Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Conference Papers Conference Paper Faculty Publications- Conference Papers Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Significance of extra-framework monovalent and divalent cation motion upon CO2 and N2 sorption in zeolite X Subject The topic of the resource Adsorption; Divalent cations; Flue gas; GCMC (Grand Canonical Monte Carlo); Zeolite-X Description An account of the resource Experimental observations and the GCMC (Grand Canonical Monte Carlo) simulations with fixed and mobile cations in their cavities have been used to study nitrogen and carbon dioxide sorption in divalent cation (Ca, Sr, and Ba) exchanged Zeolite X. Simulations of carbon dioxide and nitrogen adsorption isotherms and the heat of adsorption in divalent cation exchanged zeolite X produced results that were similar to those found in experimental results. Both experimental and simulated isotherms showed that carbon dioxide adsorption capacity is saturated at lower pressure with high adsorption capacity than the nitrogen isotherm in all zeolite samples. In the order of electronegativity of the extra-framework cations, the isosteric heat of sorption results show that carbon dioxide as well as nitrogen molecules interact more with divalent metal ion exchanged zeolites. Simulations of carbon dioxide and the nitrogen sorption in zeolite -X revealed that the mobile extra-framework cations in the cages of zeolite X had a significant advantage over zeolite molecular sieves in the separation process. The simulation with mobile cations can be a good tool for developing selective and purposeful zeolite-based adsorbents by knowing the cation position and its migration upon the adsorption of various gases. 2022 Creator An entity primarily responsible for making the resource Peters S.; Pillai R.S.; Jasra R.V. Source A related resource from which the described resource is derived Materials Today: Proceedings, Vol-68, pp. 85-92. Publisher An entity responsible for making the resource available Elsevier Ltd Date A point or period of time associated with an event in the lifecycle of the resource 2022-01-01 Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.matpr.2022.06.105" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.matpr.2022.06.105</a> <br /><br /><a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-85132932653&amp;doi=10.1016%2Fj.matpr.2022.06.105&amp;partnerID=40&amp;md5=f572af11c7591066db2c989b75f98070" target="_blank" rel="noreferrer noopener">https://www.scopus.com/inward/record.uri?eid=2-s2.0-85132932653&amp;doi=10.1016%2fj.matpr.2022.06.105&amp;partnerID=40&amp;md5=f572af11c7591066db2c989b75f98070</a> Rights Information about rights held in and over the resource Restricted Access Relation A related resource ISSN: 22147853 Format The file format, physical medium, or dimensions of the resource Online Language A language of the resource English Type The nature or genre of the resource Conference paper Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Peters S., Department of Chemistry, School of Basic Sciences, SRM Institute of Science and Technology, Kattankulathur, 603 203, India; Pillai R.S., Department of Chemistry, Christ University, Bangalore, 560029, India; Jasra R.V., Reliance Technology Group, Reliance Industries Limited, Vadodara Manufacturing Division, Vadodara, 391 346, India