ItemArticle

Carbon dots-Zno/TiO2 ternary nanocomposite as a proficient material to enhance the performance of natural DSSC

Title
Carbon dots-Zno/TiO2 ternary nanocomposite as a proficient material to enhance the performance of natural DSSC
Creator
Varghese M.; Ninan G.G.; Balachandran M.
Description
A novel sustainable approach for enhancing the efficiency of dye-sensitized solar cells (DSSCs) involves the utilization of a combination of ZnO and carbon dots (CDs) derived from Citrus medica fruit extract, along with microwave-synthesized TiO2 nanoparticles for the preparation of the photoanode. Natural dyes such as Hibiscus rosa-sinensis and Allium Cepa peel are employed as sensitizers to reduce production costs. This co-activation method has demonstrated a significant improvement in the output parameters of the devices. Notably, the photoanode co-activated with ZnO-CD composite (ZnO-CD/TiO2) exhibits the most favorable output parameters when combined with Hibiscus rosa-sinensis dye (open circuit voltage (Voc) = 0.80 V, short circuit current density (Jsc) = 6.62 mA/cm2, fill factor (FF) = 64.20 %, photo conversion efficiency (PCE) = 3.40 %) and Allium Cepa peel dye (Voc = 0.81 V, Jsc = 6.79 mA/cm2, FF = 65.70 %, PCE = 3.61 %). When paired with Allium Cepa dye, the CD modified photoanode (CD/TiO2) offers Voc = 0.73 V, Jsc = 6.64 mA/cm2, FF = 61.27 % and PCE = 2.97 %. Similarly, when combined with Hibiscus rosa-sinensis dye, the output parameters of the CD/TiO2 photoanode are Voc = 0.72 V, Jsc = 6.54 mA/cm2, FF = 64.4 % and PCE = 3.03 %. In comparison to all tested devices, the unmodified photoanode (TiO2) displayed the lowest performance, with parameters such as Voc = 0.59 V, Jsc = 6.45 mA/cm2, FF = 52.5 %, PCE = 2.10 % using Allium Cepa peel dye, and Voc = 0.66 V, Jsc = 6 mA/cm2, FF = 51.60 %, PCE = 2.04 % using Hibiscus rosa-sinensis dye. Furthermore, the co-activation process has been shown to enhance the stability of the devices. While the unmodified photoanodes ceased to operate after eight days, the ZnO-CD composite co-activated photoanodes retained their initial efficiencies up to 61.50 % and 68.53 % with the Allium Cepa peel dye and Hibiscus rosa-sinensis dye, respectively. Therefore, this study underscores the potential of the synthesized composite material in enhancing the performance of natural DSSCs. 2024 Elsevier Ltd
Source
Micro and Nanostructures, Vol-194
Date
2024-01-01
Publisher
Elsevier Ltd
Subject
Carbon dots; Co-activation; Composites; DSSC; Natural dye; Stability
Coverage
Varghese M., Department of Physics and Electronics, Christ University, Karnataka, Bengaluru, 560029, India; Ninan G.G., Department of Physics and Electronics, Christ University, Karnataka, Bengaluru, 560029, India; Balachandran M., Department of Physics and Electronics, Christ University, Karnataka, Bengaluru, 560029, India
Rights
Restricted Access
Relation
ISSN: 27730123
Format
Online
Language
English
Type
Article

Collection

Articles

Citation

Varghese M.; Ninan G.G.; Balachandran M., “Carbon dots-Zno/TiO2 ternary nanocomposite as a proficient material to enhance the performance of natural DSSC,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 25, 2025, https://archives.christuniversity.in/items/show/12799.

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