N-doped graphene quantum dots incorporated cobalt ferrite/graphitic carbon nitride ternary composite for electrochemical overall water splitting
- Title
- N-doped graphene quantum dots incorporated cobalt ferrite/graphitic carbon nitride ternary composite for electrochemical overall water splitting
- Creator
- Reghunath B.S.; Rajasekaran S.; Devi K R S.; Pinheiro D.; Jaleel UC J.R.
- Description
- Multicomponent electrocatalysts containing carbon supports play a crucial role in influencing the hydrogen and oxygen evolution reactions which enhance the total water splitting. Herein, we report a ternary composite with cobalt ferrite, graphitic carbon nitride, and N-doped graphene quantum dots prepared via hydrothermal technique. The purity of the samples is established by carrying out various characterization methods. The intrinsic characteristics of the obtained materials are investigated by employing electrocatalytic processes in an alkaline media toward hydrogen and oxygen evolution reactions. Cobalt ferrite/graphitic carbon nitride/N doped graphene quantum dots electrocatalyst demonstrates a very low overpotential towards hydrogen evolution reaction of 287 mV at a constant 10 mA cm?2 current density in 1.0 M KOH. Tafel slope and Rct values generated are 94 mV dec?1 and 0.86 cm2, respectively. Oxygen evolution reaction studies reveal an overpotential of 445 mV at 10 mA cm?2 with a Tafel slope of 69 mV dec?1. Finally, the cell potential needed for the cobalt ferrite/graphitic carbon nitride/N doped graphene quantum dots electrode to achieve 10 mA cm?2 in total water splitting is only 2.0 V while displaying long-term stability. 2022 Hydrogen Energy Publications LLC
- Source
- International Journal of Hydrogen Energy, Vol-48, No. 8, pp. 2906-2919.
- Date
- 2023-01-01
- Publisher
- Elsevier Ltd
- Subject
- Cobalt ferrite; gCN; HER and OER; N doped graphene quantum dots; Ternary electrocatalyst; Water splitting
- Coverage
- Reghunath B.S., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; Rajasekaran S., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; Devi K R S., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; Pinheiro D., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India; Jaleel UC J.R., Department of Chemistry, CHRIST (Deemed to Be University), Karnataka, Bengaluru, 560029, India
- Rights
- Restricted Access
- Relation
- ISSN: 3603199; CODEN: IJHED
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Reghunath B.S.; Rajasekaran S.; Devi K R S.; Pinheiro D.; Jaleel UC J.R., “N-doped graphene quantum dots incorporated cobalt ferrite/graphitic carbon nitride ternary composite for electrochemical overall water splitting,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 25, 2025, https://archives.christuniversity.in/items/show/14426.