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Sputter deposited tungsten oxide thin films and nanopillars: Electrochromic perspective
Tungsten oxide (WO3) thin films and nano pillars were grown on FTO and corning substrates by using DC magnetron sputtering. Structural properties, surface morphology, optical properties, and electrochromic properties were systematically characterized by using SEM, XRD, UVVis Spectrometer, and Electrochemical Analyser respectively. Increased oxygen partial pressure resulted a rise in the optical transmittance from 72% to 89% at a wavelength of 600 nm. Moreover, coloration efficiency was also found to vary with partial pressures for both planar and glad from 30.48 cm2C-1 to 78.36 cm2C-1. We observe that glad deposited nano pillars showing higher coloration efficiency as compared to the planar thin film. The coloration efficiency found for the planar thin film and nano pillars at optimized partial pressure are 37.04 cm2C-1 and 78.36 cm2C-1 respectively. A strong influence of oxygen partial pressure and surface to volume ratio has been observed on the coloration efficiency, which can play a major role in the electrochromic application. 2022 Elsevier B.V. -
Theory and Applicability of the Weighted Modified Lindley Distribution
As a bridge between the exponential and Lindley distributions, the modified Lind-ley distribution was created. It has been used successfully in a variety of fields related to survival analysis. In this study, we present a novel distribution that extends the modified Lindley distribution using the traditional weighted (or length/size-biased) approach. It is named as weighted modified Lindley distribution. This idea is mainly used to flexibilize the former modified Lindley distribution through the use of a one-parameter polynomial weight. This weight is intended to modulate the functionalities of the new distribution, well beyond those of the former modified Lindley distribution. The related probability density function, cumulative density function, hazard rate function, moments, moment generating function and characteristic function are analysed from a theoretical and practical point of view. Estimation of the parameters is done by the classical method of maximum likelihood and a simulation study is carried out to check the consistency of the maximum likelihood estimates. A data set is used to illustrate the application of the proposed distribution. 2022, Society of Statistics, Computer and Applications. All rights reserved. -
Natural convection of a binary liquid in cylindrical porous annuli/rectangular porous enclosures with cross-diffusion effects under local thermal non-equilibrium state
The present article reports an analytical study of the double diffusive natural convection (DDNC) in cylindrical porous annuli (CPA) and rectangular porous enclosures (RPE), which are handled in a unified way using the curvature parameter, saturated by a binary liquid under the assumption of local thermal non-equilibrium (LTNE) state. The buoyancy forces (thermal and solutal) driving the flow are assumed to be induced by the maintenance of constant and uniform heat and mass fluxes applied along the vertical (radial) walls and insulation of both horizontal walls of the annuli/rectangular enclosures. The Darcy-Boussinesq equations with LTNE assumption between the fluid and solid phases are employed to model the problem of DDNC in a binary liquid-saturated porous medium with cross-diffusion effects. The analytical results are obtained by employing the Oseen-linearization transformation technique in the study. The influence of various dimensionless parameters on heat and mass transports of the system are depicted using the Nusselt and Sherwood numbers and isotherms plots, and the obtained results are analysed with the physical explanation. Special attention is given to understand the effect of LTNE parameter and cross-diffusion parameters on heat and mass transports of the system. Different aspect ratio values are chosen to obtain the results of three types of CPA/RPE (shallow, square and tall). Among these CPA/RPE, maximum and minimum heat and mass transports are achieved in the cases of shallow and tall CPA/RPE, respectively. The results of the pure thermal convection problem is obtained at the zero value of buoyancy ratio and solute Rayleigh number. The increasing value of N magnifies the heat and mass transports in the system due to the augmented buoyancy effect resulted from the thermal and solutal gradients. The increase of solid inner cylinder radius, by fixing its volume, makes the annulus slender which yields to decrease the heat and mass transports in the system. The effects of LTNE parameter and cross-diffusion parameters on heat and mass transports of the system are clearly brought out. The results of LTE model are obtained at the infinite value of ratio of porosity modified thermal conductivities, ?, as a particular case of the present model. From the study, we conclude that the shallow porous annulus and tall rectangular enclosure are best suited in the design of heat removal and heat storage systems, respectively. 2021 -
On ?(k)-coloring of powers of helm and closed helm graphs
If the availability of colors to color a graph G is less than that of the chromatic number ?(G) of the graph, then coloring the graph with available colors, say k colors, where 1 ? k ? ?(G)-1, will cause the end vertices of at least one edge to be colored with same color. Such an edge whose end vertices receive a same color is called as a bad edge. A coloring that restricts few color classes to have adjacency between the elements in it so as to minimize the number of bad edges obtained from it in a graph G is called as a near proper coloring and a near proper coloring that uses k colors where 1 ? k ? ?(G)-1 to color a graph G by permitting only one color class to have adjacency among the elements in it and thereby minimize the number of bad edges resulting from the permitted color class is called as a ?(k)-coloring of the graph G. In this paper, we determine the number of bad edges of powers of helm graphs H1,nr and powers of closed helm graphs CH1,nr. 2022 World Scientific Publishing Company. -
Psychological capital and innovative work behaviour: The role of mastery orientation and creative self-efficacy
Continuous innovation is what helps companies survive the highly discontinuous competition. Securing innovative work behaviour from employees has drawn the attention of businesses and researchers alike. The current work draws on broaden-and-build theory and goal orientation theory to propose how an individual's psychological capital, which is malleable, helps in achieving innovative work behaviour from employees. The study has been conducted in the context of three-star hotels located in and around New Delhi, the capital of India. The data was collected using standard scales from a dyad of 229 employees and their managers. The present study enriches the innovative work behavior literature by combining different perspectives in a coherent framework and demonstrates the partially mediated positive relationship of psychological capital and innovative work behavior via mastery orientation. Also, the study reveals that the partially mediated indirect effect varies among employees based on their level of CSE. 2022 Elsevier Ltd -
Enzyme based bioelectrocatalysis over laccase immobilized poly-thiophene supported carbon fiber paper for the oxidation of D-ribofuranose to D-ribonolactone
A modified electrode based on laccase immobilized poly-thiophene-3-carboxylic acid supported on carbon fiber paper was developed for the electrocatalytic oxidation of D-ribofuranose to otherwise difficult-to-access D-ribonolactone, a precursor for C-nucleoside based drug like Remdesivir. The electrochemical oxidation of D-ribofuranose was achieved by the TEMPO-mediated electrochemical process. The experimental parameters were optimized and validated using Design of Experiment (DoE) statistical tool indicating the concentration of TEMPO and stirring as important parameters in bulk electrolysis. The mechanism for the electrochemical oxidation of D-ribofuronose followed single electron anodic oxidation of TEMPO mediated by laccase to the corresponding oxoammonium nitrosonium species which was vital for the mediated electrochemical oxidation. The mechanism for the electrochemical oxidation was established using cyclic voltammetry and computational studies. The plausible interactions of laccase enzyme with TEMPO mediator were studied using molecular docking experiments. This facile method was successfully applied for the oxidation of D-ribofuranose to D-ribonolactone. 2022 -
Three-Component Convection in a Vertically Oscillating Oldroyd-B Fluid With Cross Effects
This paper sheds light on the impact of vertical oscillations (or gravity modulation) on triple-diffusive convection in a viscoelastic fluid using the Oldroyd-B model, in the presence of cross effects. Cross effects can significantly impact three-component convective systems, despite having small magnitudes. When the cross terms, indicating coupled molecular cross-diffusion of the mixture components, are included in the equations governing heat and species transport, then a deviation from the usual three-component convection process is observed. An analytical solution has been found using linear and nonlinear analysis. The conditions for the onset of convection have been obtained using the linear analysis, which is based on the perturbation technique and the Venezian method. In nonlinear analysis, the expressions for Nusselt and Sherwood numbers, which quantify the rate of heat and mass transport respectively, are obtained by deriving the Lorenz model. It has been found that the onset of convection and heat and mass transport can be controlled by choosing the appropriate values of the parameters. 2022, The Author(s), under exclusive licence to Springer Nature B.V. -
The Content of Heavy Metals in Cigarettes and the Impact of Their Leachates on the Aquatic Ecosystem
Smoked cigarettes and butts are the most common kind of litter around the world. The buildup of these litters has badly polluted local water bodies and their compartments, and the cumulative effect of many cigarette butts scattered in a centralized location may pose a serious hazard to living species. To understand how heavy metals are leached out into the aquatic ecosystem, researchers must analyse the behavior of the materials that make up cigarettes. Using atomic absorption spectrometry, this study evaluated the content of several metals (such as Cd, Cu, Fe, Pb, Sn, Zn, and Hg) leached from various brands of unsmoked and smoked cigarettes and cigarette butts. The findings revealed that heavy metal is more prevalent in butte. These findings indicate that cigarette litter is a major source of metal contamination in the aquatic ecosystem and that apparent leaching may increase the risk of toxicity to aquatic organisms. 2022 by the authors. Licensee MDPI, Basel, Switzerland. -
Framing and control for sustainability of industries
Purpose: The paper attempts to frame the challenge of managing the transition to a sustainable economy by way of a conceptual model consisting of a zero-footprint regulatory regime and a sustainability fund. Design/methodology/approach: A conceptual model of the sustainable industrial revolution has been developed based on the learnings from industries such as originators (mining), farming, pharmaceuticals, pesticides and chemicals and long-lasting artefacts against an overall perspective. Findings: It is suggested to have an institutional structural mechanism in place to ensure that footprint is minimized through recycling including refurbishing, resale or transformation. This includes management of recycling businesses through execution of a zero-waste regulatory regime that will build and use a sustainability fund. Research limitations/implications: The limitations of the paper are arising out of the topic being an issue of gigantic proportions with immense complexity. An attempt has been made to bring out the inescapability and the imperative of a sustainable industrial revolution. Practical implications: This paper presents practical aspects such as collusion between trash and recycling businesses, land use and social aspects of criticality of public support. If implemented, the suggested model can make a paradigm shift in the way firms, industry and governments can handle the challenge of sustainability. Originality/value: The value of this conceptual paper lies in an attempt to extend the learning organization framework to the concept of a regulatory model for sustainability that is not limited to the definition of a firm but stands extended to industries and to the economics, land use and demographics of the planet. 2021, Emerald Publishing Limited. -
Forbidden Cravings: Exploring socio-cultural ramifications of food practices in Aamis
Food choices represent conscious affirmation and expression of personal, group, ethnic or national identity. Due to its multidimensional role, food that we rely on sustenance is often politicised and used as a tool to create conflict amongst and within diverse social groups. Assamese cuisine includes a rich platter of authentic food varieties, often limited to the north-eastern region. Although food consumption is a subjective experience, cultural taboos within a community might be acceptable practices in another culture, creating conflicting notions of food practices. The balance between the twin axis of culture and politics regarding food is disrupted when heterogeneous cultural patterns and opposing political notions are in discord. Similarly, the solidarity within a cultural group becomes hostile when the authority of the individual concerning food choices is not aligned with the authority of the social structure. This discord from a political and cultural standpoint is evident in the Assamese socio-cultural scenario. Taking Bhaskar Hazarika's Ravening/Aamis (2019) as a case study, this paper proposes to analyse the representational troupe of food, through a structuralist anthropological lens, with respect to food politics to understand socio-cultural ramifications of Assamese food patterns. 2022 Aesthetics Media Services. All rights reserved. -
Optical and Electrochromic Properties of CeO2/WO3 Hybrid Thin Films Prepared by Hydrothermal and Sputtering
Innovative chromogenic nanostructures like hybrids but also composite materials can be increased electrochromic efficiency because of their prospective application values in low-power displays, smart windows, electronic papers, and car anti-reflect mirrors. We used a hydrothermal approach to make Cerium oxide Nanorods have various ratios in this report. DC magnetron sputtering procedures cover the generated cerium oxide nanorods of various diameters with a tungsten oxide layer in one step. the surface plasmon effect varies depending on the size of Ce Nanorods, and this phenomenon impacts electrochromic results. the electrochromic performances of CeO2/WO3 nanorods on FTO-coated glass slides are examined using a 0.5 M solution of H2SO4 as the electrolyte in the visible range. These structures produce considerable optical modulation (47 %, 45 %, and 41 % at 700 nm) and coloration efficiency (11.6, 7.57, and 10.84 cm2C-1 at 700 nm). 2022 Seventh Sense Research Group -
Applications of bioconvection for tiny particles due to two concentric cylinders when role of Lorentz force is significant
The bioconvection flow of tiny fluid conveying the nanoparticles has been investigated between two concentric cylinders. The contribution of Lorenz force is also focused to inspect the bioconvection thermal transport of tiny particles. The tiny particles are assumed to flow between two concentric cylinders of different radii. The first cylinder remains at rest while flow is induced due to second cylinder which rotates with uniform velocity. Furthermore, the movement of tiny particles follows the principle of thermophoresis and Brownian motion as a part of thermal and mass gradient. Similarly, the gyro-tactic microorganisms swim in the nanofluid as a response to the density gradient and constitute bio-convection. The problem is modeled by using the certain laws. The numerical outcomes are computed by using RKF-45 method. The graphical simulations are performed for flow parameters with specific range like 1?Re?5, 1?Ha?5, 0.5?Nt?2.5, 1?Nb?3, 0.2?Sc?1.8, 0.2?Pe?1.0 and 0.2???1.0. It is observed that the flow velocity decreases with the increase in the Hartmann number that signifies the magnetic field. This outcome indicates that the flow velocity can be controlled externally through the magnetic field. Also, the increase in the Schmidt numbers increases the nanoparticle concentration and the motile density. 2022 Zhang et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. -
An Enhanced SEIR Model for Prediction of COVID-19 with Vaccination Effect
Currently, the spread of COVID-19 is running at a constant pace. The current situation is not so alarming, but every pandemic has a history of three waves. Two waves have been seen, and now expecting the third wave. Compartmental models are one of the methods that predict the severity of a pandemic. An enhanced SEIR model is expected to predict the new cases of COVID-19. The proposed model has an additional compartment of vaccination. This proposed model is the SEIRV model that predicts the severity of COVID-19 when the population is vaccinated. The proposed model is simulated with three conditions. The first condition is when social distancing is not incorporated, while the second condition is when social distancing is included. The third one condition is when social distancing is combined when the population is vaccinated. The result shows an epidemic growth rate of about 0.06 per day, and the number of infected people doubles every 10.7 days. Still, with imparting social distancing, the proposed model obtained the value of R0 is 1.3. Vaccination of infants and kids will be considered as future work. 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/). -
Investigating the contrast diurnal relationship of land surface temperatures with various surface parameters represent vegetation, soil, water, and urbanization over Ahmedabad city in India
Many climatic problems have arisen due to congested and inefficient planning, reduced vegetation cover, and increased pollution from factories and vehicles. One such primary concern is increased land surface temperature (LST) contributes to the urban heat island (UHI) occurrence. This research aims to understand better the UHI effect in the region neighbouring the Indian city of Ahmedabad. MODIS sensor data (onboard Aqua and Terra platforms) and Landsat data were used for the study. The research was done for the summer, monsoon, and winter seasons in the research region, using data from thirteen years between 2003 and 2015. The current study looked at LSTs' spatial and temporal differences to assess the SUHI effect over Ahmedabad city. The association between diurnal LST and various surface variables such as vegetation, built-up, soil, water, and so on has also been examined. A variety of land surfaces influences the diurnal variations of LSTs. The diurnal associations of LST with vegetation, urbanization, soil, and water factors have been studied. The overall study of LST' relationship with all of the various parameters reveals a very significant dynamic relationship. 2022 The Author(s) -
Numerical surfaces of fractional Zika virus model with diffusion effect of mosquito-borne and sexually transmitted disease
This paper analyzes the dynamics of fractional partial differential equation (FPDE) model of Zika virus that incorporates diffusion using AtanganaBaleanu (AB) fractional derivative. Zika virus disease is an infection transmitted predominantly by the bite of an infected Aedes species mosquito and may be a severe epidemic if not contained in its premature stages. The q-homotopy analysis transform method is employed to analyze and compute the solutions for this nonlinear partial differential model, and the fractional derivative is defined in AtanganaBaleanu sense. We determine some new approximate numerical results for different values of parameters of alpha. Numerical models focused on various distributions of the population help to explain how the spread of humans and mosquitoes influences the disease's transmission. With the utilization fixed-point hypothesis, the existence and uniqueness of the solutions obtained for the proposed model are presented. 2021 John Wiley & Sons, Ltd. -
Impact of COVID-19 on NSE Sectoral Indices
The paper examined the level of impact of COVID-19 on different sectors of the Indian economy using NSE sectoral indices under the event study methodology. Multiple events and event windows were considered to examine the sectoral impact of the pandemic on different events and at various stages of the outbreak. Amongst the specific events considered, the lockdown announcement had a significant impact on sectoral indices, whereas the stimulus package announcement had limited impact and the 1st COVID-19 case had no impact on sectoral indices. The impact was intensive in the prelockdown period leading to the intensive lockdown, there was not much impact in other phases. The overall impact of the COVID-19 outbreak was significantly negative on Banks, Financial Services, and Realty indices, and positive on Pharma and FMCG indices. The media index showed no significant impact of the pandemic. Indian Institute of Finance. -
Optimal allocation of solar photovoltaic distributed generation in electrical distribution networks using Archimedes optimization algorithm
This paper proposes to resolve optimal solar photovoltaic (SPV) system locations and sizes in electrical distribution networks using a novel Archimedes optimization algorithm (AOA) inspired by physical principles in order to minimize network dependence and greenhouse gas (GHG) emissions to the greatest extent possible. Loss sensitivity factors are used to predefine the search space for sites, and AOA is used to identify the optimal locations and sizes of SPV systems for reducing grid dependence and GHG emissions from conventional power plants. Experiments with composite agriculture loads on a practical Indian 22-bus agricultural feeder, a 28-bus rural feeder and an IEEE 85-bus feeder demonstrated the critical nature of optimally distributed SPV systems for minimizing grid reliance and reducing GHG emissions from conventional energy sources. Additionally, the voltage profile of the network has been enhanced, resulting in significant reductions in distribution losses. The results of AOA were compared to those of several other nature-inspired heuristic algorithms previously published in the literature, and it was observed that AOA outperformed them in terms of convergence and redundancy when solving complex, non-linear and multivariable optimization problems. The Author(s) 2022. -
Root cause analysis of COVID-19 cases by enhanced text mining process
The main focus of this research is to find the reasons behind the fresh cases of COVID-19 from the publics perception for data specific to India. The analysis is done using machine learning approaches and validating the inferences with medical professionals. The data processing and analysis is accomplished in three steps. First, the dimensionality of the vector space model (VSM) is reduced with improvised feature engineering (FE) process by using a weighted term frequency-inverse document frequency (TF-IDF) and forward scan trigrams (FST) followed by removal of weak features using feature hashing technique. In the second step, an enhanced K-means clustering algorithm is used for grouping, based on the public posts from Twitter. In the last step, latent dirichlet allocation (LDA) is applied for discovering the trigram topics relevant to the reasons behind the increase of fresh COVID-19 cases. The enhanced K-means clustering improved Dunn index value by 18.11% when compared with the traditional K-means method. By incorporating improvised two-step FE process, LDA model improved by 14% in terms of coherence score and by 19% and 15% when compared with latent semantic analysis (LSA) and hierarchical dirichlet process (HDP) respectively thereby resulting in 14 root causes for spike in the disease. 2022 Institute of Advanced Engineering and Science. All rights reserved. -
An Improved Alternative Method of Imputation for Missing Data in Survey Sampling
In the present paper, a new and improved method of ratio type imputation and corresponding point estimator to estimate the finite population mean is proposed in case of missing data problem. It has been shown that this estimator utilizes the readily available auxiliary information efficiently and gives better results than the ratio and mean methods of imputation; furthermore, its efficiency is also compared with the regression method of imputation and some other imputation methods, discussed in this article, using four real data sets. A simulation study is carried out to verify theoretical outcomes, and suitable recommendations are made. 2022 NSP Natural Sciences Publishing Cor. -
Challenges of Treating Bilingual and Multilingual Stuttering
[No abstract available]