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              <text>Electronic structure and intrinsic dielectric polarization of defect-engineered rutile TiO2</text>
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              <text>Experimental realization of colossal permittivity associated with intrinsic dielectric polarization of defect-engineered (Nb, In) co-doped rutile TiO2 appears to be most suitable for microelectronics and solid-state device applications. Combining resonant photoemission spectroscopy, X-ray absorption spectroscopy, and density functional theory calculations, we here present a coherent understanding of electronic structure, in-gap defect states, doped electron localization, and their connection with macroscopic polarization for various doping configurations. Most often, conventional sample preparation conditions introduce in-gap states of Ti3+? character, limiting the maximum achievable intrinsic polarization value. Our understanding provides a pathway to enhance intrinsic polarization and minimize dielectric loss through suitable defect-engineering.   The Royal Society of Chemistry.</text>
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              <text>Mandal S.; Ska T.; Menon K.S.R.</text>
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              <text>Journal of Materials Chemistry C, Vol-9, No. 2, pp. 595-599.</text>
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              <text>Royal Society of Chemistry</text>
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              <text>2021-01-01</text>
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              <text>&lt;a href="https://doi.org/10.1039/d0tc05108j" target="_blank" rel="noreferrer noopener"&gt;https://doi.org/10.1039/d0tc05108j&lt;/a&gt;
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              <text>ISSN: 20507534; CODEN: JMCCC</text>
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              <text>Mandal S., Physics and Electronics Department, CHRIST (Deemed to Be University), Bangalore, 560029, India; Ska T., Charles University, Faculty of Mathematics and Physics v, Holeovi?kh 2, Prague 8, 18000, Czech Republic; Menon K.S.R., Surface Physics and Material Science Division, Saha Institute of Nuclear Physics, Kolkata, 700064, India</text>
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