MnO2-Pi on biomass derived porous carbon for electro-catalytic oxidation of pyridyl carbinol
- Title
- MnO2-Pi on biomass derived porous carbon for electro-catalytic oxidation of pyridyl carbinol
- Creator
- Mathew A.T.; Hegde S.; Akshaya K.B.; Kannan P.; Varghese A.; Hegde G.
- Description
- A facile electrochemical oxidation of pyridyl carbinol based on Manganese dioxide-Phosphate (MnO2-Pi) was fabricated by electro-deposition of MnO2-Pi on Porous carbon nanospheres (PCN) modified carbon fiber paper (CFP) electrode. A simple working electrode was developed initially by coating Monkey Pod (MP) derived PCN on carbon fiber paper (CFP) electrode. Voltammetric deposition of MnO2-Pi on PCN/CFP electrode was carried out in an electrolyte containing phosphate buffer and KMnO4. The modified electrodes (PCN/CFP and MnO2-Pi-PCN/CFP) were characterized by different physicochemical methods and electroanalytical techniques like cyclic voltammetry and AC impedance spectroscopy. Inorganic phosphate (Pi) and MnO2 centers present on PCN/CFP electrode plays a major role towards oxidation of pyridyl carbinol electrochemically. The proposed MnO2-Pi-PCN/CFP electrode was effectively applied for the electrochemical oxidation of pyridyl carbinol in TEMPO medium. 2020 The Author(s).
- Source
- Journal of the Electrochemical Society, Vol-167, No. 15
- Date
- 2020-01-01
- Publisher
- IOP Publishing Ltd
- Coverage
- Mathew A.T., Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, 560029, India; Hegde S., Centre for Nano-Materials and Displays, B.M.S. College of Engineering, Bengaluru, 560019, India; Akshaya K.B., Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, 560029, India; Kannan P., Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, 560029, India; Varghese A., Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, 560029, India; Hegde G., Centre for Nano-Materials and Displays, B.M.S. College of Engineering, Bengaluru, 560019, India
- Rights
- All Open Access; Hybrid Gold Open Access
- Relation
- ISSN: 134651; CODEN: JESOA
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Mathew A.T.; Hegde S.; Akshaya K.B.; Kannan P.; Varghese A.; Hegde G., “MnO2-Pi on biomass derived porous carbon for electro-catalytic oxidation of pyridyl carbinol,” CHRIST (Deemed To Be University) Institutional Repository, accessed April 1, 2025, https://archives.christuniversity.in/items/show/16386.