Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Synthesis, Photophysical, and Computational Studies of Mono-Azo-Bridged, Meso-Tris(2-Furyl/2-Thienyl) Substituted Porphyrin-Arene Hybrids Subject The topic of the resource 2-furyl; 2-thienyl; Azo-bridge; Photo-isomerization; Porphyrin Description An account of the resource Porphyrins hybrids have been used as models to study various energy/electron transfer processes. The linkers connecting various subunits in such hybrids are vital in establishing good electronic communication between the subunits and the azo-bridge can be one of the efficient linkers to do so. Despite of these, the mono azo-bridged porphyrin-arene hybrids reported in the literature are only handful and the methods used to create them are not that efficient. In addition, the porphyrins used in this field so far contains only six-membered meso-substituents. By keeping these points in mind, we have developed a mild, one-pot, work-up-free, high-yielding method to synthesize mono-azo-bridged, porphyrin-arene hybrids which also features porphyrins containing three five-membered substituents like 2-furyl or 2-thienyl on their meso-positions. Along with the NMR and mass characterizations, the photophysical and computational studies of all the reported hybrids are presented. The hybrids containing meso-tris(2-furyl/thienyl) substituted porphyrins displayed red-shifted absorption and emission bands compared to their all-meso-aryl-containing counterparts. In general, all the hybrids displayed enhanced fluorescence quantum yields compared to their precursor porphyrins. Among the series, the meso-tris(2-furyl) substituted porphyrin-arene hybrids exhibited the more significant Stokes shift and small bandgap. The computational studies were in good agreement with the experimental findings. 2024 Wiley-VCH GmbH. Creator An entity primarily responsible for making the resource Nagesh Shet S.; Ganesh Bhat V.; Hegde V.; Hegde G.; Kumar Dalimba U.; Shetti V.S. Source A related resource from which the described resource is derived ChemistrySelect, Vol-9, No. 36 Publisher An entity responsible for making the resource available John Wiley and Sons Inc Date A point or period of time associated with an event in the lifecycle of the resource 2024-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1002/slct.202403181" target="_blank" rel="noreferrer noopener">https://doi.org/10.1002/slct.202403181</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85204560471&amp;doi=10.1002%2Fslct.202403181&amp;partnerID=40&amp;md5=e4e2debf2c56f845fc5ad22d23ef7a49" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85204560471&amp;doi=10.1002%2fslct.202403181&amp;partnerID=40&amp;md5=e4e2debf2c56f845fc5ad22d23ef7a49</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 23656549 Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Nagesh Shet S., Department of Chemistry, National Institute of Technology Karnataka, Surathkal, 575025, India; Ganesh Bhat V., Department of Chemistry, National Institute of Technology Karnataka, Surathkal, 575025, India; Hegde V., Department of Chemistry, CHRIST Deemed-to-be University, Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST Deemed-to-be University, Bangalore, 560029, India; Hegde G., Department of Chemistry, CHRIST Deemed-to-be University, Bangalore, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST Deemed-to-be University, Bangalore, 560029, India; Kumar Dalimba U., Department of Chemistry, National Institute of Technology Karnataka, Surathkal, 575025, India; Shetti V.S., Department of Chemistry, National Institute of Technology Karnataka, Surathkal, 575025, India