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Green Synthesis and Application of Copper-Based Nanomaterials
A vital aspect of nanoscience and nanotechnology is the synthesis of nanomaterials and nanostructures. Although nanotechnology is a relatively new field of study, nanomaterials have been used in industry for years. Synthesis of nanomaterials is an essential area due to its significant characteristics and is ideally suited for applications in a multiple discipline. Metal and metal-based nanoparticles play a major role across all disciplines, making up the majority of all nanomaterials. Among these, copper-based nanomaterials have drawn a lot of curiosity considering their varied features and wide range of uses in numerous sectors, particularly in nanotechnology for healthcare and biomedical fields. Synthesis of copper-based nanomaterials can be achieved by several approaches such as physical, chemical, biological methods. Among these approaches, synthesizing nanomaterials through biological processes is the most affordable and environmentally responsible method. This chapter aims to share details on green synthesis of copper-based nanomaterials obtained from different sources and utilized in a broad range of industries including electronics, agriculture, biomedicine, and manufacturing. 2024 American Chemical Society. -
Low-cost bio-waste carbon nanocomposites for sustainable electrochemical devices: A systematic review
Innovative brains have always drawn inspiration from nature while creating new designs. Animals and plants offer a variety of structures that are stronger, have higher energy sorption capacities, and have lower densities. These structures can inspire the creation of new, functional designs. Scientists have created structures by drawing inspiration from biological structures seen in nature. These structures have been demonstrated to significantly outperform conventional structures for use in the environmental and energy sectors. Due to their simple synthesis, adaptability, excellent performance, and variety of uses, including in light-harvesting systems, batteries, catalysis, bio-fuels, water, and air purification, and environmental monitoring, bio-fabricated materials have demonstrated several advantages. However, sensitive fabrication tools that can create bio-inspired structures and scale up manufacturing from laboratory-scale synthesis are urgently needed. A quick rundown of recent developments in bionanomaterials for different electrochemical systems, particularly the extensively researched rechargeable batteries, sensors, and supercapacitors, provided a discussion of the design principles for bionanomaterials, synthesis, and strategies for low-cost bio-inspired nanomaterial synthesis and device integration. A quick overview of the future research priorities is then suggested, followed by a critical analysis of the current problems. This review is anticipated to provide some understanding of biowaste-nanocomposites for electrochemical applications by taking cues from nature. 2024 Elsevier Ltd -
Properties, Synthesis, and Characterization of Cu-Based Nanomaterials
Copper-based nanomaterials offer a fascinating array of properties that make them pivotal in various technological applications. These materials, when scaled down to the nanoscale, exhibit enhanced electrical conductivity, surpassing their bulk counterparts. This book chapter primarily focuses on the properties, synthesis, and characterization of copper nanoparticles while also discussing metal and metal oxide nanoparticles. Their large surface-to-volume ratios enable efficient electron transport, making them valuable components in electronics and conductive inks for flexible devices. Furthermore, copper nanomaterials possess exceptional thermal conductivity, making them crucial for efficient heat management in electronics and advanced thermal interface materials. Copper and copper oxide have positive economic and environmental effects. Their catalytic properties render them important in diverse chemical reactions and as components in energy storage systems like batteries and supercapacitors. Additionally, the tunability of their optical properties makes them suitable for various photonic and optoelectronic applications, ranging from sensors to light-emitting devices. The multifaceted properties of copper-based nanomaterials continue to drive innovation across a broad spectrum of industries. 2024 American Chemical Society. -
Biomass-Based Functional Carbon Nanostructures for Supercapacitors
For the creation of next-generation biocompatible energy technologies, it is urgently necessary to examine environmentally acceptable, low-cost electrode materials with high adsorption, rapid ion/electron transit, and programmable surface chemistry. Because of their wide availability, environmentally friendly nature, and affordability, carbon electrode materials made from biomass have received a lot of interest lately. The biological structures they naturally possess are regular and accurate, and they can be used as templates to create electrode materials with precise geometries. The current study is primarily concerned with recent developments in research pertaining to biomass-derived carbon electrode materials for supercapacitor applications, including plant, fruit, vegetable, and microorganism-based carbon electrode materials. Also provided is a summary of alternative synthesis methods for the conversion and activation of biomass waste. 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
Risks and ethics of nanotechnology: an overview
Environmental nanotechnology is thought to be important to current environmental engineering and scientific techniques. The biomedical, textile, aerospace, manufacturing, cosmetics, oil, defense, agricultural, and electronics industries can all benefit from the use of nanotechnology to enhance a wide range of material properties, including physical, chemical, and biological properties. However, nanotechnology-based products or nanomaterials (e.g., nanofibers, nanowires, nanocomposites, and nanofilms) may be harmful to human health. Since nanomaterials are usually manufactured using novel manufacturing techniques and have a variety of sizes, shapes, and surface energies, there can also be uncertainties in their manufacture and handling. This chapter provides a detailed account of ethical issues related to nanotechnology, particularly environmental toxicity, risk management, health risk evolution, and environmental significance of nanomaterials. In addition, environmental challenges, toxic effect of nanoparticles on the environment, ethics of nanotechnology, and social, ecological, biological, and other legal issues are highlighted. The potential of nanomaterials in environmental remediation and their use in environmental protection is also emphasized. 2023 Elsevier Inc. All rights reserved. -
Renewable Musa Sapientum derived porous nano spheres for efficient energy storage devices
Biomass-based carbonaceous materials derived from Musa Sapientum have gained much attention in recent years for their application in energy storage devices, especially supercapacitors. In the present work, we synthesized carbonaceous material from banana peel as the biomass precursor by using a pyrolysis method carried out at various temperatures (600, 800, and 1000 C). The characterization of the prepared carbonaceous materials BP600, BP800 and BP1000 was done by using different characterization techniques such as FTIR, XRD, FE-SEM, and TEM, studies. The electrochemical study of the synthesized material was carried out by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) electrochemical impedance spectroscopy (EIS). The supercapacitive performance of the material was studied using a 3-electrode system with 3M KOH as an electrolyte. As a result, the BP600 exhibited a better specific capacitance with higher energy and power densities along with a maximum cyclic stability of 16,000 cycles. To show the practical applicability of the material BP 600, two electrode system studies were carried out as well, which showed preferentially good values for specific capacitance with appreciable power and energy density values. The study provides us with a green approach for the fabrication of non-toxic, low-cost, and environmentally friendly potential porous carbonaceous electrode materials by converting bio-waste into a clean and renewable source of energy. 2024 The Author(s). Published by IOP Publishing Ltd. -
Zinc oxide/tin oxide nanoflower-based asymmetric supercapacitors for enhanced energy storage devices
Research on energy storage devices has focused on improving asymmetric supercapacitors (ASCs) by utilizing two different electrode materials. In this work, we have successfully prepared a unique material, ZnO/SnO2 nanoflower, via the hydrothermal method. Graphene oxide (GO) was synthesized by applying the modified Hummers' technique. The ZnO/SnO2 nanoflower was deposited on a polypyrrole (PPY) nanotube/graphene oxide composite (ZS/GP) in two steps: in situ chemical polymerization, followed by a hydrothermal method. Electrochemical properties of the prepared material nanocomposite were analyzed by applying cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) techniques. An asymmetric supercapacitor (ASC) was constructed using ZS/GP nanocomposite as the positive electrode and Caesalpinia pod-based carbonaceous material as the negative electrode material, and its performance was investigated. As a result, the fabricated ASCs were found to have an excellent specific capacitance of 165.88 F g?1 at 1.4 V, with an energy density of 5.12 W h kg?1 and a power density of 2672 W kg?1. The prepared nanocomposite material for the ASC showed a cycle stability of 17k cycles at a current density of 5 A g?1. This study revealed that the electrode material ZS/GP nanocomposite is highly suitable for supercapacitor applications. The ASC device's extended cycle life experiments for 17k cycles produced a coulombic efficiency of 97% and a capacitance retention of 73%, demonstrating the promising potential of the electrode materials for greener as well as efficient energy storage applications while converting abundant bio waste into effective energy. 2024 The Royal Society of Chemistry. -
Turning mango kernel waste into high-energy porous carbon: a sustainable electrode material for high-performance supercapacitors with exceptional stability
This study explores the sustainable production of high-performance supercapacitor electrodes from waste mango kernels, addressing the growing need for eco-friendly energy storage solutions. Porous carbon materials were synthesized via pyrolysis at varying temperatures (700, 800, 900, and 1000 C), designated as MK7, MK8, MK9, and MK10, respectively. The synthesized carbon was obtained via a simple and eco-friendly carbonization, yielding a highly porous structure with a large specific surface area of 1348.9 m2 g?1, for MK9 material as confirmed by BET analysis. Raman spectroscopy revealed a high degree of graphitization with D and G bands, indicating the presence of both disordered and graphitic carbon domains. SEM imaging showed a well-developed, interconnected porous morphology, while XRD patterns confirmed the amorphous nature with partially crystalline domains. The resulting carbon materials were evaluated for their electrochemical performance in supercapacitor applications. Electrochemical characterization revealed that the MK9 sample, pyrolyzed at 900 C, exhibited the highest specific capacitance of 205.8 F g?1, surpassing the performance of the other samples. To optimize device performance, symmetric supercapacitors were fabricated using a CR2032 coin cell configuration with different electrolytes and concentrations. The KOH electrolyte device demonstrated a maximum power density of 5137.86 W kg?1, an energy density of 12.32 W h kg?1, and a specific capacitance of 112.4 F g?1. Furthermore, this device exhibited excellent cycling stability, maintaining its performance over 100 000 galvanostatic charge-discharge cycles. A practical demonstration showed the ability of the device to power a red LED for approximately 15 minutes. These results highlight the potential of utilizing waste biomass, specifically mango kernels, for sustainable and efficient supercapacitor development. 2025 The Royal Society of Chemistry. -
Carbon Nanodots: Application in Drug Delivery and Bioimaging
Carbon nanodots (CNDs), the newest member of the carbon-based nanomaterial family, are also among the most promising for the development of unique, cutting-edge applications. They are regarded as a rising star among nanomaterials due to their singular and unmatched physicochemical and photoluminescent capabilities. Numerous applications built on CNDs have been created during the past 10 years. Carbon dots exhibit ease of functionalization, biocompatibility, nontoxicity, photostability, and favorable photoluminescence and water solubility properties. Due to these distinctive characteristics, they find extensive applications in live cell imaging, catalysis, electronics, biosensing, power systems, targeted drug delivery, and various other biomedical fields. This chapter examines the most recent advancements in carbon dot nanomedicine, including their application as imaging agents and drug transporters. Springer Nature Singapore Pte Ltd. 2025. -
Functionalized Nanomaterials in Nanobiomedicines and Diagnostic Devices
The development of nanomaterials for biomedical applications over the last 20 years has shown great potential for altering the way that all facets of illness management are thought to be approached. Since nanomaterials may be customized to incorporate features for early diagnosis, medication delivery, therapy, treatment, and patient response monitoring, they are particularly appealing as a system. The realm of functionalized nanomaterials is characterized by its diversity and rapid evolution, with ongoing research endeavors focused on discovering novel functionalities and applications for nanoscale materials. Functionalized nanomaterials play a pivotal role in nanobiomedicines and diagnostic devices, contributing significantly to advancements in these fields. The use of functionalized nanomaterials varies from cancer therapy, drug delivery, cosmetics, and medical use to various other entities. Therefore, this chapter reviews the fundamentals of nanomaterials fictionalization, surface fictionalization, and different nanomaterials that are contributing to drug delivery and diagnostic devices. Springer Nature Singapore Pte Ltd. 2025. -
An Efficient Multi-Modal Classification Approach for Disaster-related Tweets
Owing to the unanticipated and thereby treacherous nature of disasters, it is essential to gather necessary information and data regarding the same on an urgent basis; this helps to get a detailed overview of the situation and helps humanitarian organizations prioritize their tasks. In this paper, "An Efficient Multi-Modal Classification Approach for Disaster-related Tweets,"the proposed framework based on Deep Learning to classify disaster-related tweets by analyzing text and image contents. The approach is based on Gated Recurrent Unit (GRU) and GloVe Embedding for text classification and VGG-16 network for image classification. Finally, a combined model is proposed using both text and image modules by the Late Fusion Technique. This portrays that the proposed multi-modal system performs significantly well in classifying disaster-related content. 2022 IEEE. -
Tracing the outer disk of NGC300: An ultraviolet view
We present an ultra-violet (UV) study of the galaxy NGC300 using GALEX far-UV (FUV) and near-UV (NUV) observations. We studied the nature of UV emission in the galaxy and correlated it with optical, HI and mid-infrared (3.6 ?m) wavelengths. Our study identified extended features in the outer disk, with the UV disk extending up to a radius of 12 kpc (> 2 R25). We estimated the FUV and NUV disk scale-length as 3.05 0.27 kpc and 2.66 0.20 kpc respectively. The scale-length in FUV is 2.3 times larger than that at 3.6 ?m, and we also find the disk to gradually become flatter from longer to shorter wavelengths. We performed a statistical source subtraction to eliminate the background contaminants and identified 261 unresolved UV sources between the radii 5.3 kpc and 10 kpc (1 ? 2 R25). The identified UV sources show an age range between 1300 Myr with a peak at 25 Myr and a mass range between 10 3M? to 10 6M?, estimated using Starburst99 models. The north-eastern spiral arm is found to be populated by young low mass sources suggesting that the star formation in this spiral arm is a recent phenomenon. The UV emission beyond the R25 radius has contribution from these low mass sources and is extended up to ? 2 R25 radius. We conclude that NGC300 has an extended UV disk, mainly populated by young low mass sources. The star formation rate is measured to be ?0.46M?/yr which is comparable to its near optical twin M33. 2019, Indian Academy of Sciences. -
Categorization of artwork images based on painters using CNN
Artworks and paintings has been an integral part of human civilization since the dawn of the Stone Age. Paintings gives more insight about any subject compared to the scriptures and documents. Archiving of digital form of paintings helps to preserve the artworks of different painters. The anticipated work is aimed for the classification of painters' artworks. The artworks of Foreign & Indian painters are considered for the proposed work. The foreign painters' artworks are obtained from [14]. At present, the Indian painters' artwork dataset is not readily available. The images were downloaded from the specific genuine website [13]. Conventional Neural Network is used for Feature learning and classification. Around 20k images of artworks is used for the experiment and got an average accuracy of 85.05%. Published under licence by IOP Publishing Ltd. -
Interpenetrated Robust Metal-Organic Framework with Urea-Functionality-Decked Pores for Selective and Ultrasensitive Detection of Antibiotics and Oxo-anions
Conjoining the benefits of structural diversity and deliberate implantation of task-specific sites inside the porous channels, metal-organic frameworks (MOFs) not only ensure environmental remediation via acute detection of organic as well as inorganic pollutants but also rationalize structure-performance synergies to devise smarter materials with advanced performances. Herein, we report a urea-functionality-grafted Co(II)-framework (UMOF) based on a mixed ligand approach. The 3-fold interpenetrated and [Co2(COO)4N4] building unit-containing structure exhibits high stability and free-carboxamide-site-decorated microporous channels. Assimilation of high-density hydrogen-bond donor groups plus the ?-electron-rich aromatic ligand benefits the UMOF acting as a selective fluoro-sensor for three noxious antibiotics through remarkable quenching, including nitrofurazone (NFT, Ksv: 3.2 104 M-1), nitrofurantoin (NFZ, Ksv: 3.0 104 M-1), and sulfamethazine (SMZ, Ksv: 3.3 104 M-1) with ppb level limits of detection (LODs, NFT: 110.42, NFZ: 97.89, and SMZ: 78.77). The mechanistic insight of luminescence quenching is supported from density functional theory calculations, which endorse the electron-transfer route via portraying variation in the energy levels of the urea group-affixed linker by individual organo-toxins, besides verifying analyte-linker noncovalent interactions. The framework further demonstrates highly discriminative turn-off detection of oxo-anions with extreme low LODs (Cr2O72-: 73.35; CrO42-: 189; and MnO4-: 49.96 ppb). Of note is the reusability of the UMOF toward multicyclic sensing of all the organic and inorganic analytes besides their fast-responsive detection, where variable magnitudes of energy-transfer contributions unequivocally authenticate the turn-off event. 2023 American Chemical Society. -
Spectral and temporal studies of Swift J1658.24242 using AstroSat observations with the JeTCAF model
We present the X-ray spectral and temporal analysis of the black hole X-ray transient Swift J1658.2-4242 observed by AstroSat. Three epochs of data have been analysed using the JeTCAF model to estimate the mass accretion rates and to understand the geometry of the flow. The best-fitting disc mass accretion rate (? d) varies between 0.90+-000102 and 1.09+-000304 M?Edd in these observations, while the halo mass accretion rate changes from 0.15+-000101 to 0.25+-000102 M?Edd. We estimate the size of the dynamic corona that varies substantially from 64.9+-3319 to 34.5+-1250 rg and a moderately high jet/outflow collimation factor stipulates isotropic outflow. The inferred high disc mass accretion rate and bigger corona size indicate that the source might be in the intermediate to soft spectral state of black hole X-ray binaries. The mass of the black hole estimated from different model combinations is ?14 M?. In addition, we compute the quasi-periodic oscillation (QPO) frequencies from the model-fitted parameters, which match the observed QPOs. We further calculate the binary parameters of the system from the decay profile of the light curve and the spectral parameters. The estimated orbital period of the system is 4.0 0.4 h by assuming the companion as a mid or late K-type star. Our analysis using the JeTCAF model sheds light on the physical origin of the spectrotemporal behaviour of the source, and the observed properties are mainly due to the change in both the mass accretion rates and absorbing column density. 2023 The Author(s) Published by Oxford University Press on behalf of Royal Astronomical Society. -
Two-dimensional chromium telluride-coated 3D-printed architectures for energy harvesting
Rapid development of industries, urbanization, and technological advancements have increased demand for sustainable and cost-effective alternative energy sources. In this work, a self-powered flexible 3D-printed triboelectric nanogenerator coated with 2D chromium telluride (Cr2Te3) (3D-TENG) is presented as an innovative energy harvesting approach from pressure and temperature. The optimized flexible 3D-printed hexagonal structures with coatings show varying specific yield strength and porosity. The 3D-TENGs achieved a maximum output voltage of ?39 V under periodic impacts of ~0.8 kPa and their performance further increased (?45 V) in the presence of varied temperatures. The outstanding results and flexibility of the 3D-TENG devices highlight their potential in self-powered energy harvesting from external heat, magnetic fields, and body weight. Density functional theory (DFT) calculations further explained the interaction between 2D Cr2Te3 and the polymer surface under external impact. Therefore, we believe that our findings illustrate the potential of integrating 2D materials with 3D-printed architectures to enhance the efficiency and adaptability of flexible, lightweight, low-cost, and eco-friendly TENG devices for industrial applications. 2025 The Royal Society of Chemistry. -
Exploring cybernetic approaches to sustainable co-working spaces in emerging economies: a sentiment analysis
Purpose In quest of achieving long-term sustainability of co-working spaces (CWSs) and drawing on the cybernetic principles, this study aims to develop a resilient business model promoting economic viability, encouraging environmental responsibility and reinforcing its social impact. Furthermore, to address the transformative shift in way people work in emerging economies, this study probed respondents from India and United Arab Emirates (UAE) and finally identified critical challenges and opportunities bringing in maximum customer satisfaction and achieving long-term business profitability. Design/methodology/approach Using a multi-method qualitative triangulation approach (sentiment analysis), the study collected primary data from India and UAE, analysed through the grounded theory approach. Whereas secondary data in form of tweets was tested using text-mining approach using NVivo. The findings from the dual study were corroborated to identify common dimensions, leading to the development of a hypothetical framework. Findings In CWSs business, dynamic organisation culture holds key in fostering future sustainability, and the study has explored its important antecedents like adaptive management, continuous innovation and technological integration. The impact of these antecedents was found to be moderated by two critical dimensions of regulatory challenges and competitive landscape. Furthermore, the study delved into connecting with the principles of circular economy moderating the impact of dynamic organisation culture towards long-term sustainability of CWSs. Practical implications This study applies cybernetic principles alongside shared and circular economy frameworks to assess consumer perceptions of CWSs. The insights generated can guide researchers, entrepreneurs, urban planners and policymakers in designing flexible business models, strengthening community networks and exploring diverse revenue streams to enhance resilience and long-term growth. Originality/value This research provides empirical evidence on the sustainability dynamics of CWSs, offering a balanced perspective on overcoming challenges and leveraging growth opportunities. Additionally, it bridges the concepts of cybernetics, shared economy and circular economy, presenting a novel framework for ensuring the sustainable development of CWS businesses. 2025 Emerald Publishing Limited -
Fostering cultural vitality and enhancing sustainable urban tourism through international labelling: anethno-morphological exploration
Purpose Cultural Vitality (CV) nurtures creativity, enhances engagement with the local community and supports the art and culture of the place. In quest of exploring the impact of International Labelling (IL) in enhancing CV and reinforcing Sustainable Development (SD), the study pursues a comprehensive Morphological Analysis (MA) and builds a hypothetical framework bridging culture-driven urban tourism with sustainable growth. Design/methodology/approach An ethno-morphological study based on the Durga Puja Festival (India) was adopted to identify the critical dimensions of culture-driven urban tourism. A series of in-depth interviews and cross-sectional studies were carried out to develop a hypothetical research framework for empirical (quantitative) validation thereon. Findings Critical dimensions such as Cultural Investment, Collaborative Partnership and Embracing Glocal Approach were identified as major constructs towards achieving CV of a destination. IL and Responsible Consumption were found to moderate the effect of antecedents and CV upon sustainable growth. Research limitations/implications The present research limits its scope to the geographical boundary within India, keeping cross-boundary research for future study. This study will aid future researchers and scholars in expanding the domain of culture-driven urban tourism. Practical implications The present study bears significance to the urban policymakers, governing bodies, marketers and tour operators in embracing a culture-driven perspective while undertaking a suitable strategy towards developing CV, promoting urban-tourism attributes and vis-vis ensuring its SD. Originality/value This study makes a novel attempt at adopting an ethno-morphological approach and blending culture-driven tourism with sustainable growth while exploring the impact of IL, all together in a research initiative, making it a single-point reference in urban tourism literature. Emerald Publishing Limited -
Investigation on Electrode/Electrolyte Interfaces through Impedance Spectroscopy
In the present paper, impedance measurements of the battery configuration, Anode?lithium borophosphate glass electrolyte?LiCoO2 cathode, has been carried out to throw some light on the electrochemical interfacial behavior between the chosen electrodes and electrolyte. The cathode material, lithium cobalt oxide (LiCoO2) has been prepared by three different techniques and characterized. Sol-gel synthesized LiCoO2 showed uniformly distributed spherical shape particles with an average size of 500 nm and also exhibited better electrochemical performance. Charging and discharging (23 cycles) of the battery indicated an OCV of 2 V. However, the theoretical OCV of 4 V could not be achieved. The poor performance of the battery could be attributed to the electrochemical processes and SEI film formation at the electrode/electrolyte interfaces. Impedance spectroscopy shows that the major contributions to the impedance of the battery are the electrolyte resistance and the electrode/electrolyte interfacial resistance. With each recharging cycle, the value of electrolyte resistance remains almost constant; however, the interface resistance increases, during the passage of current, due to the interfacial passive layer formation. 2020 Taylor & Francis Group, LLC. -
Secure Decentralization: Examining the Role of Blockchain in Network Security
Blockchain generation has emerged as a novel answer for securing decentralized networks. This technology, which was first created for use in crypto currencies, has received enormous interest in recent years because of its capability for boosting protection in various industries and community protection. The essential precept at the back of block chain technology is the decentralization of statistics garage and control. In a decentralized network, no central authority may control the statistics. Rather, the facts are shipped amongst multiple nodes, making it immune to tampering and single factors of failure. One of the most important advantages of blockchain in community protection is its capacity to offer cozy and transparent communication amongst community customers. Through cryptographic techniques, block chain can affirm the identities of network participants and ensure the authenticity of records trade. This feature is extraordinarily valuable in preventing unauthorized access and facts manipulation. 2024 IEEE.