Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}-phenyl acetate monohydrate
- Title
- Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}-phenyl acetate monohydrate
- Creator
- Datta R.; Ramya V.; Sithambaresan M.; Prathapachandra Kurup M.R.; Simpson J.
- Description
- The asymmetric unit of the title compound, C15H13N3O3H2O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazinyl-idene]methyl}phenyl acetate molecule and a solvent water molecule linked by O - H?O and O - H?N hydrogen bonds from the water molecule and a C - H?O contact from the organic molecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90 (7). The azomethine bond [1.275 (2) distance is very close to the formal C=N bond length, which confirms the azomethine bond formation. An extensive set of O - H?O, O - H?N, N - H?O and C - H?O hydrogen bonds builds a two-dimensional network progressing along the c axis.
- Source
- Acta Crystallographica Section E: Structure Reports Online, Vol-71, No. 2, pp. o79-o80.
- Date
- 2015-01-01
- Publisher
- International Union of Crystallography
- Subject
- Aroyl hydrazone; Crystal structure; Hydrazone; Hydrogen bonding
- Coverage
- Datta R., Department of Chemistry, Christ University, Hosur Road, Bangalore, 560 029, India; Ramya V., Department of Chemistry, Christ University, Hosur Road, Bangalore, 560 029, India; Sithambaresan M., Department of Chemistry, Faculty of Science, Eastern University, Sri Lanka, Chenkalady, Sri Lanka; Prathapachandra Kurup M.R., Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, 682 022, India; Simpson J., University of Otago, New Zealand
- Rights
- All Open Access; Gold Open Access; Green Open Access
- Relation
- ISSN: 16005368
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Datta R.; Ramya V.; Sithambaresan M.; Prathapachandra Kurup M.R.; Simpson J., “Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}-phenyl acetate monohydrate,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 25, 2025, https://archives.christuniversity.in/items/show/17244.