MoS2-TiO2 Nanocomposites for Enhanced Photo-electrocatalytic Hydrogen Evolution
- Title
- MoS2-TiO2 Nanocomposites for Enhanced Photo-electrocatalytic Hydrogen Evolution
- Creator
- Chacko L.; Joseph A.; Tadi K.K.; Kumar A.; Narayanan T.N.; Aneesh P.M.
- Description
- The investigation on the designing and fabrication of highly efficient electrocatalysts for hydrogen evolution reaction (HER) is critical for future applications in renewable sustainable energy. The present work reports the hydrothermal synthesis of two-dimensional MoS2 and MoS2-TiO2 nanostructures. The as-prepared nanostructures were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Raman analysis, UV-vis-NIR, and photoluminescence spectrophotometry and vibrating sample magnetometer (VSM). Systematic electrochemical measurements for HER were performed and MoS2-TiO2 nanocomposites demonstrated the lowest onset potential in comparison with MoS2. The results suggest that the nanofusion interface between MoS2 nanoflakes and TiO2 nanoparticles induced an efficient charge transfer from the conduction band of MoS2 to TiO2 and favored the reduction of H+ at active sites. We believe the present work can open up new possibilities that would provide deep insights for the rational design of 2D materials-based catalysts for energy storage and conversion applications. 2023 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited.
- Source
- Journal of the Electrochemical Society, Vol-170, No. 7
- Date
- 2023-01-01
- Publisher
- Institute of Physics
- Coverage
- Chacko L., Department of Physics, Central University of Kerala, Tejaswini Hills, Periye, Kerala, Kasaragod, 671316, India, Department of Physics and Electronics, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Joseph A., Department of Physics, Central University of Kerala, Tejaswini Hills, Periye, Kerala, Kasaragod, 671316, India; Tadi K.K., Centre for Healthcare Advancement, Innovation and Research, Vellore Institute of Technology, Chennai, 600127, India; Kumar A., Tata Institute of Fundamental Research - Hyderabad, Sy. No. 36/P Serilingampally Mandal, Gopanapally Village, Hyderabad, 500 046, India; Narayanan T.N., Tata Institute of Fundamental Research - Hyderabad, Sy. No. 36/P Serilingampally Mandal, Gopanapally Village, Hyderabad, 500 046, India; Aneesh P.M., Department of Physics, Central University of Kerala, Tejaswini Hills, Periye, Kerala, Kasaragod, 671316, India
- Rights
- Restricted Access
- Relation
- ISSN: 134651; CODEN: JESOA
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Chacko L.; Joseph A.; Tadi K.K.; Kumar A.; Narayanan T.N.; Aneesh P.M., “MoS2-TiO2 Nanocomposites for Enhanced Photo-electrocatalytic Hydrogen Evolution,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 24, 2025, https://archives.christuniversity.in/items/show/14152.