Two-dimensional Ti3C2Tx MXenes as a catalyst support for the synthesis of 1,4-disubstituted-1,2,3-triazoles via azide-nitroalkene oxidative cycloaddition
- Title
- Two-dimensional Ti3C2Tx MXenes as a catalyst support for the synthesis of 1,4-disubstituted-1,2,3-triazoles via azide-nitroalkene oxidative cycloaddition
- Creator
- Verma S.K.; Verma R.; Girish Y.R.; Verma S.; Pramoda K.; Vaishnav Y.; Saji J.; Kumar K.S.S.
- Description
- Two-dimensional transition metal carbides/nitrides: MXenes have become a prime choice for researchers to exploit their outstanding properties for various applications in different fields majorly including energy, health and environment. Interestingly, there are no reports of utilizing 2D materials especially MXenes as a catalyst support for organic transformations. In the present study, we have utilized 2D Ti3C2Tx MXenes as a catalyst support for the synthesis of 1,4-disubstituted-1,2,3-triazoles via azide-nitroalkene cycloaddition for the first time. Reusability of Ti3C2Tx MXene catalyst up to five cycles without the loss of catalytic activity with appreciable yields of the product is the noteworthy feature of the present protocol. The synthesized 1,2,3-triazole derivatives possessing long alkyl chain upto fourteen carbon atoms on terminal nitrogen in triazole ring could become a good precursors to give a liquid crystalline properties beyond its biological properties. Nontoxic catalyst, catalyst reusability, broad substrate scope, and good yield are some of the salient features of the present protocol. 2023 Elsevier B.V.
- Source
- Journal of Molecular Structure, Vol-1281
- Date
- 2023-01-01
- Publisher
- Elsevier B.V.
- Subject
- 1,2,3-triazoles; Cycloaddition; MXenes; Ti3C2Tx; Two-dimensional
- Coverage
- Verma S.K., School of Chemistry and Chemical Engineering, Yulin University, Yulin, 719000, China, Shaanxi Key Laboratory of Low Metamorphic Coal Clean Utilization, Yulin University, Yulin, 719000, China; Verma R., School of Chemistry and Chemical Engineering, Yulin University, Yulin, 719000, China, Shaanxi Key Laboratory of Low Metamorphic Coal Clean Utilization, Yulin University, Yulin, 719000, China; Girish Y.R., Centre for Research & Innovations, BGSIT, Adichunchanagiri University, B.G. Nagara, Mandya District, Karnataka, 571448, India; Verma S., University college of Pharmacy Raipur, Pt. Deendayal Upadhyay Memorial Health, Sciences and Aayush University of Chhattisgarh, Chhattisgarh, Raipur, 492010, India; Pramoda K., Centre for Nano and Material Sciences, Jain University, Jain Global Campus, Bangalore-, Ramanagaram, 562112, India; Vaishnav Y., Faculty of Pharmaceutical Sciences, Shri Shankaracharya Techincal Campus, Chattisgarh, Junwani Bhilai, 491001, India; Saji J., Department of Sciences and Humanities, School of Engineering and Technology, CHRIST (Deemed to be university), Bangalore, 560029, India; Kumar K.S.S., Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru, 570 006, India
- Rights
- Restricted Access
- Relation
- ISSN: 222860; CODEN: JMOSB
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Verma S.K.; Verma R.; Girish Y.R.; Verma S.; Pramoda K.; Vaishnav Y.; Saji J.; Kumar K.S.S., “Two-dimensional Ti3C2Tx MXenes as a catalyst support for the synthesis of 1,4-disubstituted-1,2,3-triazoles via azide-nitroalkene oxidative cycloaddition,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 25, 2025, https://archives.christuniversity.in/items/show/14197.