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Photoresponsive Carbon-Azobenzene Hybrids: A Promising Material for Energy Devices
Advancements in renewable energy technology have been a hot topic in the field of photoresponsive materials for a sustainable community. Organic compounds that function as photoswitches is being researched and developed for use in a variety of energy storage systems. Azobenzene photoswitches can be used to store and release solar energy in solar thermal fuels. This review draws out the significance of azobenzene as photoswitches and its recent advances in solar thermal fuels. The recent developments of nano carbon templated azobenzene, their interactions and the effect of substituents are highlighted. The review also introduces their applications in solar thermal fuels and concludes with the challenges and future scope of the material. The advancements of solar thermal fuels with cost effective and desired optimal properties can be explored by scientists and engineers from different technological backgrounds. 2022 Wiley-VCH GmbH. -
Capacitive Behaviour of Imidazole Azo Modified Carbon Nanotubes/Polypyrrole Composite in Aqueous Electrolytes
Here, we reported imidazole azo (Im) modified carbon nanotubes (CNT) grafted polypyrrole (PPy) via the chemical oxidation method. The synthesized hybrid material has shown a unique structure consisting of carbon nanotubes with a conductive network via polypyrrole. The presence of Im derivatives has helped CNTs to enhance their electrochemical performances. The as synthesized composite was characterized using various techniques like FT-IR, XRD, XPS, and Raman spectroscopy. The morphological studies were performed using SEM technique which also confirmed the nature of the composite. The electrochemical performances of the electrode material were investigated using cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy in various electrolytes. The best performance of the electrode material was observed in 1 M H2SO4 with a specific capacitance of 305 F g?1 at a current density of 1 A g?1. The electrode material also showed a coulombic efficiency of 96% even after 5000 cycles. 2023 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. -
Azopyridine as a Linker Molecule in Polyaniline-Grafted Graphene Oxide Nanocomposite Electrodes for Asymmetric Supercapacitors
Electronically conducting polymers (ECPs)/carbon nanomaterial-based polyaniline electrodes have received great interest in the field of supercapacitors due to their high specific capacitance, good electronic conductivity, good mechanical strength, good chemical and electrochemical stabilities, etc. Among the various available ECPs, they have received much importance due to their excellent electrochemical performances. Herein, we report a facile synthesis of a PANI-grafted graphene oxide (GO)-azopyridine (Azo) (PANI/GO-Azo) nanocomposite and use it as electrodes for fabricating supercapacitors. The azo units present in the nanocomposite act as a spacer between PANI and GO. The interfacial polymerization method is adopted for the synthesis of PANI/GO-Azo nanocomposites. The PANI/GO-Azo nanocomposite electrode exhibits a gravimetric capacitance of 426 F g-1 at a current density of 0.25 A g-1 in 1 M H2SO4 (aqueous) electrolyte. The electrode possesses good cycling stability of more than 5000 cycles with a Coulombic efficiency of 98.5%. An asymmetric supercapacitor fabricated with PANI/GO-Azo as the positive electrode and activated carbon as the negative electrode delivers an energy density of 12.45 W h kg-1 with a power density of 274.9 W kg-1. This study proclaims that the PANI/GO-Azo nanocomposite electrode is highly promising for next-generation supercapacitors. 2023 American Chemical Society -
Strategically designed multiwalled carbon nanotube/bismuth ferrite/polyaniline nanocomposites and unlocking their potential for advanced supercapacitors
Bismuth ferrite (BF) serves a potential electrode-active material due to its peculiar characteristics such as wide voltage window and high specific capacitance, excellent stability, facile synthesis routes, etc. to name a few. Herein we report the strategic design and facile synthesis of multiwalled carbon nanotubes (MWCNT)/BF/polyaniline (PANI) nanocomposites, particularly for application in advanced supercapacitors. The MWCNT/BF/PANI nanocomposite architecture is a strategic design in which the maximum available surface area is utilized for the electrode nanostructure with increased porosity that allows easy movement of electrolyte-ions through it. The uniform arrangement of BF on MWCNTs helps in mitigating the possible agglomeration, further augmenting the surface area for an enhanced charge storage. The strategic layout of PANI on BF-decorated MWCNTs has given a coral-like structure for the nanocomposite electrode which significantly increased the surface area, reduced ion pathways and facilitating better access to electrolytic K+ ions. The MWCNT/BF/PANI nanocomposite electrode exhibits a specific capacitance of 3640 F g?1 at a current density of 5 A g?1. The innovative design as well as the synergy between the individual components of the nanocomposite electrode play a pivotal role in attaining the enhanced electrochemical performance. 2024 Elsevier B.V. -
Conceptual comprehension analysis of a student using soft cosine measure
Knowledge is the substantial wealth of a man and he possesses an innate thirst to acquire it. Knowledge embodies facts or ideas acquired through study, investigation and observation or experience. In this context, technology with its varied techniques comprising endless algorithms in natural language processing (NLP) plays an imperative role in the pursuit of knowledge. Inferences thus gathered are a clear pointer to the content teaching of students. Soft cosine measure algorithm is used in this analysis process to provide an answer regarding the grasping ability of each student with optimum learner participation and creativity. After each lecture, students have to upload their corresponding notes and this in turn would be compared with the teacher's lecture notes. The soft cosine computation gives individual results, on how much each student has comprehended a concept. This new methodology is a much awaited contribution of the educational field. 2022 Author(s). -
One-pot hydrothermal synthesis of MWCNTs/NiS/graphitic carbon nitride as next generation asymmetric supercapacitors
Fabricating new electrode materials with high capacitive properties is crucial in contemporary research. The construction of hybrid supercapacitors developed using transition metal-sulfides and carbonaceous materials provides significant surface area and distinctive charge storage characteristics. In the present work, NH2-multiwalled carbon nanotubes/NiS/g-C3N4 (MNG) hybrid was synthesized by a one-pot hydrothermal method, and pristine g-C3N4 using thermal method. The morphological studies of the hybrid materials show the presence of tube like MWCNTs, sphere-like NiS, and sheet like g-C3N4. The uniform distribution of all the components in the hybrid helps in exhibiting excellent electrochemical performances. The prepared electrode material shows a specific capacitance of 2432 F g?1 at a current density of 4 A g?1. Furthermore, following a series of 10,000 cycling tests, the hybrid ternary composite retains 98 % of its initial capacitance. An asymmetric coin cell of MNG//AC was fabricated with an exceptional energy density of 73.3 Wh kg?1 and a power density of 1599.2 W kg?1. This remarkable rate performance and cycle stability exhibited by the material indicate its potential as a highly efficient electrode material for supercapacitors. 2024 Elsevier B.V. -
Hybrid architecture of Multiwalled carbon nanotubes/nickel sulphide/polypyrrole electrodes for supercapacitor
A hybrid electrode structure consisting of amino functionalised multi-walled carbon nanotube, nickel sulphide, and polypyrrole is successfully synthesized using a two-step synthesis such as hydrothermal and in-situ polymerization method. The resulting MWCNT/NiS/PPy composite exhibits a distinct tube-in-tube morphology with excellent stratification. The combination of different components and the unique structure of the composite contribute to its impressive specific capacitance of 1755 F g?1 at 3 A g?1. The prepared ternary composite enables ample exposure of numerous active sites while improving structural stability, ultimately leading to enhanced energy storage capabilities. They do this by combining the advantages of constituent components, a hierarchical assembly approach, and an integrated composite structure. Furthermore, even after undergoing 10,000 charge-discharge cycles, the supercapacitor retains more than 97% of columbic efficiency. An asymmetric coin cell was fabricated using MWCNT/NiS/PPy//AC device which delivered an energy density and power density of 33.12 Wh Kg?1 and 6750 W kg?1 respectively. These findings highlight the exceptional potential of the fabricated device for future applications in hybrid energy storage systems. 2024 Elsevier Ltd -
Analysis of unsteady flow of blood conveying iron oxide nanoparticles on melting surface due to free convection using Casson model
Iron oxide nanoparticles have great importance in future biomedical applications because of their intrinsic properties, such as low toxicity, colloidal stability, and surface engineering capability. So, blood containing iron oxide nanoparticles are used in biomedical sciences as contrast agents following intravenous administration. The current problem deals with an analysis of the melting heat transfer of blood consisting iron nanoparticles in the existence of free convection. The principal equations of the problem are extremely nonlinear partial differential equations which transmute into a set of nonlinear ordinary differential equations by applying proper similarity transformations. The acquired similarity equalities are then solved numerically by Runge-Kutta Felhsberg 45th-order method. The results acquired are on the same level with past available results. Some noteworthy findings of the study are: the rate of heat transfer increases as the Casson parameter increases and also found that the temperature of the blood can be controlled by increasing or decreasing the Prandtl number. Hence, we conclude that flow and heat transfer of blood have significant clinical importance during the stages where the blood flow needs to be checked (surgery) and the heat transfer rate must be controlled (therapy). 2020 Wiley Periodicals LLC -
A parallel approach for region-growing segmentation
Image Segmentations play a heavy role in areas such as computer vision and image processing due to its broad usage and immense applications. Because of the large importance of image segmentation a number of algorithms have been proposed and different approaches have been adopted. In this theme I tried to parallelize the image segmentation using a region growing algorithm. The primary goal behind this theme is to enhance performance or speed up the image segmentation on large volume image data sets, i.e. Very high resolution images (VHR). In parliamentary law to get the full advantage of GPU computing, equally spread the workload among the available threads. Threads assigned to individual pixels iteratively merge with adjacent segments and always ensuring the standards that the heterogeneity of image objects should be belittled. An experimental analysis upon different orbital sensor images has made out in order to assess the quality of results. 2015 IEEE. -
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Dynamic Load Scheduling Using Clustering for Increasing Efficiency of Warehouse Order Fulfillment Done Through Pick and Place Bots
The domain of warehouse automation has been picking up due to the vast developments in e-commerce owing to growing demand and the need to improve customer satisfaction. The one crucial component that needs to be integrated into large warehouses is automated pick and place of orders from the storage facility using automated vehicles integrated with a forklift (Pick and Place bots). Even with automation being employed, there is a lot of room for improvement with the current technology being used as the loading of the bots is inefficient and not dynamic. This paper discusses a method to dynamically allocate load between the Pick and Place BOTs in a warehouse during order fulfillment. This dynamic allocation is done using clustering,an unsupervised Machine Learning algorithm. This paper discusses using fuzzy C-means clustering to improve the efficiency of warehouse automation. The discussed algorithm improves the efficiency of order fulfillment significantly and is demonstrated in this paper using multiple simulations to see around 35% reduction in order fulfillment time and around 55% increase in efficiency. 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
Patient Monitoring System for Elderly Care using AI Robot
The use of robots in numerous industries has expanded in recent decades. Self-guiding robots have started to arise in human life, particularly in sectors pertaining to the lives of old people. Age-related population growth is accelerating globally. As a result, there is a rising need for personal care robots. The purpose of this requirement is to increase opportunities for mobility and support independence. To meet this demand, a robot with specific functionalities to help older people has been designed. The standard values of healthcare parameters are stored in the database by recording and comparing the current values the system will give an alarm and also sends a message to the doctor or caretaker so that a proper care would be given to the patients. We are including a preset distance value to monitor the elder people. Here we are using some sensors to detect the health parameters from the person. Robot have designed to intimate the family members if any changes occur in the health parameters. It helps the people to stay alone in home with safe manner. 2022 IEEE. -
Metal-Based Nanoparticles for Infectious Diseases and Therapeutics
Infectious diseases that are easily transmitted by microorganisms like bacteria, protozoa, fungus, etc. are a menace to humans. The greatest threat to human race is to mitigate the impact of these diseases. People with less immunity and children are prone to these diseases. Even healthy people get infected due to its easy transmission. Microorganisms causing these diseases are becoming more resistant to the drugs that are available in the market. So, there is a need to find new therapeutic which is facile, sensitive, and selective, is an important challenge for the medical field and this is where nanotechnology is having a greater chance. Nanoparticles especially metal-based nanoparticles have the ability to act against infectious and non-infectious diseases, this is because of their unique properties like small size, high surface area, etc. They do not have a specific binding site on the bacterial cell, which lead to the failure of bacterial resistant towards the nanoparticle mechanism. There are many nanoparticles which are efficient against particular diseases. In this review we are discussing about the advanced nanomaterials as therapeutics for infectious diseases. We have also discussed about antiviral activities which gives us a ray of hope for the solution of the SARS-COV-2. The Editor(s) (if applicable) and The Author(s), under exclusive licence to Springer Nature Singapore Pte Ltd. 2022. -
Implementing artificial intelligence agent within connect 4 using unity3d and machine learning concepts
Nowadays, we come across games that have unbelievably realistic graphics that it usually becomes hard to distinguish between reality and the virtual world when we are exposed to a virtual reality gaming console. Implementing the concepts of Artificial Intelligence (AI) and Machine-Learning (ML) makes the game self-sustainable and way too intelligent on its own, by making use of self-learning methodologies which can give the user a better gaming experience. The use of AI and ML in games can give a better dimension to the gaming experience in general as the virtual world can behave unpredictably, thus improving the overall stigma of the game. In this paper, we have implemented Connect-4, a multiplayer game, using ML concepts in Unity3D. The machine learning toolkit ML-Agents, which depends on Reinforcement Learning (RL) technique, is provided using Unity3D. This toolkit is used for training the game agent which can distinguish its good moves and mistakes while training, so that the agent will not go for same mistakes over and over during actual game with human player. With this paper, authors have increased intelligence of game agent of Connect 4 using Reinforcement Learning, Unity3D and ML-Agents toolkit. BEIESP. -
Study of Bard-Marangoni Convection in a Microfluid with Coriolis Force
The convection of micro-structured fluid particles and the Coriolis force has been investigated in the problem. The eigenvalues are calculated for upper free velocity and adiabatic temperature boundary conditions and lower rigid velocity and isothermal temperature boundary conditions. The analysis is based on solving linear disturbance equations. The impact of different micropolar fluid variables and the Taylor number based on the convection has also been investigated. The study could observe that while the coupling and micropolar heat conduction parameters along with rotational parameters have a stabilizing effect, the couple stress parameter results in a destabilizing effect. The Author(s), under exclusive license to Springer Nature Switzerland AG 2024. -
The impact of slip mechanisms on the flow of hybrid nanofluid past a wedge subjected to thermal and solutal stratification
This investigation aims to inspect the flow and thermal characteristics of hybrid nanoparticles under the effect of thermophoresis and Brownian motion. The hybrid nanofluid is formed by dispersing the silver nanoparticles into the base fluid composed of tungsten oxide and water. The resulting hybrid nanofluid is assumed to flow over a moving wedge. The wedge is a geometry that can be commonly seen in many manufacturing industries, moulding industries, etc., where friction creates more heat and cooling becomes a necessary process. This study currently focuses on such areas of the industries. In this regard, the flow expressions in the form of Partial Differential Equations (PDEs) are obtained by incorporating the modified Buongiorno's model and using boundary layer approximations. The modified Buongiorno model helps us analyze the impact of volume fraction along with the slip mechanisms. Suitable transformations are used to achieve the nondimensional form of governing equations, and further, it transforms the PDE to Ordinary Differential Equation (ODE). The RKF-45 is used to solve the obtained ODE and the boundary conditions. Furthermore, graphic analysis of the solutions for fluid velocity, energy distributions and dimensionless concentration is provided. It was noted that the behavior of the Nusselt and Sherwood numbers was determined by analyzing numerous parameters. The conclusions show that they decrease with greater values of the stratification factors. Additionally, with higher values of the wedge parameter, the magnitude of the velocity field and the thermal boundary layer diminish. 2023 World Scientific Publishing Company. -
Adopting Metaverse as a Pedagogy in Problem-Based Learning
Pedagogical practices vary from time to time based on the requirement of various academic disciplines. Course instructors are constantly searching for inclusive and innovative pedagogies to enhance learning experiences. The introduction of Metaverse can be observed as an opportunity to enable the course instructors to combine virtual reality with augmented reality to enable immersive learning. The scope of immersive learning experience with Metaverse attracted many major universities in the world to try Metaverse as a pedagogy in fields such as management studies, medical education, and architecture. Adopting Metaverse as a pedagogy for problem-based learning enables the course instructors to create an active learning space that tackles the physical barriers of traditional pedagogical practices of case-based learning facilitating collaborative learning. Metaverse, as an established virtual learning platform, is provided by Meta Inc., providing the company a monopoly over the VR-based pedagogy. Entry of other tech firms into similar or collaborative ventures would open up a wide array of virtual reality-based platforms, eliminating the monopoly and subsequent dependency on a singular platform. The findings of the study indicate that, currently, the engagements on Metaverse are limited to tier 1 educational institutions worldwide due to the initial investment requirements. The wide adoption of the Metaverse platform in future depends on the ability of the platform providers to bridge the digital gap and facilitate curricula development. 2023, The Author(s), under exclusive license to Springer Nature Switzerland AG. -
Pemetrexed loaded gold nanoparticles as cytotoxic and apoptosis inducers in lung cancer cells through ROS generation and mitochondrial dysfunction pathway
Supramolecular nanoparticles containing peptides and drugs have recently gained recognition as an effective tumor treatment drug delivery system. A multitarget drug termed pemetrexed is effective against various cancers, including nonsmall cell lung cancer. The work aims to establish the capability of pemetrexed gold nanoparticles (PEM-AuNPs) to induce apoptosis and explore molecular changes. X-ray diffraction, Fourier-transform infrared spectroscopy, ultravioletvisible spectroscopy, scanning electron microscope, and transmission electron microscope were used to investigate the synthesized nanoparticles. The MTT assay was utilized to investigate the anticancer properties of PEM-AuNPs at varying concentrations (50, 100, and 200M). PEM-AuNPs demonstrated a decrease in cell viability with 55.87%, 43.04%, and 25.59% for A549 cells and 54.31%, 37.40%, and 25.84% for H1299 cells at the respective concentrations. To assess apoptosis and perform morphological analysis, diverse biochemical staining techniques, including acridine orange-ethidium bromide and 4?,6-diamidino-2-phenylindole nuclear staining assays, were employed. Additionally, 2?,7?-dichlorofluorescein diacetate staining confirmed the induction of reactive oxygen species generation, while JC-1 staining validated the impact on the mitochondrial membrane at the IC50 concentration of PEM-AuNPs. Thus, the study demonstrated that the synthesized PEM-AuNPs exhibited enhanced anticancer activity against both A549 and H1299 cells. 2024 International Union of Biochemistry and Molecular Biology, Inc. -
Graphene-metal oxide composites for electrochemical energy storage and conversion
The development of clean and renewable alternative energy sources is essential due to the rising energy consumption. Advancements in energy conversion and storage technologies, such as fuel cells, batteries, and solar cells, are currently the subject of active research. The unique structure and properties of two-dimensional graphene materials are explored in developing energy devices. The efficient utilization of graphene's enormous specific surface area and exceptional electrical, chemical, and mechanical properties still remains a challenge to researchers due to the agglomeration of its layers. The introduction of metal oxides into these 2D layers helps to enhance their structural and electrochemical stability, which helps in the production of energy storage devices. This chapter discusses the synthesis protocols, tunable properties, as a function of size and shape, and characterization tools. It also provides a deeper understanding of graphene-metal oxide composites in various energy storage devices, highlighting the importance of the synergistic effects between graphene and metal oxides. The chapter concludes with the prospects and potential of graphene-metal oxide composites for energy storage applications. The Royal Society of Chemistry 2025. -
Bithiophene and 3,4-Ethylenedioxythiophene Copolymers with Biphenyl and Bis-[octyloxy]benzene acceptors for NLO Application
Two groups of thiophene-based donoracceptor (DA) type conjugated copolymers with low band gaps were designed and synthesized through direct arylation. Biphenyl and bis(octyloxy)benzene were incorporated as electron-deficient units to effectively lower the band gaps. The HOMOLUMO energy levels of the resulting copolymers were theoretically determined using DFT calculations at the HSE06 and B3LYP levels with a 631G(d,p) basis set. The copolymers were characterized by UVVis, FT-IR, fluorescence, and H NMR spectroscopy. Their thermal stability was assessed using thermogravimetric analysis, which confirmed that the bithiophene-based copolymers P(BT-BP) and P(BT-DOB) were highly thermally stable. Additionally, P(BT-DOB) and P(EDOT-DOB) exhibited solvatochromic behavior in varying toluene/acetonitrile solvent mixtures. Third-order nonlinear optical properties of P(BT-BP), P(EDOT-BP), P(BT-DOB), and P(EDOT-DOB) were studied using an open-aperture Z-scan method at 532 nm in DMSO. These copolymers showed reverse saturable absorption with low optical threshold values. 2025 Elsevier B.V.