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Nicotiana genus: a green and sustainable source for designing of nitrogen-rich efficient carbon nanocomposites for the hydrogenation of nitrophenol and non-enzymatic glucose sensing
Transition metals based nitrogen-doped carbon nanocomposites have been envisioned as a potential replacement for precious metal-based nanostructures to catalyze a variety of reactions. Herein, we report the synthesis of a group of nitrogen-doped carbon nanocomposites derived from the Nicotiana genus family plant, e.g. tobacco, a highly nicotine rich entity, and iron nitrate mixture followed by their exploitation for the reduction of 4-nitrophenol (4-NP) and non-enzymatic electrochemical glucose sensing. The controlled study suggests that the pyrolysis of tobacco results in ?7 at.% of nitrogen doping, an important heteroatom to enhance the catalytic efficiency of nanocomposites. The kinetics of the reduction of 4-NP follow a pseudo-first-order reaction. The time constant is found to increase with the Fe content in the composite owing to the formation of FeNx centers. The separation of a catalyst with the aid of a magnetic field offers a huge add-on to vouch for the recovery of these catalysts. Along with the display of appealing catalytic reduction, its application to non-enzymatic electrochemical glucose sensing is also demonstrated. Overall, the Nicotiana genus can be used as nitrogen-carbon precursors for designing of targeted N-doped carbon-based composites that could be exploited for various applications. 2021 Elsevier Ltd -
Cyanogenic glycosides: A sustainable carbon and nitrogen source for developing resilient Janus reversible oxygen electrocatalysts for metal-air batteries
Most of the transition metal based heteroatom doped carbon electrocatalysts, utilizes the fossil fuel derived commercially available precursors as source of nitrogen and carbon which may question our environmental generosity. Herein, we have developed Ni-based efficient bifunctional electrocatalysts using apple seeds (that contains cyanogenic glycosides) as the precursor for nitrogen and carbon. With tuning the temperature, we were able to optimize the nitrogen doping up to ?3 at.%. The optimized electrocatalyst catalyses the oxygen reduction reaction (ORR) process with muted peroxide generation (for 0.7500.1 V the % HO2 ? generation ?3 - 2%), preferential 4e? reduction pathways (n ? 3.93 to 3.98 in 0.750.1 V range) and electron transfer via inner-sphere electron transfer mechanism which ensures the maximum utilization of instituted active centres owing to the direct interaction of reactant species. Alike to ORR, the superior oxygen evolution reaction (OER) performance with smaller Eonset, EJ=10, Tafel slope and enduring accelerated stability test advocates its potential as a bifunctional oxygen electrocatalyst. Moreover, smaller potential gap ?E (EJ10_OER - E1/2_ORR) of 0.845 V further warrants the energy efficient OER/ORR process. A porotype of Al-air battery system using our catalysts as oxygen electrode and chocolate wafer as anode material is well capable of powering the light emitting diodes. This study hopefully opens a new avenue to explore cyanogenic glycosides plants product to develop multifunctional electrocatalysts. 2019 Elsevier Ltd -
THE MONOCHROME TAPESTRY OF SOLO EXISTENTIAL TRAVEL IN 21ST CENTURY HOLLYWOOD: A CRITICAL ANALYSIS
Solo existential travel films of Hollywood enjoyed their heyday in the first two decades of the 21st century with most of them emerging as cult classics that have inspired millions to venture out on backpacking trips. The solo travel beyond the margins of a materialistic society that promises the traveller some existential clarity, in theory, is a truly existential endeavour that lets the individual exercise their Sartrean freedom and responsibility. But a quick survey of the films produced by Hollywood over the decades reveals a rather stealthy racism within. Solo existential travellers in Hollywood films of the 21st century have predominantly been white Americans. Despite being a powerful tool to create ones meaning and authentic identity in society, solo travel is still an instrument of self-redemption that is kept away from people of colour, especially the black American community. The paper will look into the significance, relevance and consequences of this seemingly invisible omission. From an embodiment perspective, the paper will attempt to analyze the absence of racial diversity in the genre to shed light on why the coloured body is to find its space in Hollywoods tapestry of solo existential travel. Copyright 2024 Namitha Nandan. -
Study of Influence of Combustion on DarcyBard Convection with Inherent Local Thermal Non-equilibrium Between Phases
This work deals with a DarcyBard convection problem in the presence of combustion and with local thermal non-equilibrium between the fluid and the solid phases. The effects of combustion and local thermal non-equilibrium on the onset of convection is studied in the linear and nonlinear regimes. Unlike all reported local thermal non-equilibrium problems reported so far, the present problem has a unique situation of having thermal non-equilibrium not only in the perturbed state but also in the basic state. Further, we observe that local thermal non-equilibrium does not, under any circumstance, lead to local thermal equilibrium except in an approximate sense when the combustion is quite weak. The effect of combustion is to advance the onset of convection compared to that in its absence. The effect of local thermal non-equilibrium is to reinforce the effect of combustion. In the presence of both these effects, sub-critical instability exists. The results are obtained numerically and have implication in practical porous medium convection problems. 2022, The Author(s), under exclusive licence to Springer Nature B.V. -
Thermorheological effect on RayleighBard magnetoconvection in a biviscous Bingham fluid with rough boundary condition on velocity and Robin boundary condition on temperature
The thermorheological effect on the onset of RayleighBard convection in a biviscous Bingham fluid in the presence of a horizontal magnetic field is investigated considering rough boundary conditions on velocity and Robin boundary conditions on temperature. The viscosity of the electrically conducting fluid is assumed to be sensitive to temperature variation. Linear and global nonlinear stability analyses are performed using the Chebyshev pseudospectral method to determine the existence of instability or otherwise. A general interpretation is made from the results to show the effects of the magnetic field and the variable viscosity on the system's stability. The biviscous Bingham parameter and the Chandrasekhar number are shown to have a delay in the onset of convection, while the effect of temperature sensitivity is to advance the onset. It is found that the results of linear and global nonlinear stability are not in agreement, so the region of subcritical instability exists. Also, the results obtained for RayleighBard convection agree pretty well with those of Platten and Legros and Siddheshwar et al. for the limiting cases. 2023 Wiley Periodicals LLC. -
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Tracking Sigmoid Regression with Multicollinearity in Phase I: An Approach Incorporating Control Charts
Regression and quality control are two crucial techniques that data analysis employs in improving the decision-making process. We use the sigmoid function to model the connection between independent factors and the dependent variable in sigmoid regression. When there is a significant correlation among the independent variables in a regression model, multicollinearity a statistical phenomenon exists. Multicollinearity presents problems with higher uncertainty when estimating individual coefficients possibly making it harder to identify each variable's distinct contribution to the model. By suggesting a control chart specifically designed for the sigmoid regression model, this research presents a strategy to address the impact of influential observations using regression control charts, by making use of principal component regression class estimators. Principal component regression merges from the principal component analysis and linear regression methodologies, aiming to alleviate multicollinearity issues and enhances the stability of regression models. The performance of the model is evaluated using Pearson's residuals, Deviance residuals, and residuals. This strategy is proven to be useful in real world situations demonstrated through an application in the field of sleep wellness disorder. In conclusion, this study introduces a unique control chart to manage multicollinearity in sigmoid regression, providing a new perspective on the topic to spot differences in the underlying process by highlighting trends in the residuals. The Author(s), under exclusive license to Springer Nature Switzerland AG 2024. -
Residual-Based Statistical Process Control Charts in the Presence of Multicollinearity: an EWMA Framework with (RK) Estimator
Reliability monitoring of financial health requires strong control mechanisms, and the residual chart is an invaluable instrument to perform it. One of the key problems statisticians face while modeling is the problem of multicollinearity which arises when there is a strong correlation between independent variables leading to imprecise coefficient estimates and poor outcomes. To solve this problem and to make sure that the control chart works even with correlated data, we integrated a Weighted Moving Average Exponential smoothing chart within the modeling technique. The theoretical approach assures long-term variability and consistency of the residual control chart. These control charts are used to understand the process and the performances in various sectors. The charts can be used as analytical instruments to help recognize patterns, variations, or anomalies in economic indicators specifically in budget deficit data and facilitate rapid identification of any changes or inconsistencies in the fiscal deficit by policymakers. Further advances in statistical process control are rendered feasible by this study, which deepens the understanding and awareness of the potential uses and implications of the Weighted Moving Average Exponential smoothing chart for fiscal deficit data in the Economic realm. The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024. -
Situating censorship: A study of the politics of state and self in literary translations in Iran /
A nation’s culture flourishes by interacting with other cultures” (Razmjou). Cultural variety not only enriches our knowledge, but also acts as a guide towards the growth of a nation. It gives an insight about the basic human right practices of different cultures. The standard of culture of any particular nation can be gauged through various tools, but importance is given to literature, as it acts as a barometer to measure the cultural growth of the nation. To interpret any culture it is important to understand the beginnings of that particular culture and make an in-depth study of the progress of its civilization. The cultural evolution of any place is continuous and is a combination of many factors like geographic location, weather conditions prevalent, suitable food crops grown, its political policies, religious influences, its history and its present circumstances. The above factors directly or indirectly become responsible to blend and give shape to a culture. -
Titania Doped CDs as Effective CT-DNA Binders: A Novel Fluorescent Probe via Green Synthesis
Carbon dots (CDs), which belong to the class of zero-dimensional carbon-based nanomaterials, have garnered significant interest owing to their wide array of applications spanning from the electronics industry to the healthcare sector. This work employs a facile, inexpensive approach to synthesize green luminescent carbon dots (J-10) from a potential medicinal plant named Justicia Wynaadensis by the one-step hydrothermal method. A nanocomposite (JT-10) of the CDs is prepared by adding TiO2 nanoparticles derived from green synthesis of Lavandula leaves. The J-10 and JT-10 are further characterized by X-ray Diffraction spectroscopy (XRD), Transmission Electron Microscopy (TEM), Raman analysis X-ray Photoelectron Spectroscopy (XPS), and Fourier transform infrared techniques (FTIR), UVvis spectroscopy, Photoluminescence (PL), and Fluorescence or PL lifetime analysis. The average size of synthesized CDs is 1.85 nm and exhibits an excitation-dependent fluorescence nature at 320 nm. PL lifetime analysis of J-10 and JT-10 is calculated to be 5.80 and 2.84 ns respectively. Offering these unique optical properties and biocompatibility, the synthesised material is suitable for investigating their binding affinity and interaction mechanisms with DNA. The use of JT-10 in DNA binding studies contributes to the development of sustainable and efficient nanomaterials for applications in biosensors, drug delivery, and gene therapy. 2024 Wiley-VCH GmbH. -
Privacy-preserving federated learning in healthcare: Fundamentals, state of the art and prospective research directions
Recent collaborations in medical diagnostic systems are based on data private collaborative learning using Federated Learning (FL). In this approach, multiple organizations train a machine-learning model at the same time eventually leading to global model generation. This paper reviews the fundamentals of FL and its evolution path in Healthcare. The objective of this review is to scope a wide variety of healthcare applications in FL. Exactly what research direction is moving in interesting for research communities to guide their future course. This review uniquely focuses on examining numerous FL-based healthcare implementations, detailing their core methodologies and performance metrics, which, to our knowledge, have not been previously available. Privacy-preserving collaborative distributed learning through federated learning in healthcare enhances research collaborations, thereby resulting in better-performing models. This comprehensive review will act as a valuable reference for researchers exploring new FL applications in the healthcare domain. 2024 IEEE. -
A study on socio-economic impact of remittances on forward migrants household of tibetan refugees in india
Migration and Development is an agenda of every country s economic policy in recent time. Migration has been linked to the flow of remittances influencing socio-economic development particularly of developing countries. Studies on remittances have also reflected its positive side having potential effect at all levels including micro (households), macro (country) and meso newline(community) levels.The existing literature on remittance manifested the prominent role of remittance in enhancing livelihood of receiving households. Empirical study conducted on developing economies concluded that households receiving remittances are better off than those of non-receiving newlinehouseholds. International remittance has a direct role on household s economy by raising newlinehousehold s standard of living. Remittances were used for household consumption activities including education, health, housing, accumulating assets leading to human capital development. Likewise, literature pointed out the potential role of remittance inducing investment in business and entrepreneurship development by employing households in becoming self-reliant. Further, remittance improves trust and network within households and community which indirectly helps poor in the community. Thus, it is evident from the previous literature that newlineremittances have enhanced human and financial and social capital development. However, the existing literature lacks information on remittance affecting livelihood in Tibetan newlinecontext. Hence, there is a need of in-depth study in this area of research which is latent and unexplored. In this study, it has made an attempt to understand the role of remittance on Tibetan refugee communities in India who rely on remittance as one of the major sources of income. The study focuses on the impact of remittances from forward migrants who migrated from India towards newlinewestern and European countries. They send remittances back home leading to socio-economic development in the country of origin. -
A study on socio-economics impact of remittances on forward migrants household of the Tibetan refugees in India /
Migration and Development is an agenda of every country’s economic policy in recent time. Migration has been linked to the flow of remittances influencing socio-economic development particularly of developing countries. Studies on remittances have also reflected its positive side having potential effect at all levels including micro (households), macro (country) and meso (community) levels. The existing literature on remittance manifested the prominent role of remittance in enhancing livelihood of receiving households. Empirical study conducted on developing economies concluded that households receiving remittances are better off than those of non-receiving households. -
Influence of remittances oncapital endowment of Tibetan refugees in India
Purpose: An issue concerning Tibetan refugees in India is the poverty and unemployment among Tibetan youth. This often leads to households adopting a strategy of sending one of its members abroad towards North American or European countries in search of better income opportunities. Incomes in the form of remittances from these forward migrants have numerous impacts on living standard of left behind families. This study aims to focus on the influence of forward migrants remittances on livelihood in terms of human, financial and social capital development of Tibetan refugees in India. Design/methodology/approach: The paper includes 400 households from high-economic and low-economic-access regions of Tibetan settlements in India. Ordinary least square method was used to study these impacts. Findings: Findings show that remittances have significantly influenced human and financial capital development. However, it was found to be statistically not significant for social capital development. Originality/value: The present paper is original work. 2019, Emerald Publishing Limited. -
Continuity and changes in food consumption pattern among Tibetan refugee community in India
The Food consumption pattern of refugee communities is being carried out by many scholars and few acknowledged the food continuity, its implications on the health of refugees in the host country. The present study highlights food continuity among Tibetan refugees in the Bylakuppe settlement, India. 200 household data were administered to understand food consumption patterns by employing a structured household questionnaire. Simultaneously, 23 individual data were collected consisting of first migrants (15) and second-generation (8) for the qualitative study. Households derive energy mainly from carbohydrates and animal fats, and there is a prevalence of food insecurity among the Tibetan community. It is a proven fact that food insecurity will have serious health consequences in terms of emotional and mental well-being and suggest the need for further study of food insecurity among Tibetan refugees across the world. 2021 -
Integrating AI and Cybersecurity: Advancing Autonomous Vehicle Security and Response Mechanisms
The rapid evolution of autonomous and connected vehicles has led to their integration with numerous technologies and software, rendering them vulnerable targets for cybersecurity attacks. While efforts have traditionally focused on preventing these attacks, the escalating risk underscores the importance of also vindicating their wallop. Nevertheless, this procedure is often onerous & facade scalability confronted, particularly due to connectivity issues in automobiles. This research advises a vehicle-based vibrant imposition response scheme, enabling swift responses to a variety of incidents and reducing reliance on external security centers. The classification encompasses an inclusive range of probable retorts, a procedure for evaluating retorts, & innumerable assortment approaches. Implemented on an embedded platform, the solution was evaluated using two distinct cyberattack use cases, highlighting its adaptability, responsiveness, volume for dynamic arrangement constraint alterations & nominal memory trail. Concurrently, this paper presents an innovative (AVSF) that synergistically integrates (AI) and cybersecurity techniques to fortify AV resilience against evolving threats. Additionally, the framework incorporates advanced cybersecurity measures such as encryption, authentication, and intrusion detection to mitigate vulnerabilities and safeguard critical AV systems. The fusion of AI and cybersecurity not only enhances AV security posture but also enables intelligent cyber threat monitoring and response capabilities. Extensive simulations and experimental evaluations demonstrate the efficacy of the AVSF in real-time scenarios, contributing to the development of robust security solutions for autonomous vehicle deployment and advancing safer transportation systems in the era of AI-driven mobility. 2024 IEEE. -
Protection of intellectual property and human rights during health emergencies: an assessment of the patent waiver proposal
Purpose: Several countries, such as South Africa and India, believe that intellectual property rights (IPRs), including patents, impede the efficient increase in vaccine production to inoculate the global population as they scramble to recover from the COVID-19 pandemic. Their proposal at the World Trade Organization (WTO) to waive these pharmaceutical patents has been met with resistance from a few developed countries, who believe that the abrogation of IPRs is unnecessary, even during a pandemic. The purpose of this paper is to discuss the impact of a potential waiver of medical patents at the WTO versus the status quo of IPR laws in the global economy. Design/methodology/approach: This study examines key arguments from economic and moral standpoints regarding the provisions of the Trade-Related Aspects of Intellectual Property Rights (TRIPS) agreement and other related international agreements and their validity based on the premise of the internalisation of positive externalities posed by vaccines. Findings: The effectiveness of the TRIPS agreement in securing medical access is weak on account of the ability of profit-making multinationals to secure IP rights and on account of the Trans-Pacific Partnership, a multilateral agreement that supports patent evergreening and a period of protection on test data which challenges the access to medicines and the fundamental human right to health. Originality/value: This study examines international IPRs through the lens of human rights and proposes a new system that balances the two. 2022, Emerald Publishing Limited. -
Predictors of behavioral and emotional issues in children involved in custody disputes: A cross sectional study in urban Bengaluru
Background: The increasing rates of divorce in urban India has led to the subsequent parental battle for the child's custody. This paper discusses the behavioral and emotional issues of these children in relation to their psychosocial environmental factors and other relevant socio-demographic variables. Methods: We used samples from parent interviews concerning 52 children aged 717-years-old, involved in child custody cases in the Family court of urban Bengaluru. The Strengths and Difficulties Questionnaire was used to measure response variables of behavioral and emotional issues in these children. Predictor models of quantile and multiple linear regression were used to assess the influence of psychosocial environmental factors and socio-demographic variables on the response variables. Results: The predictor models revealed that risk of child suffering emotional and behavioral issues increased with factors such as excessive parental control, change of academic environment, general unrest at school, frequency of child's court visit, child's visitation of non-custodian parent on occasions and vacations, and negatively altered family relationship. The model however intriguingly showed that residing in nuclear household rather than with their grandparents in a non-nuclear household, decreased the risk of mental health issues in these children. Conclusions: This study is a novel attempt to understand the influence of the psychosocial issues on the child's mental health in the context of custody cases in India. Despite the minimum sample size, the findings imply that family-based intervention is the need of the hour in these cases. The implications for clinical practice and research are discussed. 2021 Elsevier B.V. -
Derris Indica Leaves Extract as a Green Inhibitor for the Corrosion of Aluminium in Alkaline Medium
The corrosion inhibitive effect of Derris indica leaves extract (DILE) on aluminium in 1 M NaOH is investigated at different temperatures. For this purpose, weight loss studies and electrochemical methods including potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) technique are employed. Surface analysis of the treated and untreated aluminium coupons are done by using metallurgical microscopy. About 60.2% of maximum corrosion inhibition efficiency is attained with an optimum inhibitor concentration of 1.2 g/L. Both weight loss and electrochemical studies confirmed that DILE plays a crucial role in the formation of a protective layer over metal surfaces. Also, electrochemical measurements revealed that DILE behaves as a mixed type of corrosion inhibitor. The kinetic parameters and thermodynamic parameters are calculated using Arrhenius theory and transition state theory. Langmuir adsorption isotherm was found to be the best fit and physical adsorption mechanism was proposed. En ineered Science Publisher LLC 2022 -
Coronal Elemental Abundances During A-Class Solar Flares Observed by Chandrayaan-2 XSM
The abundances of low first ionization potential (FIP) elements are three to four times higher in the closed loop active corona than in the photosphere, known as the FIP effect. Observations suggest that the abundances vary in different coronal structures. Here, we use the soft X-ray spectroscopic measurements from the Solar X-ray Monitor (XSM) onboard the Chandrayaan-2 orbiter to study the FIP effect in multiple A-class flares observed during the minimum of Solar Cycle 24. Using time-integrated spectral analysis, we derive the average temperature, emission measure, and the abundances of four elements Mg, Al, Si, and S. We find that the temperature and emission measure scales with the sub-class of flares while the measured abundances show an intermediate FIP bias for the lower A-flares (e.g. A1), while for the higher A-flares, the FIP bias is near unity. To investigate it further, we perform a time-resolved spectral analysis for a sample of the A-class flares and examine the evolution of temperature, emission measure, and abundances. We find that the abundances drop from the coronal values towards their photospheric values in the impulsive phase of the flares and, after the impulsive phase, they quickly return to the usual coronal values. The transition of the abundances from the coronal to photospheric values in the impulsive phase of the flares indicates the injection of fresh unfractionated material from the lower solar atmosphere to the corona due to chromospheric evaporation. However, explaining the quick recovery of the abundances from the photospheric to coronal values in the decay phase of the flare is challenging. 2023, The Author(s), under exclusive licence to Springer Nature B.V.