Conversion of alkynes into 1,2-diketones using HFIP as sacrificial hydrogen donor and DMSO as dihydroxylating agent
- Title
- Conversion of alkynes into 1,2-diketones using HFIP as sacrificial hydrogen donor and DMSO as dihydroxylating agent
- Creator
- Gujjarappa R.; Vodnala N.; Putta V.P.R.K.; Ganga Reddy V.; Malakar C.C.
- Description
- A metal-free and hypervalent iodine free conversion of internal alkynes into 1,2-diketo compounds has been described. The efficacy of the present protocol rely on the use of HFIP (1,1,1,3,3,3-Hexafluoro-2-propanol) as reducing agent of alkynes and DMSO as dihydroxylating agent of olefins to acquire the desired chemical transformations. The obtained 1,2-diketones were further transformed into useful derivatives. 2020 Elsevier Ltd
- Source
- Tetrahedron Letters, Vol-61, No. 10
- Date
- 2020-01-01
- Publisher
- Elsevier Ltd
- Subject
- 1,2-Diketones; Alkyne; Dihydroxylation; HFIP
- Coverage
- Gujjarappa R., Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal, 795004, Manipur, India; Vodnala N., Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal, 795004, Manipur, India; Putta V.P.R.K., Department of Chemistry, CHRIST (Deemed to be University), Bangalore, 560029, India; Ganga Reddy V., Centre for Advanced Materials & Industrial Chemistry (CAMIC), School of Science, RMIT University, GPO Box 2476, Melbourne, 3001, Australia; Malakar C.C., Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal, 795004, Manipur, India
- Rights
- Restricted Access
- Relation
- ISSN: 404039; CODEN: TELEA
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Gujjarappa R.; Vodnala N.; Putta V.P.R.K.; Ganga Reddy V.; Malakar C.C., “Conversion of alkynes into 1,2-diketones using HFIP as sacrificial hydrogen donor and DMSO as dihydroxylating agent,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 24, 2025, https://archives.christuniversity.in/items/show/16346.