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A simple and efficient synthesis of imidazoquinoxalines and spiroquinoxalinones via pictect-spengler reaction using Wang resin
An efficient approach for the synthesis of various imidazoquinoxalines and spiroquinoxalinones has been reported from 2-(1H-imidazol-1-yl) aniline and different aldehydes using Wang-OSO3H as a reusable catalyst to get in good yields. The reaction condition has been optimized by screening in various solvents and a gram scale experiment has also demonstrated. Further, the substrate scope of the reaction has also been well demonstrated. 2021 Taylor & Francis Group, LLC. -
A Simple and Efficient [(n-Bu3Sn)2MO4]n Catalyzed Synthesis of Quinazolinones and Dihydroquinazolinones
A novel unprecedented approach for the synthesis of various quinazolinones and dihydroquinazolinones has been using [(n-Bu3Sn)2MO4]n as a catalyst. The reaction has been screened in various solvents and a gram scale experiment has also been demonstrated under given conditions. Further, the substrate scope of the reaction and the recyclability of the catalyst have also been studied. 2021 Taylor & Francis Group, LLC. -
Digital and Artificial Intelligence in Education
The article examines the relationship between digital intelligence and artificial intelligence, with an emphasis on the pedagogical aspects of this problem. The author emphasizes that the creation of AI requires not only technical literacy, but also developed digital thinking, supported by clear ethical principles. Particular attention is paid to the role of modern education in the formation of such specialists - the school should educate not just IT specialists, but people who are able to responsibly use technology. The work analyzes the various levels of digital competencies required in professional activities, and also provides an overview of scientific publications on the implementation of artificial intelligence in the educational process. The study demonstrates how important it is to combine technological progress with humanistic values in the training of future personnel. The Author(s), under exclusive license to Springer Nature Switzerland AG 2025. -
Analysis of food consumption expenditure patterns for developing sustainable business practices
Food consumption patterns are said to be near ideal variable since it is one of the most important commodities that ensure human survival. The patterns within the consumption as well as between different types of food items to different levels of consumption varies with respect to the macroeconomic conditions. The consumption expenditure for cereals, pulses and pulse products, edible oil, milk and milk products, meat, fish and egg, vegetables and fruits, shows an increasing trend in India and in Karnataka. The income elasticity for all food categories are lesser in urban sectors of Karnataka than the rural sector which indicates that the income of the rural households is lesser and the increase in income is also lesser compared to that of the Urban-Karnataka. The business enterprises can aim at sustainable consumption practices through the pricing strategies, product design and distribution channels. 2021 Ecological Society of India. All rights reserved. -
Bioremediation and Detoxification of Asbestos from Soil
Asbestos is referred to as magic mineral and used as excellent building material. It finds its application in wide range of products such as floor tiles, pipes, paper, rope, cloth, insulated partition board, etc. On average, India uses 3, 50, 000 tons of asbestos annually and asbestos fibers readily undergo weathering releasing them into soil, water and air. Occupational and environmental exposure to this asbestos is leading to asbestosis (asbestos-related disease), lung cancer, and heart failure. Considering the serious health risk, countries like Australia, Brazil, and Canada had banned the use of asbestos. As asbestos is extensively used in construction of buildings, the demolished materials are dumped in the soil and thus it finds its route in soil as pollutant. Soil borne microbes like bacteria, fungi and lichens are found to be best means to reduce the toxicity of asbestos. These microorganisms remove iron from asbestos and reduce its toxicity. Another most effective bioremediation approach is phytoremediation to clean up the soil wherein vegetative cover on contaminated soil can remove iron and breaks down asbestos as source of inorganic nutrient. The main advantage of phytoremediation is that it can be extended to any geographical area where plants can grow. This chapter emphasizes various means of use and disposal of asbestos, followed by various means of bioremediation using microbes and plants and as an alternate for the sustainable soil condition. The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG 2022, corrected publication 2022. -
The effect of an environmental education program based on empathy and reflective thinking on preadolescents environmental values and knowledge
As a remedial measure to human-induced climate change, it is imperative to develop intrinsic altruistic values and adequate knowledge of environmental phenomena and behavior to act in favor of the environment. The study aims to assess the effect of an Environmental Education Program (EEP) based on empathy, reflective thinking, and information on preadolescents environmental values and knowledge. For that, a non-equivalent control group design was used. Data collection was done through questionnaires, checklists, and participant thought diaries. Forty-six students (eleven-to-twelve-year-old children) selected through purposive sampling from the sixth standard of two semi-urban schools in Kerala, India, constituted the sample. In the intervention, empathy was manipulated through stories and empathy exercises, reflective thinking through thought diaries, and information on environmental phenomena, issues, and the effect of human actions through stories and knowledge exercises. Empathy, reflective thinking, and information manipulations positively influenced the participants environmental values and knowledge, and the effect manifested in cognitive, affective, and conative dimensions. The study has implications for conducting Environmental Education indoors effectively by integrating affective, cognitive, and metacognitive approaches. Empathy stories can be utilized to address various environmental phenomena and issues. Reflective thinking on environmental phenomena and issues can be applied to teach appropriate environmental behaviors. 2024 Informa UK Limited, trading as Taylor & Francis Group. -
Environmental value development among preadolescents: a content analysis of reflective responses
Addressing the environmentally detrimental values prevalent in society in the context of rapid climate change is the need of the hour. Combining empathy with cognitive skills such as reflective thinking effectively creates new values among people. The present study attempts to reveal the pattern of environmental value development among 33 preadolescents by reflecting upon the empathy-generating story experiences and the related contents. The study is part of a more extensive quasi-experimental study, and it specifically performs a content analysis on the participants responses in their workbooks. Biospheric nature-related values are the most highly developed, and social justice is the least developed value, implying the need to focus more on the value of social justice. Stories are aids, and reflective thinking and empathetic elicitation are effective techniques for passing environmental values. Empathy generation instead of negative emotions from self-concern and emotion regulation through reflective thinking may be helpful to promote well-being in the context of climate change. Reflective thinking helps environmental value development by enhancing comprehension, emotion regulation, and self-awareness of values, implying a shift from telling the moral of a story to exploring the same through reflective thinking. 2025 Informa UK Limited, trading as Taylor & Francis Group. -
A Self-Reflective and Empathy Based Environmental Education Intervention to Enhance Environmental Values and Knowledge of Preadolescents
Environmental degradation and climate change have become common phenomena and they are attributable to human actions focusing solely on economic growth. Therefore, it is necessary to fetch drastic changes in the lifestyles of majority of the public and to acquire the collective capacity of ecological intelligence. The accumulation of ecological intelligence results in environmental knowledge, values, and skills to deal effectively with the environment. The present study is an attempt to develop and apply a self-reflection and empathy-based Environmental Education module for 11-12 years old children to enhance their environmental values and knowledge. The study utilized a pre-test post-test quasi experimental design for which two existing sixth grade classes (intervention group and control group) from different schools, selected through purposive sampling formed the sample. A pre-test and a post-test were conducted on the participants environmental values, attitude, knowledge for the intervention and control groups. Additionally, environmental behaviour, self-reflection and insight were assessed before and after the intervention and the student workbooks were undergone content analysis for the intervention group. The self- reflective and empathy-based Environmental Education intervention was administered for the class selected as the intervention group in between the pre and post-tests. The researcher observed the interventions effectiveness on environmental values with the help of the attitude scale of the Children's Environmental Attitude and Knowledge Scale (CHEAKS), through the content analysis of student workbooks, and through session feedback form. The positive impact of the intervention on environmental knowledge was understood from the analysis of the knowledge scale of the Children's Environmental Attitude and Knowledge Scale (CHEAKS) and from the session feedback form. Additionally, there is an improvement in the intervention groups reflective thinking ability and environmental behaviour when assessed through Self-Reflection and Insight Scale for Youth and parent observation checklist. The study has implications concerning the implementation of Environmental Education. -
Monoclonal antibodies targeting the Erns protein of classical swine fever virus: application for virus detection
Classical swine fever (CSF), caused by the classical swine fever virus (CSFV; genus Pestivirus), is a highly transmissible disease in pigs that leads to severe economic losses for pig farmers worldwide. Early and accurate diagnosis of CSFV infections is crucial for effective containment of the disease, especially in endemic areas. In this study, the full-length viral protein Erns was successfully expressed in E. coli. The recombinant protein was purified using Ni-NTA affinity chromatography, and its antigenicity confirmed by western blot and indirect ELISA (iELISA) using CSFV-specific antiserum. The purified Erns protein was then used as an immunogen to generate murine hybridomas producing monoclonal antibodies (mAbs). A panel of 15 mAbs targeting this protein was characterized using iELISA and western blotting, for their ability to react with native antigens in cultures infected with CSFV. These mAbs have the potential to be used in the development of diagnostic tools, particularly for the detection and titration of virus-infected cultures through endpoint dilution assays. 2025 Elsevier B.V. -
Internet chat based intervention as a mode for therapy and counselling
Increasing mental health issues in India demands for a strong intervention to curb the rise. According to the World Health Organization, roughly around 21 Indians out of 100,000 die by suicide every year. The burden on mental health domain increases due to the existing system as most of the existing services follow a traditional approach and are most sought after but lack reachability and ease of access. This study recognises the need for programmes that help in reachability and ease of access while simultaneously maintaining anonymity, therefore, analyses the impact of chat-based therapy provided online through the platform. The paper analyses the difference in subjective unit of well-being (SUW) pre and post chat-based sessions among 2624 college students and 805 corporate employees. The Wilcoxon signed rank test between pre and post intervention indicates significant results with the p < 0.001 (Z = -44.100a) suggesting and increase in SUW scores post intervention. Further, the Kruskal-Wallis test revealed that the gender of the clients has an association with the SUW scores (p < 0.05). It was also found that the duration of the sessions had a positive relation with the impact scores (p < 0.001). The Author(s), 2025. -
The effect of an environmental education program based on empathy and reflective thinking on preadolescents environmental values and knowledge
As a remedial measure to human-induced climate change, it is imperative to develop intrinsic altruistic values and adequate knowledge of environmental phenomena and behavior to act in favor of the environment. The study aims to assess the effect of an Environmental Education Program (EEP) based on empathy, reflective thinking, and information on preadolescents environmental values and knowledge. For that, a non-equivalent control group design was used. Data collection was done through questionnaires, checklists, and participant thought diaries. Forty-six students (eleven-to-twelve-year-old children) selected through purposive sampling from the sixth standard of two semi-urban schools in Kerala, India, constituted the sample. In the intervention, empathy was manipulated through stories and empathy exercises, reflective thinking through thought diaries, and information on environmental phenomena, issues, and the effect of human actions through stories and knowledge exercises. Empathy, reflective thinking, and information manipulations positively influenced the participants environmental values and knowledge, and the effect manifested in cognitive, affective, and conative dimensions. The study has implications for conducting Environmental Education indoors effectively by integrating affective, cognitive, and metacognitive approaches. Empathy stories can be utilized to address various environmental phenomena and issues. Reflective thinking on environmental phenomena and issues can be applied to teach appropriate environmental behaviors. 2024 Informa UK Limited, trading as Taylor & Francis Group. -
Environmental value development among preadolescents: a content analysis of reflective responses
Addressing the environmentally detrimental values prevalent in society in the context of rapid climate change is the need of the hour. Combining empathy with cognitive skills such as reflective thinking effectively creates new values among people. The present study attempts to reveal the pattern of environmental value development among 33 preadolescents by reflecting upon the empathy-generating story experiences and the related contents. The study is part of a more extensive quasi-experimental study, and it specifically performs a content analysis on the participants responses in their workbooks. Biospheric nature-related values are the most highly developed, and social justice is the least developed value, implying the need to focus more on the value of social justice. Stories are aids, and reflective thinking and empathetic elicitation are effective techniques for passing environmental values. Empathy generation instead of negative emotions from self-concern and emotion regulation through reflective thinking may be helpful to promote well-being in the context of climate change. Reflective thinking helps environmental value development by enhancing comprehension, emotion regulation, and self-awareness of values, implying a shift from telling the moral of a story to exploring the same through reflective thinking. 2025 Informa UK Limited, trading as Taylor & Francis Group. -
Development of classical swine fever virus E2-protein based indirect ELISA for detection of antibodies against the virus in pigs
Classical swine fever (CSF) is an economically important and highly contagious disease of pigs caused by CSF virus, genus Pestivirus. Serological diagnosis of the disease is highly valuable for surveillance and thereby containment of spread of the disease. In this study, we have demonstrated the development of CSFV envelope glycoprotein E2-based indirect ELISA (E2-iELISA) for the detection of CSFV specific antibodies. The full-length E2 protein was expressed in E. coli and the purified protein was used as a coating antigen in indirect ELISA for detecting CSFV specific antibodies in pigs. A panel of 506 pig sera samples was used to validate the ELISA and the results were highly comparable to the results obtained with the commercial antibody detection kit (PrioCHECK CSFV Ab kit). The in-house E2-iELISA demonstrated high diagnostic sensitivity (95.4%) and specificity (95.5%), highlighting its potential application for sero-surveillance or monitoring of the disease in the swine population. The Author(s), under exclusive licence to Springer Nature B.V. 2024. -
Internet chat based intervention as a mode for therapy and counselling
Increasing mental health issues in India demands for a strong intervention to curb the rise. According to the World Health Organization, roughly around 21 Indians out of 100,000 die by suicide every year. The burden on mental health domain increases due to the existing system as most of the existing services follow a traditional approach and are most sought after but lack reachability and ease of access. This study recognises the need for programmes that help in reachability and ease of access while simultaneously maintaining anonymity, therefore, analyses the impact of chat-based therapy provided online through the platform. The paper analyses the difference in subjective unit of well-being (SUW) pre and post chat-based sessions among 2624 college students and 805 corporate employees. The Wilcoxon signed rank test between pre and post intervention indicates significant results with the p < 0.001 (Z = -44.100a) suggesting and increase in SUW scores post intervention. Further, the Kruskal-Wallis test revealed that the gender of the clients has an association with the SUW scores (p < 0.05). It was also found that the duration of the sessions had a positive relation with the impact scores (p < 0.001). The Author(s), 2025. -
Rapid Prototyping Methods in Manufacturing of Biomedical Implants: A Review
The advancements in science and technology have given the flexibility in various levels for the scientists to manufacture variety of components. Rapid prototyping is one of the most sought-after techniques in the field of biomedical engineering for material manufacture. Bio-inertness, biocompatibility, and manufacturability are the desirable properties for biomedical applications. The review aims to provide a valuable contribution to the biomedical field, by identifying and comparing the rapid prototyping methods on the basis of time, quality, and cost. This work is dedicated to study, identify, and compare different methods of rapid prototyping in the manufacture of biomedical implants, the materials used for these processes. It also encompasses comparison of the process parameters for each manufacturing method and the advantages and disadvantages of the processes. Polysiloxane, hydroxyapatite, bioceramics, and titanium alloys due to its bio-inertness and nontoxic nature are some of the identified materials in the current review of the research. The highly sophisticated and complex biomedical implant manufacturing by various methods was studied and compared. Immense researches are being carried out in this novel field and are more prevalent in biomedical field due to its beautiful characteristics. The rapid advanced technological methods facilitate immediate intervention and faster treatment of the patient which reduces the risk and helps in faster recovery. 2020, Springer Nature Singapore Pte Ltd. -
Evaluation of Mechanical Properties and Microstructure of Polyester and Epoxy Resin Matrices Reinforced with Jute, E-glass and coconut Fiber
Composite manufacturing is a novel branch of science and often finds numerous applications in several industries. Some of them are sport, automobile, aerospace and marine industries. Some of the properties that can be highlighted are good mechanical properties along with stiffness and comparatively lighter weight. There is a continuous research in this area is as the constant pursuit to achieve greater performance by changing various materials and the combinations of those with various resins are experimented. In the current work, polyester and epoxy resins were reinforced with coconut, E-glass and jute fibers of 5-6mm length and were prepared by hand layup method. The fiber and resin were taken in 18:82 weight percentages. Post production of the composites they were subjected to various physical mechanical and microstructural studies to determine various properties. The morphological features were analyzed through the microstructural study done through scanning electron microscope. In comparison with the composites manufactured, The artificial fiber reinforced composite, E-glass fiber reinforced epoxy composites exhibited superior tensile strength, flexural strength, impact toughness and hardness values. Among the natural fiber reinforced composite, coconut fiber reinforced composites exhibited better tensile, impact and hardness than its counterpart jute reinforced composites. Thus the resins reinforced with E-glass fiber had the highest mechanical properties when compared with jute fiber reinforced composites (JFRC) and coconut fiber reinforced composites (CFRC). The cost effectiveness of the natural fiber reinforced composites is also an added advantage over the artificial fiber reinforced composites. 2018 Elsevier Ltd. -
Explainable IoT Forensics: Investigation on Digital Evidence
This research examines the relevance of digital forensics in the field of Internet of Things and describes how different forensics tools and software are used to investigate cybercrimes. It emphasizes the importance of IoT Forensics and how it's used to tackle cybercrimes. It also discusses on the challenges faced by IoT forensics and gives an insight into the recent advancements in the field. It gives a walkthrough about how digital forensics investigation is done in 'data stolen' or 'data deleted' scenario. An outline of research potential and problems in IoT forensics is given in this chapter. The main details of IoT forensics are described. In all stages of a forensic investigation, issues linked to IoT are highlighted along with the potential that IoT presents for forensics. An illustration of an IoT forensics case is given with appropriate analytics. A brief research overview is provided, with information on the important research directions and a review of relevant articles. Future research proposals are included in the chapter's conclusion. 2023 IEEE. -
Nanostructured Carbon Materials from Plant Extracts
Nanostructured Carbon Materials from Plant Extracts: Synthesis, Characterization, and Applications guides the reader through the preparation and utilization of carbon nanomaterials based on various biomass sources, including fruits, vegetables, leaves, pulp and other plant extracts. The book covers the fundamentals of nanostructured carbon materials and synthesis methods from a range of plant sources. Other chapters focus on characterization, analysis, simulation and modeling in order to prepare plant extract based carbon nanomaterials with the required properties. Final sections highlight key application areas, presenting methods and approaches to prepare these materials for specific uses. This book will be of interest to researchers and advanced students across nanomaterials, polymer science, composite science, sustainable materials, chemistry, chemical engineering, and materials science, as well as industrial scientists, engineers, and R&D professionals with an interest in sustainable carbon nanomaterials. 2025 Elsevier Inc. All rights reserved. -
Strategies to achieve carbon neutrality and foster sustainability in data centers
Data centers and transmission networks are crucial in the digital age, with the market expected to grow from $50 billion in 2021 to $120 billion by 2030. However, their extensive computing infrastructure and continuous operation generate significant heat, necessitating energy-intensive cooling systems. The IEA report revealed that data center power consumption surged by over 60% between 2015 and 2021, with transmission networks experiencing a 60% usage increase. Addressing these growing energy demands poses significant challenges for the industry, with some countries considering restrictions on new data center licenses due to environmental concerns. To mitigate the climate impact, the industry must prioritize the procurement of low-carbon or carbon-free electricity to reduce Scope 2 emissions related to electricity, heating, and cooling. Tech giants like AWS, Google, and Meta/Facebook have already adopted ambitious public targets, either running on carbon-free electricity or investing in global projects for cost-effective and large-scale emissions reduction. 2024, IGI Global. -
Performance Analysis of Nonlinear Companding Techniques for PAPR Mitigation in 5G GFDM Systems
Generalized Frequency Division Multiplexing (GFDM) is a 5G waveform contender that offers asynchronous and non-orthogonal data transmission, featuring several advantages, some of them being low latency, reduced out-of-band (OOB) radiation and low adjacent channel leakage ratio. GFDM is a non-orthogonal multicarrier waveform which enables data transmission on a time frequency grid. However, like orthogonal frequency division multiplexing and many other multicarrier systems, high peak-to-average power ratio (PAPR) is one of the main problems in GFDM, which degrades the high-power amplifier (HPA) efficiency and distorts the transmitted signal, thereby affecting the bit error rate (BER) performance of the system. Hence, PAPR reduction is essential for improved system performance and enhanced efficiency. Nonlinear companding techniques are known to be one of the effective low complexity PAPR reduction techniques for multicarrier systems. In this paper, a GFDM system is evaluated using mu law companding, root companding and exponential companding techniques for efficient PAPR reduction. The PAPR and BER graphs are used to evaluate the proposed methods in the presence of an HPA. Simulations show that, out of these three techniques, exponential companding was found to provide a trade-off between the PAPR reduction and BER performance. 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.