Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Laccase mediated electrosynthesis of heliotropin on mango-kernel derived carbon nanosphere composite: A sustainable approach Subject The topic of the resource Carbon nanospheres; Electrochemical oxidation; Heliotropin or piperonal; Laccase; Mango-seed kernel; TEMPO Description An account of the resource Facile fabrication of enzyme immobilized carbon nanospheres (CNS) based catalysts with high electrical conductivity and catalytic efficiency are of decisive importance for their electrocatalysis. A novel, green and highly efficient synthesis route for the development of an electrode surface with enhanced electrical conductivity and better catalytic activity for the electrochemical synthesis of heliotropin. The obtained biowaste (mango seed kernels) was pyrolyzed and subjected to acid treatment to form functionalized CNS (f-CNS). The functionalized carbon fiber paper (CFP) electrode was employed as a template for laccase immobilization which was further treated with free laccase resulting in the formation of Lac-fCNS/CFP electrode. The developed electrode exhibited excellent electrooxidation of piperonyl alcohol in the presence of 2,2,6,6-Tetramethyl-1-piperidinyloxy (TEMPO), which served as the mediator. A high yield (78%) of heliotropin was achieved during the electrooxidation at 0.78 V via bulk electrolysis. The obtained product (heliotropin aka piperonal) was confirmed via 1H NMR and 13C NMR. Additionally, computational molecular docking analysis of f-CNS:laccase composite showed strong binding affinity (?6.2 kcal/mol) with TEMPO in comparison with free laccase (?5.1 kcal/mol). The excellent selectivity and efficiency of the developed electrocatalyst aim to surpass all other reported laccase-TEMPO mediated based electrocatalytic oxidation reactions. 2022 Vietnam National University, Hanoi Creator An entity primarily responsible for making the resource Benny L.; Cherian A.R.; P K.; Varghese A.; Hegde G. Source A related resource from which the described resource is derived Journal of Science: Advanced Materials and Devices, Vol-7, No. 4 Publisher An entity responsible for making the resource available Elsevier B.V. Date A point or period of time associated with an event in the lifecycle of the resource 2022-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.jsamd.2022.100510" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.jsamd.2022.100510</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85141867912&amp;doi=10.1016%2Fj.jsamd.2022.100510&amp;partnerID=40&amp;md5=a9a4f66b3977922d3ba70c57519d4953" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85141867912&amp;doi=10.1016%2fj.jsamd.2022.100510&amp;partnerID=40&amp;md5=a9a4f66b3977922d3ba70c57519d4953</a> Rights Information about rights held in and over the resource All Open Access; Gold Open Access Relation A related resource ISSN: 24682284 Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Benny L., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bengaluru, 560029, India; Cherian A.R., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bengaluru, 560029, India; P K., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bengaluru, 560029, India; Varghese A., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bengaluru, 560029, India; Hegde G., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bengaluru, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Hosur Road, Bengaluru, 560029, India