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              <text>Synthesis and characterization of biowaste-derived porous carbon supported palladium: a systematic study as a heterogeneous catalyst for the reduction of nitroarenes</text>
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              <text>Biowaste; Heterogeneous catalysis; Nitroarene reduction; Palladium based catalysts; Porous carbon</text>
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              <text>In this study, we present a green synthesis approach for the fabrication of porous carbon supported palladium catalysts derived from Caesalpinia pods. The synthesis involves self-activation of Caesalpinia pods in a nitrogen atmosphere at various temperatures (600C, 800C, and 1000C) to produce porous carbon nanoparticles. Among the synthesized carbon materials, the sample CP-CNS/10 synthesized at 1000C exhibited the highest surface area of 793 m2/g with an average pore size diameter of 1.8nm. The resulting porous carbon material served as an efficient support for palladium nanoparticles, with a low metal loading of about 0.2mol% Pd for the reaction. This catalyst demonstrated excellent performance in the reduction of nitroarenes to their corresponding aromatic amines. The successful incorporation of approximately 4.5% Pd during the deposition process highlights the potential of the porous carbon supported palladium catalyst synthesized at 1000C for a sustainable and efficient heterogeneous catalyst for the reduction of nitroarenes. Graphical Abstract: (Figure presented.)  Akadiai Kiad Budapest, Hungary 2024.</text>
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              <text>Shetty A.; Hegde G.</text>
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              <text>Reaction Kinetics, Mechanisms and Catalysis, Vol-137, No. 6, pp. 2989-3004.</text>
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              <text>Springer Science and Business Media B.V.</text>
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              <text>2024-01-01</text>
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              <text>&lt;a href="https://doi.org/10.1007/s11144-024-02690-2" target="_blank" rel="noreferrer noopener"&gt;https://doi.org/10.1007/s11144-024-02690-2&lt;/a&gt;
&lt;br /&gt;&lt;br /&gt;&lt;a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85201012531&amp;amp;doi=10.1007%2Fs11144-024-02690-2&amp;amp;partnerID=40&amp;amp;md5=4a78e49459414dfedd9e966a08e17305" target="_blank" rel="noreferrer noopener"&gt;https://www.scopus.com/inward/record.uri?eid=2-s2.0-85201012531&amp;amp;doi=10.1007%2fs11144-024-02690-2&amp;amp;partnerID=40&amp;amp;md5=4a78e49459414dfedd9e966a08e17305&lt;/a&gt;</text>
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              <text>ISSN: 18785190</text>
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              <text>Shetty A., Department of Chemistry, Christ University, Hosur Road, Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), Christ University, Hosur Road, Bangalore, 560029, India; Hegde G., Department of Chemistry, Christ University, Hosur Road, Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), Christ University, Hosur Road, Bangalore, 560029, India</text>
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