Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Ceramic-Polymer-Carbon Composite Coating on the Truncated Octahedron-Shaped LNMO Cathode for High Capacity and Extended Cycling in High-Voltage Lithium-Ion Batteries Description An account of the resource Long-term electrochemical cycle life of the LiNi0.5Mn1.5O4 (LNMO) cathode with liquid electrolytes (LEs) and the inadequate knowledge of the cell failure mechanism are the eloquent Achilles heel to practical applications despite their large promise to lower the cost of lithium-ion batteries (LIBs). Herein, a strategy for engineering the cathode-LE interface is presented to enhance the cycle life of LIBs. The direct contact between cathode-active particles and LE is controlled by encasing sol-gel-synthesized truncated octahedron-shaped LNMO particles by an ion-electron-conductive (ambipolar) hybrid ceramic-polymer electrolyte (IECHP) via a simple slot-die coating. The IECHP-coated LNMO cathode demonstrated negligible capacity fading in 250 cycles and a capacity retention of ?90% after 1000 charge-discharge cycles, significantly exceeding that of the uncoated LNMO cathode (a capacity retention of ?57% after 980 cycles) in 1 M LiPF6 in EC:DMC at 1 C rate. The difference in stability between the two types of cathodes after cycling is examined by focused ion beam scanning electron microscopy and time-of-flight secondary ion mass spectrometry. These studies revealed that the pristine LNMO produces an inactive layer on the cathode surface, reducing ionic transport between the cathode and the electrolyte and increasing the interface resistance. The IECHP coating successfully overcomes these limitations. Therefore, the present work underlines the adaptability of IECHP-coated LNMO as a high-voltage cathode material in a 1 M LiPF6 electrolyte for prolonged use. The proposed strategy is simple and affordable for commercial applications. 2024 The Authors. Published by American Chemical Society. Creator An entity primarily responsible for making the resource Pazhaniswamy S.; Cha G.; Joshi S.A.; Karuthedath Parameswaran A.; Jose R.; Pechmann S.; Christiansen S.; Agarwal S. Source A related resource from which the described resource is derived Energy and Fuels, Vol-38, No. 21, pp. 21456-21467. Publisher An entity responsible for making the resource available American Chemical Society Date A point or period of time associated with an event in the lifecycle of the resource 2024-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1021/acs.energyfuels.4c02933" target="_blank" rel="noreferrer noopener">https://doi.org/10.1021/acs.energyfuels.4c02933</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85206660549&amp;doi=10.1021%2Facs.energyfuels.4c02933&amp;partnerID=40&amp;md5=3f9eb3cbf2a676c891a853df8a1d38d5" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85206660549&amp;doi=10.1021%2facs.energyfuels.4c02933&amp;partnerID=40&amp;md5=3f9eb3cbf2a676c891a853df8a1d38d5</a> Rights Information about rights held in and over the resource All Open Access; Hybrid Gold Open Access Relation A related resource ISSN: 8870624; CODEN: ENFUE Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Pazhaniswamy S., Department of Materials, University of Oxford, Parks Road, Oxford, OX1 3PH, United Kingdom, Bavarian Center for Battery Technology, Advanced Sustainable Polymers, Macromolecular Chemistry II, University of Bayreuth, Universitsstrasse 30, Bayreuth, 95440, Germany; Cha G., Fraunhofer Institute for Ceramic Technologies and Systems IKTS, re Nnberger Stra 62, Forchheim, 91301, Germany; Joshi S.A., Bavarian Center for Battery Technology, Advanced Sustainable Polymers, Macromolecular Chemistry II, University of Bayreuth, Universitsstrasse 30, Bayreuth, 95440, Germany; Karuthedath Parameswaran A., Department of Physics and Electronics, Christ University, Bangalore, 560029, India, Department of Inorganic Chemistry, University of Chemistry and Technology, Technick5, Prague 6, 166 28, Czech Republic; Jose R., Center for Advanced Intelligent Materials, Universiti Malaysia Pahang Al-Sultan Abdullah, Kuantan, 26300, Malaysia, Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Kuantan, 26300, Malaysia, Battery Research Center of Green Energy, Ming Chi University of Technology, 84 Gungjuan Rd., New Taipei City, 24301, Taiwan; Pechmann S., Fraunhofer Institute for Ceramic Technologies and Systems IKTS, re Nnberger Stra 62, Forchheim, 91301, Germany; Christiansen S., Fraunhofer Institute for Ceramic Technologies and Systems IKTS, re Nnberger Stra 62, Forchheim, 91301, Germany; Agarwal S., Bavarian Center for Battery Technology, Advanced Sustainable Polymers, Macromolecular Chemistry II, University of Bayreuth, Universitsstrasse 30, Bayreuth, 95440, Germany