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White LED Light-Mediated Eosin Y-Photocatalyzed One-Pot Synthesis of Novel 1,2,4-Triazol-3-Amines By Sequential Addition
Abstract: A facile and proficient, eco-friendly multicomponent synthesis of 12 novel biologically essential 1,2,4-triazol-3-amines via the sequential addition of substituted phenacyl bromide, aromatic aldehyde, hydrazinecarbothioamide, and urea under white LED with eosin Y as a photocatalyst has been developed. The intrinsic advantages are methodology is cost-effective, non-toxic, generates a high yield of product, is column chromatography free and does not need the use of a specific instrument. Surprisingly, our methodology uses moderate conditions and can count the tolerance of a wide variety of electron-donating and electron-withdrawing groups. The analysis and early conclusions give more value and context for the future development of organic synthesis using photocatalysts. Graphical Abstract: [Figure not available: see fulltext.] 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Linking non-financial motivators of women entrepreneurs with entrepreneurial satisfaction: A cluster analysis
Women entrepreneurs confronted with several obstacles while managing their business houses and dealt firmly developing successful ventures over time. The long term sustainability of their business reflects their entrepreneurial skills. The existence of certain forces empowered entrepreneurial drive of women entrepreneurs leading to their satisfaction and engagement in their ventures. The present investigation evaluated the antecedents of women's entrepreneurial satisfaction by examining 405 women entrepreneur participants using confirmatory factor analysis and cluster analysis techniques. This study comprises only micro and small businesses of women. The non-monetary determinants emerged out as the significant determinants of satisfaction of women entrepreneurs. The results revealed four clusters of women entrepreneurs based on motivational theory such as micro-achievers, entrepreneurial team, liberal and socialist feminism and optimism. The results also indicated that the clusters of women entrepreneurs' respond distinctively towards various dimensions of entrepreneurial satisfaction, i.e., quality of married life, overall venture satisfaction, achieved innovation, achieved freedom, team orientation, achieved recognition and identity and achieved employee trust. 2022 Inderscience Enterprises Ltd. -
A post covid machine learning approach in teaching and learning methodology to alleviate drawbacks of the e-whiteboards
Deep learning has paved the way for critical and revolutionary applications in almost every field of life in general. Ranging from engineering to healthcare, machine learning and deep learning has left its mark as the state-of-the-art technology application which holds the epitome of a reasonable high benchmarked solution. Incorporating neural network architectures into applications has become a common part of any software development process. In this paper, we perform a comparative analysis on the different transfer learning approaches in the domain of hand-written digit recognition. We use two performance measures, loss and accuracy. We later visualize the different results for the training and validation datasets and reach to a unison conclusion. This paper aims to target the drawbacks of the electronic whiteboard with simultaneous focus on the suitable model selection procedure for the digit recognition problem. 2021 Tamkang University. All Rights Reserved. -
Dynamics of fractional model of biological pest control in tea plants with beddingtondeangelis functional response
In this study, we depicted the spread of pests in tea plants and their control by biological enemies in the frame of a fractional-order model, and its dynamics are surveyed in terms of boundedness, uniqueness, and the existence of the solutions. To reduce the harm to the tea plant, a harvesting term is introduced into the equation that estimates the growth of tea leaves. We analyzed various points of equilibrium of the projected model and derived the conditions for the stability of these equilibrium points. The complex nature is examined by changing the values of various parameters and fractional derivatives. Numerical computations are conducted to strengthen the theoretical findings. 2021 by the authors. Licensee MDPI, Basel, Switzerland. -
Iodine promoted synthesis of pyrido[2?,1?:2,3]imidazo[4,5-c]quinoline derivatives via oxidative decarboxylation of phenylacetic acid
An unprecedented and efficient molecular iodine promoted domino protocol for the synthesis of N polycyclic pyrido[2?,1?:2,3]imidazo[4,5-c]quinolines were reported from phenylacetic acid and 2-(imidazoheteroaryl)anilines. This methodology was also extended for the preparation of benzo[4?,5?]thiazolo [2?,3?:2,3]imidazo[4,5-c]isoquinolines in good yields. However, this protocol proceeds via a sequential decarboxylation of phenylacetic acid with I2/DMSO system followed by Pictet-Spengler cyclization in good yields. 2022 Taylor & Francis Group, LLC. -
Mediating role of teacher confidence between support system and satisfaction
Online education in India has witnessed a shift due to the ongoing pandemic, compelling the Indian education sector to adapt to new advancements. The study's main purpose has been to find the relationship between the support systems of institutions, teachers support and students, leading to instructors' satisfaction. It further analyses the mediating role of educators' confidence in linking support systems and leading to teachers' satisfaction. The sample for our research consisted of 129 teachers from Higher Educational Institutions (HEIs). We found that there is a significant relationship between support systems and teacher satisfaction. Among the three support systems, institutions support had a significant influence. On the other hand, teachers' confidence had a partially mediating effect on their satisfaction, even though they could translate to higher effectiveness in online teaching. Further, this study inferred that educational institutions are quick to adapt to online teaching due to the ongoing pandemic. Copyright 2022 Inderscience Enterprises Ltd. -
Visible Light Mediated Organophotoredox-Catalyzed One-Pot Domino Synthesis of Novel 6,7 Disubstituted 1H-Pyrroles
The development of environmentally benign protocols to synthesize novel N-heterocycles is vital in the field of synthetic organic chemistry. We herein report a successful one-pot domino synthesis of novel 6,7 disubstituted 1H-pyrroles using substituted phenacyl bromide, barbituric acid/Meldrums acid, aromatic amines catalysed by 5mol% Fluorescein in presence of visible light. This procedure is a useful and adaptable method for the synthesis of pyrroles since it is compatible with a wide range of sensitive functional groups, does not require column chromatography purification. During the reaction, Fluorescein may catalyse the formation of enamine leading to amino alcohol which subsequently undergoes dehydration to give 6,7 disubstituted 1H-pyrroles. All the synthesized derivatives were obtained in 9095% yields and were characterized by 1H, 13C NMR and HRMS (ESI) analysis. Graphical Abstract: [Figure not available: see fulltext.] 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Improved dhoa-fuzzy based load scheduling in iot cloud environment
Internet of things (IoT) has been significantly raised owing to the development of broadband access network, machine learning (ML), big data analytics (BDA), cloud computing (CC), and so on. The development of IoT technologies has resulted in a massive quantity of data due to the existence of several people linking through distinct physical components, indicating the status of the CC environment. In the IoT, load scheduling is realistic technique in distinct data center to guarantee the network suitability by falling the computer hardware and software catastrophe and with right utilize of resource. The ideal load balancer improves many factors of Quality of Service (QoS) like resource performance, scalability, response time, error tolerance, and efficiency. The scholar is assumed as load scheduling a vital problem in IoT environment. There are many techniques accessible to load scheduling in IoT environments.With this motivation, this paper presents an improved deer hunting optimization algorithm with Type II fuzzy logic (IDHOA-T2F) model for load scheduling in IoT environment. The goal of the IDHOA-T2F is to diminish the energy utilization of integrated circuit of IoT node and enhance the load scheduling in IoT environments. The IDHOA technique is derived by integrating the concepts of Nelder Mead (NM) with the DHOA. The proposed model also synthesized the T2L based on fuzzy logic (FL) systems to counterbalance the load distribution. The proposed model finds useful to improve the efficiency of IoT system. For validating the enhanced load scheduling performance of the IDHOA-T2F technique, a series of simulations take place to highlight the improved performance. The experimental outcomes demonstrate the capable outcome of the IDHOA-T2F technique over the recent techniques. 2022 Tech Science Press. All rights reserved. -
Development and evaluation of the bootstrap resampling technique based statistical prediction model for Covid-19 real time data : A data driven approach
The objective of the article is to develop earlyR package based novel coronavirus disease (COVID-19) forecasting model. The reported COVID-19 serial interval data is applied for obtaining maximum likelihood value of the reproduction number (R0) using maximum likelihood approach and projections package is applied for getting trajectories of epidemic curve. The minimum, median, mean and maximum projected value of R0 with 95% confidence interval (CI) is obtained by using bootstrap resampling strategy and the predicted cumulative probable count of new cases is also presented with different quantile. To validate the results with real scenario, the past COVID-19 data is considered. The % error rate ranges from -7.91% to 21.27% for the developed model for the five Indian States. 2022 Taru Publications. -
Improved dragonfly optimizer for intrusion detection using deep clustering CNN-PSO classifier
With the rapid growth of internet based services and the data generated on these services are attracted by the attackers to intrude the networking services and information. Based on the characteristics of these intruders, many researchers attempted to aim to detect the intrusion with the help of automating process. Since, the large volume of data is generated and transferred through network, the security and performance are remained an issue. IDS (Intrusion Detection System) was developed to detect and prevent the intruders and secure the network systems. The performance and loss are still an issue because of the features space grows while detecting the intruders. In this paper, deep clustering based CNN have been used to detect the intruders with the help of Meta heuristic algorithms for feature selection and preprocessing. The proposed system includes three phases such as preprocessing, feature selection and classification. In the first phase, KDD dataset is preprocessed by using Binning normalization and Eigen-PCA based discretization method. In second phase, feature selection is performed by using Information Gain based Dragonfly Optimizer (IGDFO). Finally, Deep clustering based Convolutional Neural Network (CCNN) classifier optimized with Particle Swarm Optimization (PSO) identifies intrusion attacks efficiently. The clustering loss and network loss can be reduced with the optimization algorithm. We evaluate the proposed IDS model with the NSL-KDD dataset in terms of evaluation metrics. The experimental results show that proposed system achieves better performance compared with the existing system in terms of accuracy, precision, recall, f-measure and false detection rate. 2022 Tech Science Press. All rights reserved. -
A versatile approach based on convolutional neural networks for early identification of diseases in tomato plants
Agriculture is one of the primary occupations in many countries. Tomatoes are grown by many farmers in countries where the water resource is available in abundance. Improper methods of cultivation and failure to identify the diseases when it is in the nascent stage results in the reduction of crop yield thus affecting the outcome of cultivation. This paper proposes a novel method of early identification of diseases in tomato plants by making use of convolutional neural networks (CNN) and image processing. Dataset from an open repository was considered for training and testing and the algorithm was capable of identifying nine different varieties of diseases that affect the tomato plant at its early stages. The images of tomato leaves were fed for identification through processing and classification. An optimum model was developed by analyzing various architectures of CNN including the VGG, ResNet, Inception, Xception, MobileNet and DenseNet. The performance of each of these architectures was compared and various metrics like the accuracy, loss, precision, recall and area under the curve (AUC) were analyzed. 2022 World Scientific Publishing Company. -
A novel optimised method for speckle reduction in medical ultrasound images
The advancement of medical imaging techniques evolving from X-ray to PET images and the medical image analysis helped medical experts to detect, diagnose and offer treatments for complex disorders and deadly diseases in the human body. Among the various modalities used, Ultrasound imaging is the most widely accepted modality because of its affordability, non-invasive nature and various other features. But the presence of speckle noise in ultrasound image lowers the image quality and reduces diagnostic value. This article states an improved hybrid speckle noise reduction method, a combined application of Kuan and non-local means filters. In this method, Kuan filter is used to sharpen the edges and thereafter the speckle noise elimination is done by using the non-local means. In addition, the performance of the proposed hybrid filter and its design parameters are optimised by using a meta-heuristic called grey wolf optimiser. The performance of hybrid method is evaluated by analysing a chosen set of well-known post filtering methods used for speckle reduction with given ultrasound B-mode images. The comparison of test results using remarkable performance metrics and computation time demonstrate that the hybrid method can be used as the efficient speckle reduction method for image analysis. Copyright 2022 Inderscience Enterprises Ltd. -
Removal of cadmium heavy metal ion using recycled black toner powder
The presence of heavy metal ions in the industrial effluents is considered as a major threat to humans and to the ecosystem. Among the available various types of heavy metal ions, cadmium is widely used in many industrial applications and is also considered as the hazardous heavy metal ion even in low level of concentration. In this present work, an attempt has been made to utilize the recycled black toner powder as a low cost adsorption material in the removal of toxic cadmium heavy metal ion. Batch adsorption technique was used for the removal of cadmium heavy metal ion. The experiments were conducted by varying the pH values from 3, 5 and 7, contact time from 15, 30, 45, 60 and 75 min and the dosage of the adsorbent from 2, 4, 6 and 8 g/L. Experimental results shows that the cadmium heavy metal ions were effectively removed for pH value of 5 and increasing the adsorbent dosage doesn't aid in increasing the adsorption rate. Rapid adsorption of cadmium heavy metal ions was observed only during the first 30 min of contact time and it reached equilibrium after contact time of 45 min. 2021 -
Self-esteem and self-efficacy among HIV-positive adolescents: an intervention study
Introduction: The aim of the present study was to understand the impact of comprehensive intervention program on self-esteem and self-efficacy among human immunodeficiency virus (HIV)-positive adolescents. Material and methods: Participants of the research were perinatally HIV-infected adolescent boys and girls, currently living in HIV care and support center. The study adopts a quasi-experimental non-equivalent control group design. Sample consisted of 97 adolescents (47 boys and 50 girls). Self-esteem was assessed using Morris Rosenbergs (1965) self-esteem scale, and self-efficacy was assessed using general self-efficacy scale (GSE) (1995) by Ralf Schwarzer & Matthias Jerusalem. It was hypothesized that there would be a significant improvement in the level of self-esteem and self-efficacy among participants of experimental group and no such improvement would be noticed in control group. Group intervention was conducted for experimental group focusing on four domains physical, cognitive, affective, and social, for 44 hours spread over 6 months. Comprehensive intervention was implemented through innovative expressive strategies. Participants were assessed pre and post-intervention. Results were analyzed using correlated t-test for self-esteem and Wilcoxon signed-rank test for self-efficacy scores. Results: There is a significant improvement in the level of self-esteem (t = 21.154; p < 0.001) and self-efficacy (z = 6.036; p < 0.001) post-intervention in the experimental group, and no such improvement was observed on both the variables in control group. Conclusions: The current study reveal that post-intervention there is a significant improvement in the level of self-esteem and self-efficacy among HIV-positive adolescents. 2022 Termedia Publishing House Ltd.. All rights reserved. -
Evaluating the usability of mhealth applications on type 2 diabetes mellitus using various mcdm models
The recent developments in the IT world have brought several changes in the medical industry. This research work focuses on few mHealth applications that work on the management of type 2 diabetes mellitus (T2DM) by the patients on their own. Looking into the present doctor-to?patient ratio in our country (1:1700 as per a Times of India report in 2021), it is very essential to develop self?management mHealth applications. Thus, there is a need to ensure simple and user-friendly mHealth applications to improve customer satisfaction. The goal of this study is to assess and appraise the usability and effectiveness of existing T2DM?focused mHealth applications. TOP? SIS, VIKOR, and PROMETHEE II are three multi?criteria decision?making (MCDM) approaches considered in the proposed work for the evaluation of the usability of five existing T2DM mHealth applications, which include Glucose Buddy, mySugr, Diabetes: M, Blood Glucose Tracker, and OneTouch Reveal. The methodology used in the research work is a questionnaire?based evaluation that focuses on certain attributes and sub?attributes, identified based on the features of mHealth applications. CRITIC methodology is used for obtaining the attribute weights, which give the pri-ority of the attributes. The resulting analysis signifies our proposed research by ranking the mHealth applications based on usability and customer satisfaction. 2021 by the authors. Licensee MDPI, Basel, Switzerland. -
A Framework for Integrating the Distributed Hash Table (DHT) with an Enhanced Blooms Filter in MANET
MANET, a self-organizing, infrastructure-less, wireless network is a fast-growing technology in day-to-day life. There is a rapid growth in the area of mobile computing due to the extent of economical and huge availability of wireless devices which leads to the extensive analysis of the mobile ad-hoc network. It consists of the collection of wireless dynamic nodes. Due to this dynamic nature, the routing of packets in the MANET is a complex one. The integration of distributed hash table (DHT) in MANET is performed to enhance the overlay of routing. The node status updating in the centralized hash table creates the storage overhead. The bloom filter is a data structure that is a space-effective randomized one but it allows the false-positive rates. However, this can be able to compensate for the issue of storage overhead in DHT (Distributed hash table). Hence, to overcome the storage overhead occurring in DHT, and reduce the false positives, the Bloom's filter is integrated with the DHT initially. Furthermore, the link stability is measured by the distance among mobile nodes. The optimal node selection should be done for the transmission of packets which is the lacking factor. If it fails to select the optimal path then the removal of malicious nodes may lead to the unwanted entry of nodes into the other clustering groups. Therefore, to solve this problem, the bloom's filter is modified for enhancing the link stability. The novelty of this proposed work is the integration of Bloom's filter with the Distributed Hash Table which provides good security on transmission data by removing false-positive errors and storage overhead 2022,International Journal of Advanced Computer Science and Applications.All Rights Reserved -
An Empirical Model for Geopolymer Reactions Involving Fly Ash and GGBS
Numerous works are reported in literature regarding the enhancement of compressive strength of fly ash-GGBS geopolymer combinations with addition of alkali activators of varying concentrations. However, a limited study has been chronicled, revealing the specific role of alkali or alkaline earth contributed by the fly ash-GGBS combinations on the compressive strength development. It is well known that the strength of a geopolymer is dependent on gel formation from Al/Si ratio, Ca/Si ratio, and Ca/(Si + Al) ratio but their exact role when cured for various extended periods is unknown as yet. In the present study, alkali concentration in a fly ash-GGBS geopolymer combination was varied from 6 M to 12 M with increments of two mol in six different fly ash-GGBS combinations with a minimum of 20 percent and a maximum of 70 percent GGBS. The correlation coefficients between compressive strength and Al/Si, Ca/Si, and Ca/(Si + Al) ratios exhibited values higher than 0.95 taken individually. Multiple linear regression analysis with compressive strength (as dependent parameter) and individual values of Al/Si, Ca/Si, and Ca/(Si + Al) ratios (as independent parameters) was effectuated. It was observed that, depending on the composition, the compressive strength circumstantiated a changeover from Ca/Si to Ca/(Si + Al) ratio in the intermediate composition range. Such a detailed analysis is considered supportive of developing a suitable composition which will provide the optimum compressive strength of the combination. 2022 Beulah M et al. -
Factors Influencing Consumer Purchasing Behaviour Towards Purchase of Palm Leaf Craft
The handicraft sector plays a significant role in providing employment opportunities in rural and semi-urban areas of the country. It helps in generating substantial income for the artisans. The uses for palm leaves are abundant. Attractive items made of Palm Leaves are very popular in South India, mostly in Southern Andhra Pradesh and Tamil Nadu. However, to generate sustainable revenue through their products, the artisans need to understand the buyers requirements. This study aims to understand the consumers purchasing behavior when buying palm leaf products. The sample consists of 233 consumers with diverse backgrounds from the state of Tamil Nadu, India. A questionnaire was developed to measure awareness and attitude influence while purchasing palm leaf products. The results can help the artisans to get an insight into end-user expectations and requirements toward palm leaf products and suggest strategies to increase the income of artisans. 2022 Taylor & Francis. -
Entropy generation analysis of radiative heat transfer in Williamson fluid flowing in a microchannel with nonlinear mixed convection and Joule heating
In this article, the spectral quasi-linearization (SQLM) method is implemented to solve the complicated differential equations governing the nonlinear mixed convective heat transfer of a Williamson fluid through a vertical microchannel. Unlike the conventional Boussinesq approximation, the quadratic Boussinesq approximation is taken into account in the formulation. The effects of Rosseland thermal radiation, Joule heating, and viscous dissipation are described in the thermal analysis subjected to the boundary conditions of convective thermal heating. The analysis of entropy production is also performed. The importance of various parameters governing velocity, Bejan number, temperature, and entropy generation was explored using graphic illustrations. It was found that the nonlinear density change with a temperature significantly affects the heat transport in the microchannel and thus increases the magnitude of the Bejan number and the production of entropy. Entropy production occurs maximum due to the boundary conditions of convection heating at the walls of the microchannel. Furthermore, due to a stronger viscous heating mechanism, the magnitude of the Bejan number is reduced, while the production of entropy increases significantly. As a limiting case of the problem, a comparison was made with results previously published in the literature and excellent agreement was established. The calculations provide a solid reference point for future CFD models and are relevant to the dynamics of polymers in microfluidic devices and the polymer industries. IMechE 2022. -
Job Crafting: A Systematic Review and Meta-Analytical Relationships with Precursors and Work Outcomes (2001-2021)
Meta-analysis and SEM (structural equation modeling) were used to investigate the relationship between job crafting, job characteristics, work engagement, and job performance. We used random effects of meta-analysis to statistically integrate 199 primary studies and structural equation modeling to examine the assumed moderation through gender and educational levels using Stata: Version 16.0 software. We also ran an exploratory moderator analysis to see any systematic differences in the relationships. The findings revealed that job performance and job characteristics were positively and significantly related at the 1% level, as were job performance, job crafting, and work engagement. All were positively and significantly related at the 1% level. Work engagement and job crafting, too, were positively correlated and statistically significant at the 1% level. Furthermore, p < 0.05 for gender and p < 0.10 for educational level indicated that educational level and gender moderated the relationship between job performance, work engagement, job characteristics, and job crafting significantly. Cronbachs alpha was used to conduct the reliability test, which indicated a good (0.8 < a < 0.9) and excellent (0.9 < a) internal consistency because Cronbachs alpha was more significant than the 0.6 thresholds, and the validity indicated that the model was adequate. 2022, Associated Management Consultants Pvt. Ltd.. All rights reserved.