Doping and Surface Modification of Carbon Quantum Dots for Enhanced Functionalities and Related Applications

Title

Doping and Surface Modification of Carbon Quantum Dots for Enhanced Functionalities and Related Applications

Creator

John V.L.; Nair Y.; Vinod T.P.

Description

Carbon quantum dots (CQDs) are a unique class of 0D nanomaterials, featured by a graphitic core and shell layers saturated with hydrogen atoms and functional groups. CQDs are prepared through top-down and bottom-up strategies from natural and synthetic precursors. CQDs can be modified through chemical (e.g., surface functionalization/passivation, doping, etc.) and physical (e.g., coreshell architecture, composite material blending, etc.) strategies to control their properties. This review highlights the effect of such modifications on the photophysical properties of CQDs, such as photoluminescence (PL), absorbance, and relaxivity. The dependence of PL upon the size, orientation at the edges, surface and edge functionalization, doping, excitation wavelength, concentration, pH, aggregate formation, etc., are summarized along with the supporting theoretical evidence available in the literature. Also, this review outlines the recent advancements, and future prospective of optical (e.g., sensing, bioimaging, and fluorescent ink) and catalytic applications (e.g., photocatalysis and electrocatalysis) of CQDs enhanced through physical and chemical modifications of their structure and composition. 2021 Wiley-VCH GmbH

Source

Particle and Particle Systems Characterization, Vol-38, No. 11

Date

2021-01-01

Publisher

John Wiley and Sons Inc

Subject

0D nanomaterials; carbon quantum dots; fluorescent inks; heteroatom doping; photocatalysis; photoluminescence mechanism; sensors

Coverage

John V.L., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bangalore, 560029, Karnataka, India; Nair Y., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bangalore, 560029, Karnataka, India; Vinod T.P., Department of Chemistry, CHRIST (Deemed to be University), Hosur Road, Bangalore, 560029, Karnataka, India

Rights

Restricted Access

Relation

ISSN: 9340866; CODEN: PPCHE

Format

Online

Language

English

Type

Review

Identifier

https://doi.org/10.1002/ppsc.202100170

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