Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Co-Electrodeposited Pi-MnO2-rGO as an Efficient Electrode for the Selective Oxidation of Piperonyl Alcohol Description An account of the resource Pi-MnO2-rGO-CFP electrode was developed through a concurrent deposition of Pi-MnO2 and reduced graphene oxide (rGO) on carbon fiber paper (CFP). Cyclic voltammetry (CV) and electrochemical impedance studies (EIS) were applied for the electrochemical characterization of the electrode. The electro catalytic activity of the modified electrode was improved by the increased synergistic characteristics of the CFP and electrochemically deposited rGO-Pi-MnO2 composite. The performance of the modified electrode was remarkable due to its lowest charge transfer resistance (R ct), and highest surface area offering more active sites and quicker electron transport kinetics. X-ray diffraction spectroscopy (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and optical profilometry (OP) were employed to study the physicochemical properties. Furthermore, the modified electrode was availed to oxidize piperonyl alcohol mediated by 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl (4-acetamido TEMPO or 4-ACT). The product obtained was purified and characterized by 1HNMR. The turnover frequency of 4-ACT was studied at different concentrations of the reactant, and the reaction parameters were also optimized using statistical tool design of experiment. This methodology is demonstrated to be economical, environmentally benign, and highly efficient in obtaining piperonal as it is carried out under milder reaction conditions. 2023 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. Creator An entity primarily responsible for making the resource Rodrigues R.M.; Thadathil D.A.; Shanker G.; Sirimahachai U.; Varghese A.; Hegde G. Source A related resource from which the described resource is derived Journal of the Electrochemical Society, Vol-170, No. 3 Publisher An entity responsible for making the resource available Institute of Physics Date A point or period of time associated with an event in the lifecycle of the resource 2023-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1149/1945-7111/acbdc2" target="_blank" rel="noreferrer noopener">https://doi.org/10.1149/1945-7111/acbdc2</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149510102&amp;doi=10.1149%2F1945-7111%2Facbdc2&amp;partnerID=40&amp;md5=caa2605f3f5295a70baa64c8ecc25e3a" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149510102&amp;doi=10.1149%2f1945-7111%2facbdc2&amp;partnerID=40&amp;md5=caa2605f3f5295a70baa64c8ecc25e3a</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 134651; CODEN: JESOA Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Rodrigues R.M., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India, Department of Chemistry, St Agnes College (Autonomous), Karnataka, Mangaluru, 575002, India; Thadathil D.A., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Shanker G., Department of Chemistry, Bangalore University, Jnana Bharati Campus, Bengaluru, India; Sirimahachai U., Center of Excellence for Innovation in Chemistry, Division of Physical Science, Faculty of Science, Prince of Songkhla University, Hat Yai, Songkhla, 90110, Thailand; Varghese A., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Hegde G., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India