Cu/Pd bimetallic supported on mesoporous TiO2 for suzuki coupling reaction
4-Nitrobiphenyl; Biphenyl; Cu/Pd-TiO2; Heterogeneous Catalysis; Suzuki Reaction
Generally bimetallic catalysts are more superior to monometallic catalysts and provide a better platform for the development of novel catalysts with enhanced activity, selectivity, and stability. In the current work we have prepared Cu/Pd bimetallic supported on mesoporous TiO2 by hydrothermal method. The prepared system was characterized by various physico-chemical techniques such as XRD, TG-DTG, SEM, EDAX, BJH isotherm, and XPS. Thermal stability and complete electronic structure were identified from TG and XPS measurements respectively. The bimetallic system was found to be very active in Suzuki cross-coupling reaction using different substrates. The products were separated and purified by column chromatography and the resultant products were characterized thoroughly by 1H NMR, and FT-IR analysis. Copyright 2018 BCREC Group. All rights reserved.
Mohan M.K.; Sunajadevi K.R.; Daniel N.K.; Gopi S.; Sugunan S.; Perumparakunnel N.C.
Bulletin of Chemical Reaction Engineering and Catalysis, Vol-13, pp. 286-294.
All Open Access; Gold Open Access; Green Open Access
https://doi.org/10.9767/bcrec.13.2.1393.286-294 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85049225927&doi=10.9767%2fbcrec.13.2.1393.286-294&partnerID=40&md5=b69b6f7ade3ddb15ba1bcab92111d16a
Mohan M.K., Department of Applied Chemistry, Cochin University of Science and Technology, Cochin-22, Kerala, India, Department of Sciences and Humanities, Christ University Faculty of Engineering, Bangalore, Karnataka, 560074, India; Sunajadevi K.R., Department of Chemistry, Christ University, Bangalore, Karnataka, 560029, India; Daniel N.K., Department of Sciences and Humanities, Christ University Faculty of Engineering, Bangalore, Karnataka, 560074, India; Gopi S., Department of Applied Chemistry, Cochin University of Science and Technology, Cochin-22, Kerala, India; Sugunan S., Department of Applied Chemistry, Cochin University of Science and Technology, Cochin-22, Kerala, India; Perumparakunnel N.C., Department of Chemistry, Sree Narayana College, Kollam, Kerala, India