Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Articles Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Synthesis, crystal structure and photophysical properties of (E)-4-(4-(2-hydroxybenzylideneamino)benzyl)oxazolidin-2-one Subject The topic of the resource Crystal packing; Ground and excited state dipole moment; Solvatochromic effect; Stokes shift Description An account of the resource A new Schiff base, (4-(benzylideneamino)benzyl)oxazolidin-2-one has been synthesised from 4-(4-aminobenzyl)oxazolidin-2-one and salicylaldehyde by a simple condensation reaction. Single-crystal X-ray analysis of (E)-4-(4-(2-hydroxybenzylideneamino) benzyl)oxazolidin-2-one (HBOA) revealed that there is a 1-D, slipped, face-to-face motif with off-set, head-to-tail stacked columns. Detailed studies on photophysical properties of the synthesised compound in solutions indicate their potential applications in the field of organic light emitting devices and nonlinear optical materials. Absorption and fluorescence study of HBOA has been conducted in a series of solvents with increasing polarity at room temperature. Ground and excited state dipole moments have been determined experimentally by using LippertMataga polarity function, Bakhshiev solvent polarity parameter, KawskiiChammaViallet solvent polarity parameter and Richardt?s microscopic solvent polarity parameter. Due to the considerable ?-electron density redistribution, the excited state dipole moment was found to be larger than that of the ground state. The ground state dipole moment value was determined by quantum chemical method which was used to estimate excited state dipole moment through solvatochromic correlations. KamletTaft and Catalan methods were used to get the information of both non-specific solutesolvent interactions and hydrogen bonding interactions. TD-DFT (B3LYP/6-311G(d,p)) has been used for the determination of HOMOLUMO energies. Mulliken charges and Molecular electrostatic potential were also evaluated from DFT calculations. 2016 Elsevier B.V. Creator An entity primarily responsible for making the resource Kumari R.; Varghese A.; George L. Source A related resource from which the described resource is derived Journal of Luminescence, Vol-179, pp. 518-526. Publisher An entity responsible for making the resource available Elsevier B.V. Date A point or period of time associated with an event in the lifecycle of the resource 2016-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.jlumin.2016.07.022" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.jlumin.2016.07.022</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-84984858116&amp;doi=10.1016%2Fj.jlumin.2016.07.022&amp;partnerID=40&amp;md5=00cc69bbdfc3562f04c7df40716eb416" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-84984858116&amp;doi=10.1016%2fj.jlumin.2016.07.022&amp;partnerID=40&amp;md5=00cc69bbdfc3562f04c7df40716eb416</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 222313; CODEN: JLUMA Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Article Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Kumari R., Department of Chemistry, Christ University, Bangalore, 560029, India; Varghese A., Department of Chemistry, Christ University, Bangalore, 560029, India; George L., Department of Chemistry, Christ University, Bangalore, 560029, India