Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Evaluation of Corrosion Mitigation Performance of 1-(3,4,5-Trimethoxyphenylmethylidene)-2-Naphthylamine (TMPNA) Schiffs Base on Carbon Steel Using Electrochemical, Thermodynamic and Theoretical Approaches Subject The topic of the resource Adsorption isotherm; Carbon steel; Corrosion inhibitor; ENA; Naphthalene schiff base; QCA; Surface protection Description An account of the resource A novel Schiff base,1-(3,4,5-trimethoxyphenylmethylidene)-2-naphthylamine(TMPNA) has been synthesized using naphthylamine and 3,4,5-trimethoxybenzaldehyde.The effective corrosion resistance and inhibition effect of TMPNA was studied at different concentrations in water medium on carbon steel by electrochemical techniques. The protective behavior of the passive film formed by the inhibitor was characterized through electrochemical impedance spectroscopy with an increased charge transfer resistance of 954 ?.cm2. The inhibition efficiency exhibited a gradual increase up to 92% with increase in schiff base concentration. Potentiodynamic polarization studies revealed that corrosion current decreased to 0.35 10?5A/cm2 with the addition of the inhibitor, TMPNA. Through various electrochemical studies such as impedance, polarization and electrochemical noise analysis (ENA), the concentration of TMPNA was optimized to 300ppm at which the maximum corrosion resistance was observed. Inhibition efficiency was found to decrease with increase in temperature. Also, the increased activation energy (Ea) value of 27kJ/mol confirmed that the inhibitor hindered the metal dissolution reaction. Adsorption of TMPNA on carbon steel/electrolyte interface was found to obey Langmuir adsorption isotherm. Scanning electron microscope (SEM) was used to evaluate the surface morphology. The Quantum chemical analysis (QCA) revealed that there was an electron transfer between TMPNA and the metal surface at ? 6.340eV. Molecular dynamic simulation study was carried out to investigate the adsorption of TMPNA on Fe (1 1 0) surface and adsorption energy value for the gaseous form was found to be ? 4197cal/mol. 2020, Springer Nature Switzerland AG. Creator An entity primarily responsible for making the resource Kannan P.; Varghese A.; Palanisamy K.; Abousalem A.S.; George L. Source A related resource from which the described resource is derived Journal of Bio- and Tribo-Corrosion, Vol-6, No. 4 Publisher An entity responsible for making the resource available Springer Date A point or period of time associated with an event in the lifecycle of the resource 2020-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1007/s40735-020-00419-x" target="_blank" rel="noreferrer noopener">https://doi.org/10.1007/s40735-020-00419-x</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85090085709&amp;doi=10.1007%2Fs40735-020-00419-x&amp;partnerID=40&amp;md5=296d44c0e59b507886d48384bd59896c" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85090085709&amp;doi=10.1007%2fs40735-020-00419-x&amp;partnerID=40&amp;md5=296d44c0e59b507886d48384bd59896c</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 21984220 Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Kannan P., Department of Chemistry, CHRIST (Deemed To Be University), Bengaluru, 560 029, Karnataka, India; Varghese A., Department of Chemistry, CHRIST (Deemed To Be University), Bengaluru, 560 029, Karnataka, India; Palanisamy K., Department of Chemistry, Srinivasan College of Arts and Science (Affiliated to Bharathidasan University, Trichy), Perambalur, 621 212, Tamil Nadu, India; Abousalem A.S., Chemistry Department, Faculty of Science, Mansoura University, Mansoura, 35516, Egypt, Quality Control Lab, Operations Department, Jotun, Egypt; George L., Department of Chemistry, CHRIST (Deemed To Be University), Bengaluru, 560 029, Karnataka, India