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Title
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Dublin Core
The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/.
Title
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Facile synthesis of Mn-Ni bimetal organic framework decorated with amine as an electrode for a high-performance supercapacitor
Subject
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Amine functionalization; Energy storage device; h<sub>2</sub>fipbb ligand; Metal organic framework; Supercapacitor
Description
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In the recent years, the whole world is looking for better energy storage devices. Supercapacitors are among the mostpromising high-capacity energy storage devices. Manganese-based material has gained more importance among transition metals due to its cost, easy fabrication, and wide potential applications. Here, we report the synthesis of a novel MOF using metal centers, dicarboxylate ligand, and aminoterephthalic acid as a co-ligand {Mn-Ni-NH2(h2fipbb)}MOF. The synthesized material has a unique hierarchical morphology consisting of manganese and nickel connected with NH2 through h2fipbb ligand linkage, which is highly efficient for the permeation of the electrolyte and electron transfer. The {Mn-Ni-NH2(h2fipbb)}MOF shows an excellent specific capacitance of 711.60 F g?1 using 2M KOH at a current density of 1 A g?1. The two electrode system material exhibitsa high-power and energy density of 743.99Wkg?1 and 20.49 Wh kg?1, respectively. From the above results, the synthesized {Mn-Ni-NH2(h2fipbb)}MOF can be considered a promising material for electrochemical energy storageapplications. 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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Rajasekaran S.; Reghunath B.S.; K. R S.D.; Saravanakumar B.; JohnsonWilliam J.; Pinheiro D.; Arumugam M.K.
Source
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Journal of Solid State Electrochemistry, Vol-27, No. 4, pp. 911-925.
Publisher
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Springer Science and Business Media Deutschland GmbH
Date
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2023-01-01
Identifier
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<a href="https://doi.org/10.1007/s10008-023-05382-4" target="_blank" rel="noreferrer noopener">https://doi.org/10.1007/s10008-023-05382-4</a>
<br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85146565416&doi=10.1007%2Fs10008-023-05382-4&partnerID=40&md5=25af1e976f2448d55776f21e5c4b718f" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85146565416&doi=10.1007%2fs10008-023-05382-4&partnerID=40&md5=25af1e976f2448d55776f21e5c4b718f</a>
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Restricted Access
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ISSN: 14328488
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Online
Language
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English
Type
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Article
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Rajasekaran S., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; Reghunath B.S., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; K. R S.D., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; Saravanakumar B., Department of Physics, Dr. Mahalingam College of Engineering and Technology, Tamilnadu, Pollachi, 64200, India; JohnsonWilliam J., Department of Physics, Dr. Mahalingam College of Engineering and Technology, Tamilnadu, Pollachi, 64200, India; Pinheiro D., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; Arumugam M.K., Cancer Biology Lab, Centre for Molecular and Nanomedical Sciences, Sathyabama Institute of Science and Technology, Tamil Nadu, Chennai, 600119, India