pharmaceutical sectors. The exercise we undertake has great relevance as it helps scientists and industries gain valuable insights into lignin's capabilities and exploit its physical and chemical properties to facilitate the development of future lignin-based materials. We have summarized the available lignin resources and their potential in the food and pharmaceutical industries at various levels. This review attempts to understand various methods adopted for the preparation of nanolignin. Furthermore, the unique properties of nano-lignin-based materials and their applications in fields including the packaging industry, emulsions, nutrient delivery, drug delivery hydrogels, tissue engineering, and biomedical applications were well-discussed. 2023 Elsevier B.V.
Abraham B.; Syamnath V.L.; Arun K.B.; Fathima Zahra P.M.; Anjusha P.; Kothakotta A.; Chen Y.-H.; Ponnusamy V.K.; Nisha P.
Science of the Total Environment, Vol-881
ISSN: 489697; PubMed ID: 37028661; CODEN: STEVA
https://doi.org/10.1016/j.scitotenv.2023.163316 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85152624852&doi=10.1016%2fj.scitotenv.2023.163316&partnerID=40&md5=6578fc78fc9bfb98d12ff6927fc3421f
Abraham B., Agro Processing and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Council of Scientific and Industrial Research, Trivandrum, 695019, India, Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India, Research Center for Precision Environmental Medicine, Kaohsiung Medical University (KMU), Kaohsiung City, 807, Taiwan; Syamnath V.L., Agro Processing and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Council of Scientific and Industrial Research, Trivandrum, 695019, India; Arun K.B., Department of Life Sciences, Christ (Deemed to be University), Bangalore, 29, India; Fathima Zahra P.M., College of Agriculture, Vellayani, Kerala Agricultural University, India; Anjusha P., College of Agriculture, Vellayani, Kerala Agricultural University, India; Kothakotta A., Agro Processing and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Council of Scientific and Industrial Research, Trivandrum, 695019, India, Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India; Chen Y.-H., Division of Gastroenterology, Department of Internal Medicine, Kaohsiung Medical University Hospital, Kaohsiung Medical University, Kaohsiung City, Taiwan; Ponnusamy V.K., Research Center for Precision Environmental Medicine, Kaohsiung Medical University (KMU), Kaohsiung City, 807, Taiwan, Department of Medicinal and Applied Chemistry, Kaohsiung Medical University (KMU), Kaohsiung City, 807, Taiwan, Department of Medical Research, Kaohsiung Medical University Hospital (KMUH), Kaohsiung City, 807, Taiwan, Department of Chemistry, National Sun Yat-sen University (NSYSU), Kaohsiung City, 804, Taiwan, Ph.D. Program of Aquatic Science and Technology, College of Hydrosphere Science, National Kaohsiung University of Science and Technology (NKUST), Kaohsiung City, 811, Taiwan; Nisha P., Agro Processing and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Council of Scientific and Industrial Research, Trivandrum, 695019, India, Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India
Nutrition paves the way to environmental toxicants and influences fetal development during pregnancy
Diet; Heavy metals; Neurodevelopment; Preeclampsia; Pregnancy nutrients; Toxic chemicals
Nutrition plays a major role in the healthy pregnancy and development of the fetus. In addition, nutrition can expose humans to a wide range of potentially hazardous environmental constituents, such as organic pollutants and heavy metals from marine or agricultural food products while processing, producing, and packaging. Humans constantly face these constituents through air, water, soil, food, and domestic products. During pregnancy, the rate of cellular division and differentiation is higher; exposure to any of these environmental toxicants can lead to developmental defects as they cross the placental barrier and, in some cases, can harm the successive generation too, as some contaminants can act on the reproductive cells of the fetus (Diethylstilbestrol). Pregnant women are considered a vulnerable population to food contaminant exposure and require a proper dietary chart and conscious food choices. Food is a source of both essential nutrients and environmental toxicants. Here, we have researched the possible toxicants of the food industry and their influence on the fetus's in-utero development, along with the importance of dietary interventions and the need to balance a healthy diet to overcome the harms. The cumulative exposure to environmental toxicants can influence the mother's prenatal environment and affect the fetus's development. 2023
Meyyazhagan A.; Kuchi Bhotla H.; Tsibizova V.; Pappuswamy M.; Chaudhary A.; Arumugam V.A.; Al Qasem M.; Di Renzo G.C.
Best Practice and Research: Clinical Obstetrics and Gynaecology, Vol-89
https://doi.org/10.1016/j.bpobgyn.2023.102351 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85161346669&doi=10.1016%2fj.bpobgyn.2023.102351&partnerID=40&md5=72d8ef850c96eecf7bc23a4a1f2ffa30
Meyyazhagan A., Perinatology Research Branch, Wayne State University, Detroit, United States, Centre of Perinatal and Reproductive Medicine, University of Perugia, Perugia, Italy, Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Kuchi Bhotla H., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Tsibizova V., Department of Obstetrics and Gynecology, IM Sechenov First State University, Moscow, Russian Federation, Almazov National Medical Research Centre, St Petersburg, Russian Federation, PREIS International School, Firenze, Italy; Pappuswamy M., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Chaudhary A., Department of Life Sciences, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Arumugam V.A., Department of Human Genetics and Molecular Biology, Bharathiar University, Tamil Nadu, Coimbatore, 641046, India; Al Qasem M., Department of Obstetrics and Gynecology, Faculty of Medicine, Mutah University, Al-Karak, Jordan; Di Renzo G.C., Perinatology Research Branch, Wayne State University, Detroit, United States, Centre of Perinatal and Reproductive Medicine, University of Perugia, Perugia, Italy, Department of Obstetrics and Gynecology, IM Sechenov First State University, Moscow, Russian Federation, Almazov National Medical Research Centre, St Petersburg, Russian Federation, PREIS International School, Firenze, Italy
From Waste to Strength: Unveiling the Mechanical Properties of Peanut-Shell-Based Polymer Composites
biodegradability; biomass; mechanical properties; peanut shell; polymer composites; surface modification; sustainability
Peanut-shell-based polymer composites have gained significant attention as sustainable and cost-effective materials with potential applications as food packaging films, ceiling tiles, insulation panels, supercapacitors, and electrodes in various industries like the packaging industry, construction, furniture, and electronics. This review article presents a systematic roadmap of the mechanical properties of peanut-shell-based polymer composites, analyzing the influence of factors such as filler content, surface modification techniques, interfacial adhesion, and processing methods. Through an extensive literature review, we highlight the mechanical properties of peanut-shell-based polymer composites. Furthermore, challenges and ongoing research efforts in this field are discussed. This comprehensive review provides valuable insights for researchers, industry professionals, and policymakers, promoting the development and utilization of peanut-shell-based polymer composites for various applications. 2023 by the authors.
Mandala R.; Hegde G.; Kodali D.; Kode V.R.
Journal of Composites Science, Vol-7, No. 8
Multidisciplinary Digital Publishing Institute (MDPI)
https://doi.org/10.3390/jcs7080307 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85169098996&doi=10.3390%2fjcs7080307&partnerID=40&md5=c745c03ae970aa50ab03a04068bc61f0
Mandala R., Department of Mechanical Engineering, Vignan Institute of Technology & Science, Deshmukhi, Telangana, Hyderabad, 508284, India; Hegde G., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India, Centre for Advanced Research and Development, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Kodali D., Department of Mechanical Engineering, Christian Brothers University, Memphis, 38104, TN, United States; Kode V.R., Department of Chemical and Biochemical Engineering, Christian Brothers University, Memphis, 38104, TN, United States
Recent Trends and Progress in Corrosion Inhibitors and Electrochemical Evaluation
corrosion; corrosion efficiency; electrochemical; inhibitors; self-healing
Science and engineering research studies are currently concentrating on synthesizing, designing, producing, and consuming ecologically benign chemical species to replace harmful chemicals. This is due to the increasing demands of conservation knowledge and strict ecological regulations. Numerous environmentally friendly substitutes produced from natural resources, including biopolymers, plant extracts, chemical pharmaceuticals (drugs), and so on, are now frequently used as inhibitors to replace dangerous corrosion inhibitors. Many compounds have been extensively used. A range of methods, including physisorption, chemisorption, barrier protection, thin-film growth, and electrochemical procedures, will be used to provide corrosion resistance. The various kinds of corrosion inhibitors (CIs), the mechanisms underlying inhibition, and the evaluation procedures have all been covered in-depth. This review provides an overview of the relevant literature in which researchers and scientists used different types of CIs, the effect of CIs on metals, and information about designs and mechanisms used to minimize corrosion in a variety of equipment composed of alloys or metals, along with electrochemical evaluation studies. This review will provide scholars with fresh insights to advance the discipline. 2023 by the authors.
Bijapur K.; Molahalli V.; Shetty A.; Toghan A.; De Padova P.; Hegde G.
Applied Sciences (Switzerland), Vol-13, No. 18
https://doi.org/10.3390/app131810107 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85172918218&doi=10.3390%2fapp131810107&partnerID=40&md5=069af0e2d4e7d7c908b3f705e9e1b17b
Bijapur K., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Bangalore, 560076, India; Molahalli V., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Bangalore, 560076, India; Shetty A., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Bangalore, 560076, India; Toghan A., Chemistry Department, Faculty of Science, South Valley University, Qena, 83523, Egypt, Chemistry Department, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, 11623, Saudi Arabia; De Padova P., CNR-Istituto di Struttura della Materia, Via Fosso del Cavaliere, 100, Roma, 00133, Italy, INFN-LNF, Via E. Fermi, 54, Frascati, 00040, Italy; Hegde G., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Bangalore, 560076, India