Browse Items (9795 total)
Sort by:
-
Laccase mediated electrosynthesis of heliotropin on mango-kernel derived carbon nanosphere composite: A sustainable approach /
Journal of Science: Advanced Materials and Devices, Vol.7, Issue 4, pp.1-11, ISSN No: 2468-2179.
Facile fabrication of enzyme immobilized carbon nanospheres (CNS) based catalysts with high electrical conductivity and catalytic efficiency are of decisive importance for their electrocatalysis. A novel, green and highly efficient synthesis route is reported here for the development of an electrode surface with enhanced electrical conductivity and better catalytic activity for the electrochemical synthesis of heliotropin. The obtained biowaste (mango seed kernels) was pyrolyzed and subjected to acid treatment to form functionalized CNS (f-CNS). The functionalized carbon fiber paper (CFP) electrode was employed as a template for laccase immobilization which was further treated with free laccase resulting in the formation of Lac-fCNS/CFP electrode. -
β-cyclodextrin functionalized graphitic carbon nitride as a promising electrocatalyst for the selective oxidation of Tetrahydrofurfuryl alcohol /
Electrochimica Acta, Vol.430, ISSN No: 0013-4686.
Selective electrochemical conversion of Tetrahydrofurfuryl alcohol (THFA) was facilitated employing β−cyclodextrin (β−CD) functionalized graphitic carbon nitride (GCN) based nanocomposite. The GCN bulk were obtained by subjecting melamine to pyrolysis and further the material was exfoliated to improve its optoelectronic properties. Non-covalent attachment of β−CD over GCN via ultrasonication creates reactive surface sites on the electrode (β−CD/GCN/CFP) facilitating a better host-guest interaction. -
Characterization of nanocarbon based electrode material derived from anthracite coal
Nanocarbon derivatives (NCD's) have wide range of scope in the field of sensors, supercapacitors and charge storage application. In the present study, anthracite is used as a precursor to synthesis nano-carbon derivatives. One of the important aspects of this study is to intercalate the synthesized NCD's with Li-ion to enhance its electrochemical and optical properties. The prepared NCD with Li-ion interface is used as an electrode material to study charge-discharge capacity and cyclic stability. The NCD shows a specific capacitance 65.4 mF g-1 and retention of capacitance after 200 cycles. However, adding small amount of supportive electrode material with NCD's enhances the capacitance after 160 cycles. The drastic increase in electronic conductivity of NCD's by adding supportive Li-ion permits the electrochemical activity of electrode material to be effectively utilized for practical applications. 2020 IOP Publishing Ltd. -
Analysing grief on twitter: A study of digital expressions on Om Puri's death /
Funes Journal of Narratives And Social Sciences, Vol.2, pp. 136-152, ISSN No. 2532-6732. -
Football Player Substitution Analysis using NLP and Survival Analysis
Football player substitution is extremely significant in situations where the team is down by goals or attempting to retain a lead that can add value to the team's performance. However, substituting players based on their prior performance would not assist the squad in making good decisions. In one of the papers, they used an inverse gaussian hazard model to determine the survival rate of players. However, the main issue arises when players do not give their all due to their mental state, which plays a critical role during the game. Furthermore, most of the research papers relied solely on past performance of players and various analyses, which was insufficient. This study discovered that the player's mindset should be mentally stable and competitive which is also very crucial during the match by reading various research articles. Hence, this study proposes a framework which comprises of two models, namely Survival Analysis (Kaplan-Meier Fitter) and Natural Language Processing (Sentimental Analysis). Sentimental Analysis would hel p in determining a player's mindset before the match and Kaplan-Meier Fitter is used to find out the survival rate of player's performance based on several factors like goal scored, passing accuracy etc. which would allow the team to make better informed decisions. Comparison of these two models would yield the best results for substitute players on the bench on the basis of their past performance and their mental health which will allow them to make team management to make better judgments. 2023 IEEE. -
Bioconversion of Feather Composts using Proteolytic Bacillus mycoides for their Possible Application as Biofertilizer in Agriculture
Proteolytic Bacillus strains were screened for highest protease production amongst which Bacillus mycoides (G2) was chosen as an assuring protease producer. Enzyme activity was maximum at 37C, pH-7, when the medium was supplemented with 0.5 and 0.75% of sucrose and beef extract respectively. Tapioca flour and soybean meal were capable of replacing commercial carbon and nitrogen sources respectively. Feather degradation studies revealed 62% of degradation with Quail feather (QF), followed by Chicken feather (CF) (58%), Guinea fowl feather (51%) and Pigeon feather (43%). Biodegradation of feather samples in soil evidenced degradation of Quail feather and Chicken feather at the following patternQF Treatment 1 (5%) ? CF Treatment 1 (5%) ? QF Treatment 2 (10%) ? CF Treatment 2 (10%). Maximum degradation of QF and sufficient release of free amino acids into the feather compost was obvious with Field Emission Scanning Electron Microscopic (FE-SEM) and High Performance Thin Layer Chromatographic (HPTLC) analyses respectively. In vitro plant growth studies of tomato and chilly plants were accomplished with feather composts. Maximum growth of 26.44cm (shoot length) was achieved when feather compost prepared with degraded QF (5%) was utilized as plant growth substrate, than other treatment pots (P < 0.05). Plant growth was exemplary in the case of tomato when compared to that of chilly. Sound degradation of QF, followed by CF using Bacillus mycoides could strengthen the efficacy of microbial fermentation processes. This significant attempt could support poultry farms as well as organic agricultural sectors ecologically. Graphic Abstract: [Figure not available: see fulltext.] 2021, The Author(s), under exclusive licence to Springer Nature B.V. -
Development of Genetic Algorithm based Neural Network Model for Predicting Workability and Strength of High Performance Concrete
International Journal of Inventive Engineering and Sciences (IJIES), Vol.2, Issue 6, ISSN : 2319-9598. -
Development of Genetic Algorithm Based Neural Network Model for Predicting Strength of High Performance Concrete
Volume 3, Issue -2, ISSN: 2248-9622 -
Development of Genetic Algorithm based Neural Network Model For Predicting Workability and strength of High Performance Concrete.
Volume-2 Issue-6, May, ISSN 23199598 -
Effect of Replacement of Cement By Metakalion On The Properties Of High Performance Concrete Subjected To Hydrochloric Acid Attack
Vol.2, Issue 6, November-December 2012, pp 033-038
ISSN: 2248-9622 -
Effect of Replacement of Cement by Metakalion On the Properties Of High Performance Concrete Subjected To Hydrochloric Acid Attack.
Vol. 2, Issue 6, November- December , pp.033-038
-
A Mathematical Correlation of Compressive Strength Among Silica, Alumina and Calcia Present in Composite Red Mud and Iron Ore Tailingbricks
Waste Red Mud generated from bauxite beneficiation in aluminium industry contains sodium oxide in minor amount along with silica and alumina in significant quantities. Waste iron ore tailings from beneficiation of iron ore in steel industry contain silica and alumina in significant quantities. A combination of both these materials in different amounts along with GGBS and lime addition resulted in complex alkali-activated reaction products consisting of (Si/Al), (Ca/Si) and (Ca/(Si+Al)) complexes which influence compressive strength of the test samples on curing for extended time periods at room temperature. Individual correlation coefficients of these complexes with compressive strength yielded high values with (Si/Al) and (Ca/Si+Al) ratios (0.92 and 0.96, respectively) while showing a poor correlation coefficient with (Ca/Si) ratio (0.88). A direct regression analysis between compressive strength and (Si/Al) ratio and (Ca/Si+Al) ratio indicated negative values with (Si/Al) ratios but positive values with (Ca/ (Si+Al)) ratios. It is therefore concluded that the addition of lime and GGBS (contributed from both GGBS and lime addition) resulted in Ca-Si-Al complex formations which are responsible for improved compressive strength of the samples. 2021, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
A Sustainability Approach to Geopolymer Brick Manufacture Using Mine Wastes
India has tons of by-products of industries like fly ash, ground granulated blast furnace slag (GGBS), and mine tailings from different ores. By incorporating these wastes in bricks, the carbon footprint can be minimized. This research pivots around the use of iron ore tailings (IOT) and slag sand as a substitute for clay or shale in the manufacture of stabilized geopolymer blocks. Iron ore tailings and slag sand were used for substitution in the range of 20-40% and 15-40% with increments of 5%. Fly ash, ground granulated blast furnace slag, and sodium silicates (Na2SiO3) were used with a constant value of 15%. The bricks were cast and cured at ambient temperature. The study includes testing of mechanical properties of geopolymer bricks as per IS recommendations. To study the macroanalysis, SEM and XRD analyses were also carried out on raw materials and developed composites. The outcomes of this investigation show that the inclusion of 25% of IOT and 30% of slag sand is acceptable as brick material. Springer Nature Singapore Pte Ltd. 2022. -
An experimental study on utilisation of red mud and iron ore tailings in production of stabilised blocks
Construction of bricks using waste materials is one among the many ways to address the problems encountered in infrastructure. In the present study, various industrial and mining wastes have been used to manufacture stable bricks. These wastes include red mud (RM) from Hindalco, and iron ore tailings (IOT) from BMM Ispat, Bellary. Both RM and IOT were combined in different proportions with ground-granulated blast furnace slag (GGBS) and waste lime. In first series, IOT was replaced in the range of 45% to 60% with increments of 5%, and RM was replaced in the range of 15% to 30% with increments of 5%. In the second series, RM was replaced in the range of 45% to 60% with increments of 5%, and IOT was replaced in the range of 15% to 30% with increments of 5%. Tests were performed as per the Indian and ASTM standards on both the raw material and the developed composites. These tests include liquid, plastic limit, particle size, XRF, XRD, and SEM on raw materials, while tests performed on composites were compressive strength, water absorption, efflorescence, porosity, apparent specific gravity, and bulk density. Results of the study indicate that addition of IOT up to 55% is acceptable as brick material. Springer Nature Singapore Pte Ltd 2020. -
An Empirical Model for Geopolymer Reactions Involving Fly Ash and GGBS
Numerous works are reported in literature regarding the enhancement of compressive strength of fly ash-GGBS geopolymer combinations with addition of alkali activators of varying concentrations. However, a limited study has been chronicled, revealing the specific role of alkali or alkaline earth contributed by the fly ash-GGBS combinations on the compressive strength development. It is well known that the strength of a geopolymer is dependent on gel formation from Al/Si ratio, Ca/Si ratio, and Ca/(Si + Al) ratio but their exact role when cured for various extended periods is unknown as yet. In the present study, alkali concentration in a fly ash-GGBS geopolymer combination was varied from 6 M to 12 M with increments of two mol in six different fly ash-GGBS combinations with a minimum of 20 percent and a maximum of 70 percent GGBS. The correlation coefficients between compressive strength and Al/Si, Ca/Si, and Ca/(Si + Al) ratios exhibited values higher than 0.95 taken individually. Multiple linear regression analysis with compressive strength (as dependent parameter) and individual values of Al/Si, Ca/Si, and Ca/(Si + Al) ratios (as independent parameters) was effectuated. It was observed that, depending on the composition, the compressive strength circumstantiated a changeover from Ca/Si to Ca/(Si + Al) ratio in the intermediate composition range. Such a detailed analysis is considered supportive of developing a suitable composition which will provide the optimum compressive strength of the combination. 2022 Beulah M et al. -
Mine Waste-Based Next Generation Bricks: A Case Study of Iron Ore Tailings, Red Mudand GGBS Utilization in Bricks
Utilization of mine wastes as a building material in the construction industry surmises to environmental and sustainable concepts in civil engineering.The potential environmental threat posed by mining wastes, as well as a growing societal awareness of the need to effectively treat mining wastes, has elevated the subject importance.The present research proposes a method of producing bricks that is both cost effective and environmentally benign. The research is based on the geopolymerization, known to save energy by obviating high-temperature kiln firing and lowering greenhouse gas emissions. The methodology encompasses the mixing of red mud and iron ore tailings in the range of 90% to 50% with a decrement of 10% with GGBS in the range of 10% to 50% with an increment of 10%. The raw materials and the developed composites have been tested as per Indian and ASTM standards.In addition to tests pertaining to the physical and mechanical properties, XRF, XRD, and SEM tests have been performed for examining various related issues. Based on the result analysis, the compressive strength values showed noticeable differences in case of IOT and red mud bricks with IOT-based bricks showing better compressive strengths. 2021 M. Beulah et al. -
Hybrid fruit-fly optimization algorithm with k-means for text document clustering
The fast-growing Internet results in massive amounts of text data. Due to the large volume of the unstructured format of text data, extracting relevant information and its analysis becomes very challenging. Text document clustering is a text-mining process that partitions the set of text-based documents into mutually exclusive clusters in such a way that documents within the same group are similar to each other, while documents from different clusters differ based on the content. One of the biggest challenges in text clustering is partitioning the collection of text data by measuring the relevance of the content in the documents. Addressing this issue, in this work a hybrid swarm intelligence algorithm with a K-means algorithm is proposed for text clustering. First, the hybrid fruit-fly optimization algorithm is tested on ten unconstrained CEC2019 benchmark functions. Next, the proposed method is evaluated on six standard benchmark text datasets. The experimental evaluation on the unconstrained functions, as well as on text-based documents, indicated that the proposed approach is robust and superior to other state-of-the-art methods. 2021 by the authors. Licensee MDPI, Basel, Switzerland. -
Maximizing Bifunctionality for Overall Water Splitting by Integrating H2 Spillover and Oxygen Vacancies in CoPBO/Co3O4 Composite Catalyst
In the pursuit of utilizing renewable energy sources for green hydrogen (H2) production, alkaline water electrolysis has emerged as a key technology. To improve the reaction rates of overall water electrolysis and simplify electrode manufacturing, development of bifunctional electrocatalysts is of great relevance. Herein, CoPBO/Co3O4 is reported as a binary composite catalyst comprising amorphous (CoPBO) and crystalline (Co3O4) phases as a high-performing bifunctional electrocatalyst for alkaline water electrolysis. Owing to the peculiar properties of CoPBO and Co3O4, such as complementing Gibbs free energy values for H-adsorption (?GH) and relatively smaller difference in their work functions (??), the composite exhibits H2 spillover (HS) mechanism to facilitate the hydrogen evolution reaction (HER). The outcome is manifested in the form of a low HER overpotential of 65 mV (at 10 mA cm?2). Moreover, an abundant amount of surface oxygen vacancies (Ov) are observed in the same CoPBO/Co3O4 composite that facilitates oxygen evolution reaction (OER) as well, leading to a mere 270 mV OER overpotential (at 10 mA cm?2). The present work showcases the possibilities to strategically design non-noble composite catalysts that combine the advantages of HS phenomenon as well as Ov to achieve new record performances in alkaline water electrolysis. 2024 The Author(s). Small Science published by Wiley-VCH GmbH. -
Herbal healing traditions: A study of folk medicines used by traditional healers of Sonamukhi block, Bankura district, West Bengal, India
This ethnobotanical study aims to dive into the traditional medicinal practices used by tribals in Sonamukhi Block, Bankura district, West Bengal, India. Focusing on the use of medicinal herbs, the study carefully investigates the intergenerational wisdom kept by traditional healers, who play an important role in healthcare administration. Through conversations with traditional healers and patients, a thorough list of medicinal plants used to treat various diseases has been developed. The study demonstrates that traditional healers successfully use these medicinal plants to produce herbal medications, offering insights into the painstaking process of herbal medicine preparation that was explored in depth during the investigation. These findings highlight the significance of joint efforts to preserve indigenous knowledge and encourage the incorporation of traditional healing techniques into contemporary healthcare. The research study focused on the complicated junction of scientific methodologies and traditional beliefs, indicating the possibility for effective collaboration between scientific institutions and indigenous populations to improve healthcare practices. The studies' thorough examination of medicinal plant usage and herbal medication manufacturing emphasizes the importance of preserving, recording, and using this unique traditional knowledge for the benefit of world healthcare. 2024 Horizon e-Publishing Group. All rights reserved.