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An aqueous phase TEMPO mediated electrooxidation of 2-thiophenemethanol using MnO2-Pi dispersed nanocarbon spheres on a carbon fiber paper electrode
An environmentally benign and economic method was developed for the electrocatalytic oxidation of 2-thiophenemethanol in an aqueous acidic medium. Nanocarbon spheres (NCS) coated on carbon fiber paper (CFP) were used as a host matrix to disperse manganese dioxide nanoparticles from phosphate buffer solution through electrochemical deposition. The developed electrode (MnO2-Pi-NCS/CFP) was used as a working electrode for electrochemical oxidation of 2-thiophenemethanol in the presence of a mediator TEMPO in 0.01 M H2SO4 medium. Different analytical methods were used to characterize the modified electrodes. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to study the electrochemical properties of the modified electrodes. The electrochemically active surface area values calculated for bare CFP, NCS coated CFP and MnO2-Pi-NCS/CFP electrodes were found to be 1.43 cm2, 2.86 cm2, and 6.72 cm2 respectively for the geometric area of 0.7 cm2 of the electrodes. Coating of NCS and MnO2-Pi resulted in porosity and roughness of the CFP electrode which enhances the surface area. MnO2-Pi-NCS/CFP demonstrated higher electrocatalytic activity for oxidation of 2-thiophenemethanol to 2-thiophenemethanal in aqueous acidic media with a TEMPO mediator compared to unmodified electrodes. This journal is 2021 The Royal Society of Chemistry. -
An Aqueous Phase TEMPO-Mediated Electrooxidation of Benzyl Alcohol at ?-CD-PPy-Modified Carbon Fibre Paper Electrode
A green and facile electrocatalytic method for the oxidation of benzyl alcohol in an acidic aqueous medium was developed using an anionic micellar system. ?-cyclodextrin-polypyrrole-modified carbon fibre paper (?-CD-PPy/CFP) electrode was successfully used in the oxidation of benzyl alcohol with TEMPO as the mediator. The modified electrode was characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. The modified electrode exhibited a strong electrocatalytic activity towards TEMPO-mediated oxidation of benzyl alcohol. [Figure not available: see fulltext.]. 2020, Springer Science+Business Media, LLC, part of Springer Nature. -
An Architecture for Risk-Based Authentication System in a Multi-Server Environment
Identity authentication, a vital part of any application access, is also one way for imposters to gain access to an application using various fingerprint authentication technologies. Therefore, because of the lack of security in the authentication architecture, this paper proposes an architecture for a risk-based authentication system using a machine learning model in a multi-server environment. Since the recent study mainly focuses on the multi-server environment and adaptive authentication independently, very little work has been proposed using a multi-server environment for adaptive authentication. The study aims to estimate risk for the user during the initial login process and when the user's data is extracted enough for prediction in a multi-server environment. 2023 IEEE. -
An Area-Efficient Unique 4:1 Multiplexer Using Nano-electronic-Based Architecture
Quantum dot cellular automata computing methodology is a new way to develop systems with less power consumption. Nanotechnology-based computing technology has enabled the QCA principles to be more relevant with respect to the critical limitations of current VLSI-based design. In this paper, a novel 4:1 multiplexer design based on the QCA concept is presented. As compared to the previous designs of a multiplexer, this novel design is area efficient and power efficient. A five-input majority voter is used for the design of the multiplexer. The 4:1 multiplexer is constructed by making use of three 2:1 multiplexer. 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
An artificial intelligence based smart cap with voice assistant for blind person /
Patent number: 202241013502, Applicant: Dr. Aruna S K.
People who are completely blind or have reduced eyesight confront numerous challenges while navigating. Every day, they face a variety of challenges, particularly in terms of mobility. Several systems have been developed to assist visually impaired people and improve their quality of life. This invention helps the blind to navigate independently using smart cap. It enables visually impaired people to see the world by voice assistance. It enables the blind and visually impaired to navigate freely by allowing them to experience their surroundings through audio output that describes the identified things. -
An artificial intelligence based smart cap with voice assistant for blind person /
Patent number: 202241013502, Applicant: Dr. Aruna S K.
People who are completely blind or have reduced eyesight confront numerous challenges while navigating. Every day, they face a variety of challenges, particularly in terms of mobility. Several systems have been developed to assist visually impaired people and improve their quality of life. This invention helps the blind to navigate independently using smart cap. It enables visually impaired people to see the world by voice assistance. It enables the blind and visually impaired to navigate freely by allowing them to experience their surroundings through audio output that describes the identified things. -
An artificial intelligence based smart cap with voice assistant for blind person /
Patent number: 202241013502, Applicant: Dr. Aruna S K.
People who are completely blind or have reduced eyesight confront numerous challenges while navigating. Every day, they face a variety of challenges, particularly in terms of mobility. Several systems have been developed to assist visually impaired people and improve their quality of life. This invention helps the blind to navigate independently using smart cap. It enables visually impaired people to see the world by voice assistance. It enables the blind and visually impaired to navigate freely by allowing them to experience their surroundings through audio output that describes the identified things. -
An artificial intelligence based smart cap with voice assistant for blind person /
Patent number: 202241013502, Applicant: Dr. Aruna S K.
People who are completely blind or have reduced eyesight confront numerous challenges while navigating. Every day, they face a variety of challenges, particularly in terms of mobility. Several systems have been developed to assist visually impaired people and improve their quality of life. This invention helps the blind to navigate independently using smart cap. It enables visually impaired people to see the world by voice assistance. It enables the blind and visually impaired to navigate freely by allowing them to experience their surroundings through audio output that describes the identified things. -
An artificial intelligence based smart cap with voice assistant for blind person /
Patent number: 202241013502, Applicant: Dr. Aruna S K.
People who are completely blind or have reduced eyesight confront numerous challenges while navigating. Every day, they face a variety of challenges, particularly in terms of mobility. Several systems have been developed to assist visually impaired people and improve their quality of life. This invention helps the blind to navigate independently using smart cap. It enables visually impaired people to see the world by voice assistance. It enables the blind and visually impaired to navigate freely by allowing them to experience their surroundings through audio output that describes the identified things. -
An artificial intelligence based smart cap with voice assistant for blind person /
Patent number: 202241013502, Applicant: Dr. Aruna S K.
People who are completely blind or have reduced eyesight confront numerous challenges while navigating. Every day, they face a variety of challenges, particularly in terms of mobility. Several systems have been developed to assist visually impaired people and improve their quality of life. This invention helps the blind to navigate independently using smart cap. It enables visually impaired people to see the world by voice assistance. It enables the blind and visually impaired to navigate freely by allowing them to experience their surroundings through audio output that describes the identified things. -
An Assessment of Farmers' Perception and Adaptive Capacity for Climate Change
In the past decades, various regions in U.P. had experienced severe floods. The effects of climate change also affected agricultural production. This study investigated the farmers' perception of climate change and suggested strategies for mitigating its effects using a primary survey with the help of a pre-structured schedule. Change in rainfall pattern, problems in seed quality, the emergence of new pests and diseases, changes in the crop cycle were the few effects that farmers' perceived due to climate change. Even the most mitigation efforts by the farmers cannot prevent some of the impacts of climate change within the following decades. It makes adaptation a must-have for addressing these impacts. 2022, The Society of Economics and Development. All rights reserved. -
An asymmetric analysis of overall globalization on financial inclusion
Purpose: Financial inclusion is acknowledged as a critical facilitator of the United Nations Sustainable Development Goals agenda for 2030. Therefore, this study aims to examine the asymmetric role of overall globalization on financial inclusion by controlling economic growth, urbanization and population for the selected South Asian countries. Design/methodology/approach: Applying the nonlinear autoregressive distributed lag approach to cointegration explores the impact of overall globalization on financial inclusion in the presence of additional variables like economic growth, urbanization and population in the designed financial inclusion function. Findings: The estimated econometric outcomes show that increasing overall globalization fosters financial inclusion while decreasing overall globalization reduces financial inclusion. Furthermore, a positive (negative) change in economic growth leads to an increase (decrease) in financial inclusion while varying short-run findings. Moreover, both positive and negative changes increase financial inclusion in the long run in connection with urbanization. Although the short-run results are not significant, the study finds that an increase (decrease) in population leads to a decrease (increase) in financial inclusion. Finally, to support the promotion of financial inclusivity throughout South Asia, several policies pertaining to financial inclusion are suggested. Originality/value: To the best of the authors knowledge, this is the first study to examine the asymmetries related to overall globalization on financial inclusion by controlling economic growth, urbanization and population. 2024, Emerald Publishing Limited. -
An augmented artificial bee colony algorithm for data aggregation in wireless sensor networks
As wireless sensor networks comprise of a vast number of resource constrained tiny sensor nodes which are designed to operate for a long period of time, it is inevitable to efficiently utilize the available resources. Even though energy harvesting approaches exist, energy efficiency in these networks remains the primary concern. Innovative data collection methods help in the optimal utilization of the confined resources like energy, memory and processing capabilities. Majority of the energy is consumed for data transmission in contrast to sensing and processing. Adopting self-organizing system intelligence of the nature for modern advancements is effective and efficient. This paper provides a gist of the existing bio-inspired routing algorithms and describes a new energy efficient data collection strategy with mobile sinks in wireless sensor networks. IAEME Publication. -
An Automated Deep Learning Model for Detecting Sarcastic Comments
The concept of Natural Language Processing is immensely vast with a wide range of fields in which ideas can be explored and innovations can be developed. An algorithm based on deep learning is used to detect sarcasm in text in this paper. It is usually only possible to detect sarcasm through speech and very rarely through text. 1.3 million comments from Reddit were analyzed, of which half were sarcastic and half were not, and then various deep learning models were applied, such as standard neural networks, CNNs, and LSTM RNNs. The best performing model was LSTM-RNNs, followed by CNNs, and standard neural networks came last. With textual data, it is much harder to understand whether the other person is being sarcastic or not, it can only be understood by listening to their tone of voice or looking at their behaviour. The purpose of this paper is to demonstrate how to detect sarcasm in textual data using deep learning models. 2021 IEEE. -
An Automated Path-Focused Test Case Generation with Dynamic Parameterization Using Adaptive Genetic Algorithm (AGA) for Structural Program Testing
Various software engineering paradigms and real-time projects have proved that software testing is the most critical and highly important phase in the SDLC. In general, software testing takes approximately 4060% of the total effort and time involved in project development. Generating test cases is the most important process in software testing. There are many techniques involved in the automatic generation of these test cases which aim to find a smaller group of cases that could allow for an adequacy level to be achieved which will hence reduce the effort and cost involved in software testing. In the structural testing of a product, the auto-generation of test cases that are path focused in an efficient manner is a challenging process. These are often considered optimization problems and hence search-based methods such as genetic algorithm (GA) and swarm optimizations have been proposed to handle this issue. The significance of the study is to address the optimization problem of automatic test case generation in search-based software engineering. The proposed methodology aims to close the gap of genetic algorithms acquiring local minimum due to poor diversity. Here, dynamic adjustment of cross-over and mutation rate is achieved by calculating the individual measure of similarity and fitness and searching for the more global optimum. The proposed method is applied and experimented on a benchmark of five industrial projects. The results of the experiments have confirmed the efficiency of generating test cases that have optimum path coverage. 2023 by the authors. -
An autonomic computing architecture for business applications
Though the vision of autonomic computing (AC) is highly ambitious, an objective analysis of autonomic computing and its growth in the last decade throw more incisive and decisive insights on its birth deformities and growth pains. Predominantly software-based solutions are being preferred to make IT infrastructures and platforms, adaptive and autonomic in their offerings, outputs, and outlooks. However the autonomic journey has not been as promising as originally envisaged by industry leaders and luminaries, and there are several reasons being quoted by professionals and pundits for that gap. Precisely speaking, there is a kind of slackness in articulating its unique characteristics, and the enormous potentials in business and IT acceleration. There are not many real-world applications to popularize the autonomic concept among the development community. Though, some inroads has been made into infrastructure areas like networking, load balancing etc., very few attempts has been exercised in application areas like ERP, SCM, or CRM. In this paper, we would like to dig and dive deeper to extract and explain where the pioneering and path-breaking autonomic computing stands today, and the varied opportunities and possibilities, which insists hot pursuit of the autonomic idea. A simplistic architecture for deployment of autonomic business applications is introduced and a sample implementation in an existing CRM system is described. This should form the basis of new start and ubiquitous application of AC concepts for business applications. 2012 IEEE. -
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An Autonomic Systems approach to Online Retail Systems
In 2003, IBM released a document presenting its vision of autonomic computing. In this article, the author observes that the ever increasing complexity of computing systems will cross the borders of human capabilities, leading to systems that are too complex to be administrated by human beings. System administrators will no longer be able to install, configure, maintain and optimize these computing systems of the future. The solution to this problem is developing a technology that allows computing systems to manage themselves. This solution is referred to as autonomic computing. In today??s economic scenario, Online Retail Systems are gaining prominence and day by day increasing in size, leading to complexities difficult to be managed by human beings. E-Commerce Shops with thousands of articles are becoming the rule of the day. With hundreds of articles being added everyday, the administration required for efficient management of these articles, especially display selection, rejection etc are becoming a mind boggling task for human beings to manage. Parallel developments in study of buying behaviors based on various techniques like data mining, decision trees, neural networks etc are gaining significant practical ground, which also increases the complexity to be managed. The basic idea is lay foundation for creation of autonomic systems based on the outputs from behavioral study, inventory management, etc to autonomically handle management of display, inventory predictions etc. The efficiencies achieved should in turn result in higher revenue as well as profits. In short, the study intends to explore the feasibility of applying autonomic techniques for efficient display organization in online retail contexts by borrowing the intelligence from techniques evolving from data mining, artificial intelligence. This paper will address the development of a taxonomy, a model framework for ??autonomic online retail?? systems and the application of related standards. It will also delve into the theoretical background of specific techniques, which can be applied in this scenario. A basic model of the framework is also implemented. The complete implementation of the framework and measurement of the efficiency gains and other effects will be continued in the doctoral research. The design of the framework and also the measurement framework is being discussed in this document. -
An Early Detection of Autism Spectrum Disorder Using PDNN and ABIDE I&II Dataset
The current study's objective was to use deep learning methods to separate valetudinarians amidst autism spectrum disorders (ASDs) from controls employing just the patients brain activation patterns from a dataset of large brain images. We examined brain imaging data from ASD patients from the global, multi-site ABIDE dataset (Autism Brain Imaging Data Exchange). Social impairments and repetitive behaviors are hallmarks of the brain condition known as autism spectrum disorder (ASD). ASD affects one in every 68 kids in the USA, as of the most recent data from the Disease Control Centers. To understand the neurological patterns that arose from the categorization, we looked into functional connectivity patterns that can be used to diagnose ASD participants precisely. The outcomes raised the state of the art by correctly identifying 72.10% of ASD patients in the sample vs. control patients. The classification patterns revealed an anti-correlation between the function of the brain's anterior and posterior regions; this anti-correlation supports the empirical data currently showing achingly ASD impedes communication between the livid brain's anterior and posterior areas. We found and pinpointed brain regions damn frolic, distinguishing ASD among typically developing reign according to our deep learning model. The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd 2024.