Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Role of supramolecular interactions in crystal packing of Strandberg-type cluster-based hybrid solids Subject The topic of the resource electrochemical behavior; Phosphomolybdate; Strandberg-type; supramolecular interactions Description An account of the resource Abstract: Two new Strandberg-type cluster-based phosphomolybdates {H-2a3mp}5[{PO3(OH)}{PO4}Mo5O15], 1 and {H-2a4mp}5[{PO3(OH)}{PO4}Mo5O15]6H2O, 2 have been crystallized via solvent evaporation technique using 2-amino-3-methylpyridine (2a3mp) and 2-amino-4-methylpyridine (2a4mp) respectively. The solids were characterized using single-crystal X-ray diffraction, powder X-ray diffraction, fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy and cyclic voltammetry. The solid 1 crystallized in monoclinic system with space group P21/c, a = 8.394(1), b = 27.398(6), c = 21.521(4) ? = 97.68(3), Z = 4. The solid 2 crystallized in triclinic system with space group P-1, a = 11.728(1), b = 14.234(1), c = 19.589(1) ? = 68.906(3), ? = 89.454(3), ? = 66.559(3), Z = 2. The solids 1 and 2 formed a supramolecular framework stabilized by hydrogen bonding interaction between cluster anions and organic moieties. CH? interactions between the organic moieties reinforced the crystal packing in 1 and 2. While crystal packing effects resulted in the formation of solvent-accessible voids in 1; aggregation of lattice water molecules in 2 facilitated the formation of pentameric water cluster. In addition, electrochemical behavior of 1 and 2 has also been investigated. Graphic abstract: Two new Strandberg-type cluster based phosphomolybdates, 1 and 2 have been crystallized via solvent evaporation technique using 2-amino-3-methylpyridine and 2-amino-4-methylpyridine. Detailed structural analysis revealed the role of supramolecular interactions in the crystal packing of these solids. In addition, electrochemical behavior of 1 and 2 has also been investigated.[Figure not available: see fulltext.] 2020, Indian Academy of Sciences. Creator An entity primarily responsible for making the resource Joseph J.; Winson C.; Singh B.; Jose J.; Thomas J. Source A related resource from which the described resource is derived Journal of Chemical Sciences, Vol-132, No. 1 Publisher An entity responsible for making the resource available Springer Date A point or period of time associated with an event in the lifecycle of the resource 2020-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1007/s12039-020-01826-w" target="_blank" rel="noreferrer noopener">https://doi.org/10.1007/s12039-020-01826-w</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85092164214&amp;doi=10.1007%2Fs12039-020-01826-w&amp;partnerID=40&amp;md5=c667747bb8e41f49d3d82bd4f5d93532" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85092164214&amp;doi=10.1007%2fs12039-020-01826-w&amp;partnerID=40&amp;md5=c667747bb8e41f49d3d82bd4f5d93532</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 9743626; CODEN: JCSBB Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Joseph J., Centre for Sustainability Science, Research &amp; PG Department of Chemistry, St. Thomas College (Autonomous), Thrissur, 680 001, Kerala, India; Winson C., Centre for Sustainability Science, Research &amp; PG Department of Chemistry, St. Thomas College (Autonomous), Thrissur, 680 001, Kerala, India; Singh B., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110 016, India; Jose J., Department of Chemistry, CHRIST (Deemed to be University), Bengaluru, 560 029, India; Thomas J., Centre for Sustainability Science, Research &amp; PG Department of Chemistry, St. Thomas College (Autonomous), Thrissur, 680 001, Kerala, India