Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Ortho-Vanillin based multifunctional scaffold for selective detection of Al3+ and Zn2+ employing molecular logic with DFT study and cell imaging with live Grass pea Subject The topic of the resource Al3+ and Zn2+ sensing; Cell imaging; DFT study; Fluorometric method; Logic gate; Multifunctional Description An account of the resource Ligand (E)-N-(2-hydroxy-3-methoxybenzylidene) acetohydrazide (HL) has been designed and synthesized from o-vanillin and acetohydrazide for selective sensing of Al3+ and Zn2+ ions. In the photoluminescence studies, the receptor HL itself shows very poor fluorescence but on incremental addition of Al3+ and Zn2+ ions in solution of the probe HL individually leads to a sharp increase in emission intensities at wavelengths 468 nm (?15 fold) and 504 nm (?8 fold) respectively. Due to excited state intramolecular proton transfer (ESIPT), HL exhibits weak emission in absence of any analytes but in presence of Al3+ and Zn2+, chelation-enhanced fluorescence (CHEF) with coordination of Al3+ and Zn2+ inhibits ESIPT, which results large increase of fluorescence enhancement. The ligand HL shows high selectivity and sensitivity to detect Al3+ and Zn2+ among various metal ions with LOD (Limit of Detection) 0.836 10?6 M and 1.01 10?6 M respectively. DFT calculation has been performed to study the binding phenomenon of ligand HL with metal ions. A molecular logic gate has been build-up with Al3+ and Zn2+ and EDTA as three chemical input. Simultaneously, cytotoxicity and cell biology for the probe and corresponding Al3+ sensing were observed. 2023 Elsevier B.V. Creator An entity primarily responsible for making the resource Das G.C.; Kumar Das A.; Das D.; Raj Maity T.; Samanta A.; Ali Alasmary F.; Salem Almalki A.; Iqbal A.; Dolai M. Source A related resource from which the described resource is derived Journal of Photochemistry and Photobiology A: Chemistry, Vol-440 Publisher An entity responsible for making the resource available Elsevier B.V. Date A point or period of time associated with an event in the lifecycle of the resource 2023-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.jphotochem.2023.114663" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.jphotochem.2023.114663</a> <a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149731671&doi=10.1016%2Fj.jphotochem.2023.114663&partnerID=40&md5=a10945aa170194dd94b74879c4ebfbae" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149731671&doi=10.1016%2fj.jphotochem.2023.114663&partnerID=40&md5=a10945aa170194dd94b74879c4ebfbae</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 10106030; CODEN: JPPCE Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Das G.C., Department of Chemistry, Prabhat Kumar College, Contai, W.B, Purba Medinipur, 721404, India; Kumar Das A., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Karnataka, Bangalore, 560029, India; Das D., Department of Chemistry, Prabhat Kumar College, Contai, W.B, Purba Medinipur, 721404, India; Raj Maity T., Department of Biotechnology, Haldia Institute of Technology, Haldia, West Bengal, Purba Medinipur721657, India; Samanta A., Department of Botany, Prabhat Kumar College, Contai, W.B, Purba Medinipur, 721404, India; Ali Alasmary F., Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia; Salem Almalki A., Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia; Iqbal A., Department of Advanced Materials & Technologies, Faculty of Materials Engineering, Silesian University of Technology, Gliwice, 44-100, Poland; Dolai M., Department of Chemistry, Prabhat Kumar College, Contai, W.B, Purba Medinipur, 721404, India