Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource MOF derived cobalt-phospho-boride for rapid hydrogen generation via NaBH4 hydrolysis Subject The topic of the resource Hydrogen generation; Hydrolysis of NaBH<sub>4</sub>; Metal-organic framework; Transition metal phospho-borides Description An account of the resource Developing effective transition metal catalysts that can replace precious metal-based catalysts for hydrogen generation from the hydrolysis of chemical hydride has attracted extensive interest. This study focuses on synthesizing cobalt phospho-boride (CoPB) within a metal-organic framework (MOF) framework using hydrothermal and chemical reduction methodologies. Incorporating boron and phosphorous into Co-MOF enhances the hydrogen generation rate, reaching 1.8 L/min/g and 3.6 L/min/g for CoB-MOF and CoPB-MOF, respectively, during NaBH4 hydrolysis. Along with the nanostructured morphology of MOF, the electron modulation around Co-sites due to the presence of P and B creates a synergic effect to produce this high H2 generation rate and very low activation energy of 20.7 kJ/mol. The kinetic studies on NaBH4 hydrolysis reaction revealed zero-order kinetics with respect to NaBH4 concentration for CoPB-MOF, where porous morphology renders facile movement of BH4? ions to the active sites. The heat treatment at 773 K in the N2 atmosphere did not show any significant fall in the activity of CoPB-MOF, thus showcasing its robust nature. Moreover, the present catalyst also displayed recycling behavior with no signs of deactivation. 2024 Hydrogen Energy Publications LLC Creator An entity primarily responsible for making the resource Abraham A.; Silviya R.; Patel R.; Patel N.; Fernandes R. Source A related resource from which the described resource is derived International Journal of Hydrogen Energy, Vol-77, pp. 1245-1253. Publisher An entity responsible for making the resource available Elsevier Ltd Date A point or period of time associated with an event in the lifecycle of the resource 2024-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.ijhydene.2024.06.247" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.ijhydene.2024.06.247</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85196516475&amp;doi=10.1016%2Fj.ijhydene.2024.06.247&amp;partnerID=40&amp;md5=5050b01c79dc3666d3de39dba2a80760" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85196516475&amp;doi=10.1016%2fj.ijhydene.2024.06.247&amp;partnerID=40&amp;md5=5050b01c79dc3666d3de39dba2a80760</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 3603199; CODEN: IJHED Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Abraham A., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Silviya R., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Patel R., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Patel N., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Fernandes R., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India