Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Structural investigation of discrete solvent protonated vanadium and other transition metal complexes of N-[(E)-(3-ethoxy-2-hydroxyphenyl)methylidene]benzohydrazide, synthetic, spectroscopic and cytotoxicity studies Subject The topic of the resource Aroylhydrazone; Azomethine; Copper(II) complex; EPR; Vanadium(V) complex; X-ray diffraction Description An account of the resource A new ligand 3-ethoxysalicylaldehyde benzoic hydrazone (H2ESB) and its copper(II), nickel(II), cobalt(II), zinc(II), and dioxidovanadium(V) complexes have been synthesized and characterized by elemental analysis, IR, UVVis and EPR studies. Copper(II) complex (2) contains 2,2?-bipyridine as a coligand. Aroyl hydrazone and its copper and vanadium complexes were characterised by single crystal XRD. The vanadium compound crystallized in triclinic space group P1- and copper compound in orthorhombic space group P212121. The solvent molecule DMF protonates to form ammonium ion in vanadium complex which neutralises the charge on the vanadium ion. Both complexes copper and vanadium show distorted square pyramidal geometry. From EPR results, spin Hamiltonian and bonding parameters were calculated. The g values in copper complexes indicate the presence of the unpaired electron in the dx?y orbital. In vitro cytotoxicity studies of aroylhydrazone and its complexes showed that copper, cobalt and vanadium complexes are more cytotoxic than hydrazone and other complexes against Dalton's lymphoma ascites cells (DLA). 2019 Elsevier B.V. Creator An entity primarily responsible for making the resource Vineetha M.C.; Sithambaresan M.; Nair Y.S.; Prathapachandra Kurup M.R. Source A related resource from which the described resource is derived Inorganica Chimica Acta, Vol-491, pp. 93-104. Publisher An entity responsible for making the resource available Elsevier S.A. Date A point or period of time associated with an event in the lifecycle of the resource 2019-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.ica.2019.03.040" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.ica.2019.03.040</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85063892443&amp;doi=10.1016%2Fj.ica.2019.03.040&amp;partnerID=40&amp;md5=b778d49e050ac76ea8ffb562e0dc83fc" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85063892443&amp;doi=10.1016%2fj.ica.2019.03.040&amp;partnerID=40&amp;md5=b778d49e050ac76ea8ffb562e0dc83fc</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 201693; CODEN: ICHAA Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Vineetha M.C., Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, 682 022, Kerala, India, Department of Chemistry, Sree Kerala Varma College, Thrissur, 680 011, Kerala, India; Sithambaresan M., Department of Chemistry, Faculty of Science, Eastern University, Chenkalady, Sri Lanka; Nair Y.S., Department of Chemistry, Christ University, Bengaluru, 560 029, Karnataka, India; Prathapachandra Kurup M.R., Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, 682 022, Kerala, India, Department of Chemistry, School of Physical Sciences, Central University of Kerala, Tejaswini Hills, Periye, Kasaragod, 671 316, India