Studies On Single Crystals and Thin Films of Tin Sulfide(SnS) For Photovoltaic Applications
The thesis is concerned with linear and nonlinear Rayleigh-Bard electroconvection in a horizontal porous layer. Modified Darcy law is employed to describe the fluid motion. The effect of non-classical heat conduction, chemical reaction, thermal radiation and finite amplitudes on the onset of Darcy electroconvection is considered. The findings of the problems investigated in the thesis may prove useful in heat transfer application situations with dielectric fluids as working medium. The summary of the problems addressed in the thesis is given below.Effect of non-classical heat conduction on Rayleigh-Bard newlineconvection in a horizontal layer of porous medium saturated with a dielectric fluid The method of small perturbations is used to examine the effect of non-classical heat conduction on the onset of Darcy electroconvection. Exact solutions for both stationary and oscillatory instability are obtained and known results have been deduced as limiting cases of the present study. It is shown that electroconvective instability in a Darcy porous layer is hastened by increasing the strengths of second sound and electric newlineforces and that the presence of second sound and dielectrophoretic force leads to shorter wavelength electroconvection. Further, it is found that the effect of Vadasz number is to advance the onset of oscillatory Darcy newlineelectroconvection and oscillatory instability sets in before stationary convection provided that the Vadasz number and the Cattaneo number are sufficiently large. Rayleigh-Bard convection in a horizontal layer of porous medium saturated with a chemically reacting dielectric fluid The problem of the effect of chemical reaction on the onset of Darcy electroconvection in a horizontal porous layer heated from below is newlineinvestigated. It is assumed that the fluid experiences a zero-order exothermic chemical reaction and that there exists a local thermal equilibrium between the fluid and the solid phases.