CoFe2O4/g-C3N4 intercalated Ti3C2 MXene for efficient electrocatalytic hydrogen evolution reaction
description: Seeking high-efficiency and stable electrocatalysts remains key to boosting electrocatalytic water splitting. Herein, a well-designed nontoxic MXene based composite, Ti3C2-CoFe2O4/g-C3N4 is prepared via ultrasonication for enhancing the hydrogen evolution reaction (HER). Intercalation of CoFe2O4 and g-C3N4 within the multi-layered Ti3C2 MXene results in improved properties such as high surface area, large pore volume, and a low restacking tendency that leads to enhanced electrochemical active sites, high charge carrier separation, and stability. The prepared composite is characterized via various physicochemical techniques. The amalgamated composite shows a lower overpotential of 223 mV in an alkaline medium at a current density of 10 mA cm?2. The Tafel slope and charge transfer resistance (Rct) value for the HER are 48.5 mV dec?1 and 3.94 ?, respectively. The heterojunction formation improves the efficacy of the MXene composite and provides a new perception that can be beneficial for water splitting applications. 2023 The Royal Society of Chemistry.
creator: Mathew S.; Madhushree R.; Sunaja Devi K.R.
source: Sustainable Energy and Fuels, Vol-7, No. 11, pp. 2601-2612.
publisher: Royal Society of Chemistry
date: 2023-01-01
rights: Restricted Access
relation: ISSN: 23984902
format: Online
language: English
type: Article
coverage: Mathew S., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Madhushree R., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India; Sunaja Devi K.R., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bangalore, 560029, India