Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Exploring In Situ Kinetics of Oxygen Vacancy-Rich B/P-Incorporated Cobalt Oxide Nanowires for the Oxygen Evolution Reaction Subject The topic of the resource electrocatalyst; kinetics; nanowires; OER; water splitting Description An account of the resource Defect-engineering of transition-metal oxide-based nanocatalysts is an innovative approach for improving the oxygen evolution reaction (OER) owing to their enhanced activity and stability. The present study introduces a facile approach aimed at enhancing OER activity by incorporating boron and phosphorus into cobalt oxide nanowires (B/P-CoOx NWs). The resulting material, enriched with oxygen vacancies (Ov), as confirmed by X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR), induced a complete structural transformation from Co3O4 to a CoO phase. The B/P-CoOx NWs exhibited an impressive overpotential of only 230 mV to achieve a current density of 10 mA cm-2 in 1 M KOH. The presence of Ov was proved to be responsible for the improvement in conductivity along with the quantity and quality of active sites. Electrochemical kinetic analysis was performed to reveal the crucial role of Ov in facilitating the OER mechanism by enhancing the adsorption and desorption of OH- ions and O2 molecules from the surface. The robustness of the developed electrocatalyst was demonstrated through a chronoamperometric test conducted over 80 h and a recyclability test spanning 10 000 cycles. This study focuses on the fabrication and dynamic investigation of the electrocatalyst, laying the groundwork for further advancements in non-noble material-based electrocatalysts. 2024 American Chemical Society. Creator An entity primarily responsible for making the resource Bhide A.; Gupta S.; Patel M.; Charlton H.; Bhabal R.; Fernandes R.; Patel R.; Patel N. Source A related resource from which the described resource is derived ACS Applied Energy Materials, Vol-7, No. 16, pp. 6898-6907. Publisher An entity responsible for making the resource available American Chemical Society Date A point or period of time associated with an event in the lifecycle of the resource 2024-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1021/acsaem.4c00816" target="_blank" rel="noreferrer noopener">https://doi.org/10.1021/acsaem.4c00816</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85200630606&amp;doi=10.1021%2Facsaem.4c00816&amp;partnerID=40&amp;md5=220985073b96aeeedd4c8659c414dac4" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85200630606&amp;doi=10.1021%2facsaem.4c00816&amp;partnerID=40&amp;md5=220985073b96aeeedd4c8659c414dac4</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 25740962 Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Bhide A., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Gupta S., Advanced Materials Department, Joef Stefan Institute, Jamova 39, Ljubljana, 1000, Slovenia; Patel M., Department of Materials, Design and Manufacturing Engineering, University of Liverpool, Liverpool, L69 3GH, United Kingdom; Charlton H., Department of Materials, Design and Manufacturing Engineering, University of Liverpool, Liverpool, L69 3GH, United Kingdom; Bhabal R., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Fernandes R., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Patel R., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Patel N., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India