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Towards Visibility: Subaltern Counterpublics in Paul Chirakkarodes Pulayathara
Christianity has always been celebrated as a catalyst towards modernity for the Dalits of Kerala. Though missionary accounts and ethnographic studies confirm the progress of the community, there was rampant casteism and separatism too. This is succinctly revealed in Dalit Christian texts. Pulayathara by Paul Chirakkarode stands as a testimony to the Dalit Christian dilemma and traces the history of the Kuttanadan Pulaya community in the pre- and post-conversion scenarios. Conversions could not change the existing public sphere of Kerala, where upper castes were the dominant party. They (Dalits) continued to be marginalized and subordinated and lacked a class consciousness. The article highlights the limitations in the public sphere that emerged in Kerala as part of the missionary endeavours in accommodating the converted Dalits. The article attempts to trace the emergence of subaltern counterpublics among the Dalit Christians to oppose the continued oppression and casteism by situating Pulayathara at the centre of the analysis. 2022 Indian Institute of Management, Ahmedabad. -
A Study on Some Eccentricity Related Problems in Graphs
The concepts related to eccentricity in graphs are explored in this research work. newlineThe eccentric graph Ge of a graph G has the same vertex set as that of G and two newlinevertices in Ge are adjacent if one is the eccentric vertex of the other. The eccentric newlinegraphs of some graph operations are explored, and the iterated eccentric graphs Gek newlineare introduced. The process of inding eccentric graphs, known as eccentrication, is newlinestudied in detail. Graphs that result in a complete graph Kn upon iterative eccentrication are characterized, and the cyclic property of eccentrication is established for various cycle-related graphs. The eccentrication of tree graphs is studied in detail, and a general result on the cyclic property of trees is obtained. A conjecture on the cyclic property of eccentrication for any graph G is made. The ei-signed graph of a graph G, where the edge between vertices u and v receives a sign and#963; = (and#8722;1)|ecc(u)and#8722;ecc(v)|, where ecc(u) is the eccentricity of vertex u, is investigated. General properties of ei-signed graphs, such as homogeneity, consistency, switching, and sign compatibility, are discussed. Properties that behave diferently across various classes of graphs are explored. Finally, the scope of this study is presented, and some open problems in the area are provided. -
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Design Optimization of Electrical Connector Assembly using FEA
Due to the increasing number of devices and systems connected to an electric system, the need for reliable and high-quality electrical connectors has become more prevalent. This project aims to optimize the design of an electrical connector during its two most critical stages: insertion and retention of housing using FEA. A structural analysis is performed during the insertion and retention stages of housing. This process involves calculating the dimensional deformations and maximum strains developed during the steps mentioned above to determine the reliable functioning of electrical contacts. The input geometry is fed to the finite element analysis. The forces applied on the connectors latch on their respective connection are ensured to be under the limit. The analysis and simulation results are reflected to validate the safe forces in the connector assembly and a proper justification for an experimental set up in the laboratory. 2022, Books and Journals Private Ltd.. All rights reserved. -
Co-MoS2 nanoflower coated carbon fabric as a flexible electrode for supercapacitor
Cobalt doped MoS2 (Co-MoS2) nanoflowers have been successfully synthesized via a simple one-step hydrothermal method for supercapacitor applications. To identify the crystalline nature and morphology, the as-prepared material is characterized by XRD, SEM, and TEM measurements. The material exhibits a specific capacitance value of 86 F g-1 at a current density of 1 Ag-1 in symmetric two-electrode configuration with excellent cyclic stability of 98.5% even after 10,000 chargedischarge cycles. The results suggest the suitability of Co-MoS2 as an efficient electrode material for supercapacitors. 2021 Elsevier Ltd. All rights reserved. -
Comparison of genetic algorithm with Particle Swarm Optimisation, ant colony optimisation and Tabu search based on university course scheduling system
Objectives: Planning and allocation of the various resources according to the constraints is a hilarious task. The paper aims to find a suitable method to solve the university course scheduling problem. Methods and Statistical Analysis: This paper compares the usage of Particle Swarm Optimisation (PSO), Ant Colony Optimisation (ACO), Tabu Search and Genetic Algorithm (GA) in the preparation of University Course Scheduling System. Certain hard constraints, which has to be satisfied and some soft constraints that can be satisfied are considered. Findings: The algorithm should check for the satisfaction of the hard constraints and the possibility of satisfying the soft constraints. Application/Improvements: The performance of the suitable method is found by comparing with the other methods based on various parameters. -
Role of Metacognition in natural and Artificial systems
International proceedings of Computer Science and Information Technology, Vol. 37, pp. 34-99 ISSN No. 2010-460X -
DPETAs: Detection and Prevention of Evil Twin Attacks on Wi-Fi Networks
Numerous types of threats could become vulnerable to Wi-Fi networks. In terms of preventing and reducing their effect on the networks, it has become an imperative activity of any user to understand the threats. Even after thoroughly encrypting them, the route between the attackers device and the victims device may even be vulnerable to security attacks on Wi-Fi networks. It has also been noted that there are current shortcomings on Wi-Fi security protocols and hardware modules that are available in the market. Any device connected to the network could be a possible primary interface for attackers. Wi-Fi networks that are available in the transmission range are vulnerable to threats. For instance, if an Access Point(AP) has no encrypted traffic while it is attached to a Wi-Fi network, an intruder may run a background check to launch the attack.And then, attackers could launch more possible attacks in the targeted network, in which the Evil Twin attack have become the most prominent. This Evil Twin attack in a Wi-Fi network is a unique outbreak mostly used by attackers to make intrusion or to establish an infection where the users are exploited to connect with a victims network through a nearby access point. So, there are more chance to get users credentials by the perpetrators. An intruder wisely introduces a fake access point that is equivalent to something looks like an original access point near the network premises in this case. So, an attacker is capable of compromising the network when a user unconsciously enters by using this fake access point. Attackers could also intercept the traffic and even the login credentials used after breaching insecure networks. This could enable monitoring the users and perhaps even manipulating the behavior patterns of an authorized network user smoother for attackers. The key consideration of this research paper is the identification and avoidance of the Evil Twin attack over any Wi-Fi networks. It is named as DPETAs to address the strategies that intruders use to extract identities and what users need to do to keep them out of the networks. 2022, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
Recent advances in electrochemical synthesis of nitriles: A sustainable approach /
ChemistrySelect, Vol.7, Issue 12, ISSN No: 2365-6549.
Nitriles unveil widespread applications in pharmaceuticals, agrochemicals, textiles, rubber, polymers, and constitute a significant intermediate in several organic transformations, necessitating the design of simple and environmentally benign pathways for their synthesis. Over the recent years, electro-organic reactions have found widespread attention in developing effective and selective organic synthesis. They possess several advantages: high atom economy, selectivity, minimal waste production, and shorter routes to multistep traditional organic reactions. The development of novel strategies for greener and sustainable electro-organic synthesis of nitriles is therefore commendable. -
On-board intelligent energy management system for gridable electric vehicles and a method thereof /
Patent Number: 202141037003, Applicant: Parag Jose Chacko.
The idea proposed is an Intelligent Energy Management System (1EMS) which will be on board a Gridable Electric Vehicle (GEV) for enabling Grid Integration to facilitate Grid to Vehicle (G2V), Vehicle to Grid (G2V) and Vehicle to Vehicle (V2V) active power flow. Gridable Electric Vehicles are vehicles coming under the category of Plug-in Hybrid Electric Vehicles (PHEV) and Battery operated Electric Vehicles (BEV). The interest towards alternate transportation is increasing due to the increasing fuel prices and the increased air pollution. -
ZnO nanorods on POPD/GCN/TCFP with ternary synergy for promoting electro-oxidation of furfuryl alcohol
In this work, Poly(o-phenylenediamine) (POPD) and zinc oxide (ZnO) nanoparticles were electrochemically deposited on GCN (graphitic carbon nitride) coated TCFP (Toray carbon fiber paper) electrode. The modified electrode ZnO-POPD-GCN-TCFP was assessed by Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and X-ray photoelectron spectroscopy (XPS) studies. The electrochemical studies were carried out via cyclic voltammetry (CV) and electrochemical impedance spectroscopic (EIS) methods. The developed electrode was employed for the oxidation of furfuryl alcohol (FA) using 4-ACT (4-acetamido TEMPO) as a mediator in an alkaline medium via bulk electrolysis. Proton nuclear magnetic resonance (1H NMR) spectroscopy was used to characterize the final product. The oxidation of FA to furfural was accelerated by the heterogeneous catalyst ZnO-POPD-GCN-TCFP electrode owing to its good electrocatalytic activity and stability. Hence, a sustainable electrochemical method for synthesizing furfural, with significance in the realm of green chemistry, was developed. The Electro-oxidation of FA offers a clean alternative to traditional methods utilizing electricity, potentially from renewable sources, to drive the reaction, reducing reliance on harsh chemicals and minimizing environmental impact. By adjusting parameters like electrode potential and electrolyte composition, it is possible to optimize the reaction conditions for furfural production with optimal yield, which has several applications in daily life. 2024 Elsevier Ltd -
Indole-3-Carbinol Upconversion with Copper Oxide Nanoparticles Supported Graphitic Carbon Nitride: A Sustainable Approach
Electro-organic chemistry offers a sustainable and efficient approach to organic synthesis by utilizing electrochemical processes. This field has gained significant attention due to its potential for minimizing waste, reducing energy consumption, and enabling selective transformations. Herein, we report the development of a graphitic carbon nitride-coated carbon fiber electrode modified with electropolymerized amino-2-thiazole and electrodeposited Cu2O nanoparticles from copper nitrate trihydrate for the oxidation of Indole-3-carbinol (IC). Scanning electron microscopy, X-ray diffraction analysis, and X-ray photoelectron spectroscopy studies were carried out to characterize the developed electrode. Cyclic voltammetry, electrochemical impedance spectroscopy, and bulk electrolysis techniques were employed for the electrochemical studies. The enhanced electrochemical activity of the Cu2O-pAT-GCN-TCFP electrode compared to the individual GCN and polymer electrode was studied using electrochemical characterization, which revealed a 3-fold increase in the current response for Cu2O-pAT-GCN-TCFP (0.0011 A) compared to the bare electrode. The reaction was carried out using an aqueous carbonate buffer solution as an electrolyte via bulk electrolysis at a set potential of 0.82 V. The product obtained was isolated by column chromatography to obtain a yield of 74% and characterized by proton nuclear magnetic resonance (1H NMR) spectroscopy. Additionally, the Cu2O-pAT-GCN-TCFP electrode was studied for its stability, reproducibility, and selectivity. 2024 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. All rights, including for text and data mining, AI training, and similar technologies, are reserved. -
Pi-MnO2 decorated poly-3-thienylacetic acid on carbon fiber paper for electrochemical synthesis of 2-formyl-thiophene
Sustainable and environmentally benign synthesis methods have captured researchers' minds in recent times and have contributed a lot towards the green synthesis of organic compounds. This work presents an efficient green method for synthesizing 2-formyl thiophene using a newly designed Pi-MnO2 deposited on poly-3-thienylacetic acid coated Toray carbon fiber paper (PThAA-Pi-MnO2-TCFP) electrode. Cyclic voltammetry (CV), chronoamperometry (CA) and bulk electrolysis (BE) techniques were employed for the optimization and synthesis of 2-formyl thiophene and the product obtained was characterized by proton nuclear magnetic resonance (1HNMR) spectroscopy. The efficacy of the developed electrode was examined by different electrochemical and physicochemical studies. It is an intriguing approach for the 4-acetamido-TEMPO (4-ACT) mediated, PThAA-Pi-MnO2-TCFP catalyzed electro-oxidation of thiophene-2-ylmethanol (TM). This method is handy and reasonably practical since the developed electrocatalyst is inexpensive, and the synthesis is environmentally benign. Hence it is a highly efficient method for synthesizing 2-formyl thiophene, a much sought-after starting material in pharmaceuticals, agrochemicals, and cosmetics. 2023 -
Co-Electrodeposited Pi-MnO2-rGO as an Efficient Electrode for the Selective Oxidation of Piperonyl Alcohol
Pi-MnO2-rGO-CFP electrode was developed through a concurrent deposition of Pi-MnO2 and reduced graphene oxide (rGO) on carbon fiber paper (CFP). Cyclic voltammetry (CV) and electrochemical impedance studies (EIS) were applied for the electrochemical characterization of the electrode. The electro catalytic activity of the modified electrode was improved by the increased synergistic characteristics of the CFP and electrochemically deposited rGO-Pi-MnO2 composite. The performance of the modified electrode was remarkable due to its lowest charge transfer resistance (R ct), and highest surface area offering more active sites and quicker electron transport kinetics. X-ray diffraction spectroscopy (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and optical profilometry (OP) were employed to study the physicochemical properties. Furthermore, the modified electrode was availed to oxidize piperonyl alcohol mediated by 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl (4-acetamido TEMPO or 4-ACT). The product obtained was purified and characterized by 1HNMR. The turnover frequency of 4-ACT was studied at different concentrations of the reactant, and the reaction parameters were also optimized using statistical tool design of experiment. This methodology is demonstrated to be economical, environmentally benign, and highly efficient in obtaining piperonal as it is carried out under milder reaction conditions. 2023 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. -
Recent Advances in Electrochemical Synthesis of Nitriles: A Sustainable Approach
Nitriles unveil widespread applications in pharmaceuticals, agrochemicals, textiles, rubber, polymers, and constitute a significant intermediate in several organic transformations, necessitating the design of simple and environmentally benign pathways for their synthesis. Over the recent years, electro-organic reactions have found widespread attention in developing effective and selective organic synthesis. They possess several advantages: high atom economy, selectivity, minimal waste production, and shorter routes to multistep traditional organic reactions. The development of novel strategies for greener and sustainable electro-organic synthesis of nitriles is therefore commendable. This review focuses on analyzing various methods and strategies used in the electrochemical synthesis of nitriles using phase transfer catalyst, N-oxoammonium salts mediated electrocatalysis, iodine-mediated electrocatalysis, and anodic oxidations of aldoximes. In addition, the recent trends including the synthesis of nitriles via C?H cyanation, domino oxidation, bio electrocatalysis, and metal-ligand cooperative synthesis have been discussed. 2022 Wiley-VCH GmbH. -
A Study of Financialization of Commodity Markets in India
For numerous financial institutions, Commodity Futures (CF) has emerged as a widespread asset class since the 2000s. From 2000 to 2010, the estimation of the number of commodity index traders quadrupled, also, the number of hedge funds tripled. Recently, it has been noticed that in India, there occurs a vast inflow of investment toward the CF. Simultaneously, there occurs a problem of extremely higher prices along with volatility in commodity prices in India. However, studies on the financialization of the Commodity Market (CM) in India are not sufficient. This study was presented for analyzing the role of the financialization of CMs in India. Analyzing the association betweenCMs and equities markets in India is the major intention behind this study. Here, the Indian- MCX of India, the NSE of India, and the S&P500 Index are the sources from where the data has been gleaned. The outcome has been evaluated by utilizing a vector autoregression. The output demonstrated that no positive interdependence was exhibited by the correlation betwixt MCX Comdex returns and CNX Nifty. Consequently, a higher percentage of the mean value was attained by the commodity of daily returns of metal of commodity of agriculture. 2023 EDP Sciences. All rights reserved. -
Narrowband and Wideband Directional Beamformer with Reduced Side Lobe Level
In this paper, the synthesis of narrow and wideband beamformers with reduced side lobe level and wide beam steering capability is presented. A closed form expression with slope equalization technique is derived for array factor of the beamformer to meet the desired beam-pattern specifications of Half Power Beam-Width (HPBW)and Side Lobe Level (SLL). The proposed beamformer design is adaptable to any bandwidth and null placement in the desired direction. The slope equalization method improves the SLL of the beamformer. Compared to Kaiser, Chebyshev, DPSS and Taylor beamformers, the proposed narrowband and wideband beamformers exhibit lower and tapered side lobes, hence improved First Null to Last Null (FNLN)ratio. The proposed wideband beamformer exhibits superior performance in the wideband frequency range of 1-3GHz. 2019 IEEE. -
Scalable, Cost Effective IoT Based Medical Oxygen Monitoring System for Resource Constrained Hospital Environment
Oxygen therapy is one of the critical treatments employed in epidemics, pandemics, and natural calamities. Recent covid pandemic worldwide witnessed many deaths due to improper management, delayed delivery, and wastage of medical oxygen. Therefore, efficient utilization of available oxygen is very important. To monitor and manage oxygen, several hospitals employ IoT-based systems. Scalability is an essential feature in such monitoring systems in order to cater to the needs of a sudden surge in the number of patients requiring oxygen. The most commonly employed technique to monitor and manage an oxygen cylinder uses a pressure sensor where scaling up is an issue. Therefore, in this paper, a scalable solution that efficiently measures and monitors the available oxygen in the cylinder is proposed. The approach measures oxygen level using a weight sensor module and raises alerts during critical conditions such as low oxygen level and blockage or leakage of oxygen. The proposed system is a cost-effective, plug-and-play system that aids rapid deployment thereby providing timely care to the patients. Also, it does not require any change in the existing infrastructure making it suitable for a resource-constrained environment. The proposed system supports a web-based dashboard and mobile app that can be remotely accessed. 2022 IEEE. -
Brand anthropomorphisms impact on real estate purchase decisions of young buyers in India and the underlying reliance on spatial memory
Purpose: Assessing anthropomorphic tendency in relation to real estate purchase decisions and analysing the elements of friendliness, aggressiveness, pleasure and arousal as a link to the spatial memory of the consumer. This study aims to help brands and advertisers in the real estate industry to create meaningful consumer relationships by using elements that are associated with positive spatial experience. By formulating a detailed questionnaire with adapted variables from proven research and a multilayered approach of theoretic and practical analysis, this paper situates the identified variables in the plane of space and customer experience. Design/methodology/approach: By using structural equation modeling, this study analyses a sample data of 411 consumers and their response to elements of housing. Findings: The findings of this study showed that variables of friendliness, aggressiveness, pleasure and arousal significantly impact consumers real estate purchase decision; however, anthropomorphic tendency does not have a significant impact. Through theoretical analysis, it was found that spatial memory may have a role in the visual and display of the variables. Originality/value: The merit of this paper lies in the discussion it has raised with regard to the intersection between theoretics of space and the chosen variables. In the field of business and management, often philosophical implications of spatiality may not be actively associated with numerical computation. This paper not only looks at brand anthropomorphisms impact on real estate purchase decisions but also looks at friendliness and other mentioned variables as significantly impacting purchase decisions and linked to memory, space and affiliation. 2023, Emerald Publishing Limited. -
What drives the wheels of evolution in NGC 1512?: A UVIT study
Context. Environmental and secular processes play a pivotal role in the evolution of galaxies. These can be external processes such as interactions or internal processes linked to the action of bar, bulge, and spiral structures. Ongoing star formation in spiral galaxies can be affected by these processes. By studying the star formation progression in the galaxy, we can gain insights into the role of different processes that regulate the overall evolution of a galaxy. Aims. The ongoing interaction between the barred-spiral galaxy NGC 1512 and its satellite NGC 1510 offers an opportunity to inves- tigate how galactic interactions and the presence of a galactic bar influence the evolution of NGC 1512. We aim to understand the recent star formation activity in the galaxy pair and thus gain insight into the evolution of NGC 1512. Methods. The UltraViolet Imaging Telescope (UVIT) on board AstroSat enables us to characterise the star-forming regions in the galaxy with a superior spatial resolution of ?85 pc in the galaxy rest frame. We identified and characterised 175 star-forming regions in the UVIT far-ultraviolet (FUV) image of NGC 1512 and correlated with the neutral hydrogen (Hi) distribution. Extinction correc- tion was applied to the estimated photometric magnitude. We traced the star-forming spiral arms of the galaxy and studied the star formation properties across the galaxy in detail. Results. We detect localised regions of star-formation enhancement and distortions in the galactic disc. We find this to be consistent with the distribution of Hi in the galaxy. This is evidence of past and ongoing interactions affecting the star formation properties of the galaxy. We studied the properties of the inner ring. We find that the regions of the inner ring show maximum star-formation-rate density (log(SFRDmean[M yr?1 kpc?2]) ? ?1.7) near the major axis of the bar, hinting at a possible crowding effect in these regions. The region of the bar in the galaxy is also depleted of UV emission. This absence suggests that the galactic bar may have played an active role in the redistribution of gas and quenching of star formation inside the identified bar region. We therefore suggest that both secular and environmental factors might be influencing the evolution of NGC 1512. The Authors 2023.