Browse Items (16482 total)

• Article

  2--Intercalated NiCo-Layered Double Hydroxide Nanospikes: An Efficiently Synergized Material for Urine to Direct H2 Generation

  Substituting the energy-uphill water oxidation half-cell with readily oxidizable urea-rich urine, a ground-breaking bridge is constructed, combining the energy-efficient hydrogen generation and environmental protection. Hence, designing a robust multifunctional electrocatalyst is desirable for widespread implementation of this waste to fuel technology. In this context, here, we report a simple tuning of the electrocatalytically favorable characteristics of NiCo-layered double hydroxide by introducing [MoS4]2- in its interlayer space. The [MoS4]2- insertion as well as its effect on the electronic structure tuning is thoroughly studied via X-ray photoelectron spectroscopy in combination with electrochemical analysis. This insertion induces overall electronic structure tuning of the hydroxide layer in such a way that the designed catalyst exhibited favorable kinetics toward all the required reactions of hydrogen generation. This is why our homemade catalyst, when utilized both as a cathode and anode to fabricate a urea electrolyzer, required a mere .37 V cell potential to generate sufficient H2 by reaching the benchmark 10 mA cm-2 in 1 M KOH/0.33 M urea along with long-lasting catalytic efficiency. Other indispensable reason of selecting [MoS4]2- is its high-valent nature making the catalyst highly selective and insensitive to common catalyst-poisoning toxins of urine. This is experimentally supported by performing the real urine electrolysis, where the nanospike-covered Ni foam-based catalyst showed a performance similar to that of synthetic urea, offering its industrial value. Other intuition of selecting [MoS4]2- was to provide a ligand-based mechanism for hydrogen evolution half-cell [hydrogen evolution reaction (HER)] to preclude the HER-competing oxygen reduction. Another crucial point of our work is its potential to avoid the mixing of two explosive product gases, that is, H2 and O2. 2019 American Chemical Society.
• PhD

  Access to Justice Through Law Schools Legal AID Activities in India : An Empirical Study with Special Reference to Kerala

  The provision of legal services is a fundamental human right and is integral to the maintenance of the rule of law. Ensuring Justice and the rule of law are unique sustainable development goals in the 2030 Agenda. Law school clinics provide a novel way to reach SDG-16. The legal aid system has been influenced by both international and national legislation, which has contributed to the establishment of its framework. The judiciary plays a pivotal role in ensuring the provision of free legal assistance to indigent people. Access to formal and informal justice institutions must be improved so that people can seek and get justice. Law school clinics provide potential and challenges as informal justice nstitutions, yet they are mostly ignored. Under CLE, law schools LACs engage in a variety of legal aid initiatives. Through this, students acquire professional skills while clients get legal services. That is the beauty of law school LACs. In the end, this "laboratory of lawyering" helps individuals find justice. In the Indian context, this thesis answered three research questions. 1) How do the legal aid programmes undertaken by law schools clinics promote SDG-16 and improve access to justice? 2) What are the current practices being undertaken by law schools LACs to guarantee access to justice? 3) What are the shortcomings that law schools LACs face in delivering appropriate legal services in Kerala? Two methodologies were used in answering these three questions: the doctrinal method for the first two research questions and the empirical method for the third. The doctrinal study examines the operation of LACs in general. The purpose of this empirical research on law school clinics in Kerala is to investigate the numerous legal aid activities and barriers to law school clinic operations in Kerala. No meticulous study was conducted in Kerala to evaluate how law schools LACs worked. National and international law school clinics' best practises and case studies were incorporated. The study examined the relationship between BCI, NALSA, SLSAs as well as CLE requirements along with law school performance. The LACs' commitment will be assessed based on their legal aid operations pre- and post-Covid-19, including legal representation, legal awareness, legal advice, paralegal services, PIL and ADR services to beneficiaries, and the effective implementation of BCI and NALSA's CLE requirements. This study explores the relationship between dependent and independent variables, such as how the improper implementation of BCI and NALSA regulations on CLE hindered law school LACs' commitments. The prevailing policy has restricted law school LACs' activity and is not enough to achieve access to justice (ATJ). Due to multiple factors, law school LACs failed to ensure effective service learning and did not reach the needy. This gap in the current CLE and its insufficient attention to promoting access to justice have been addressed. The empirical investigation demonstrates that while the number of law schools increased, legal aid activities decreased during the past decade. Current legal aid practices of law school LACs in Kerala are unsatisfactory and inconsistent in providing access to justice. BCI and LSAs ineffective control over LACs in law schools has contributed to a decline in legal aid activities and services. BCI and NALSA must reform their CLE rules and establish mandatory legal services to foster inclusive and effective LACs that give meaningful justice to the disadvantaged.