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                <text>Faculty Publications</text>
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              <text>Toms, Snigdha; Jafri R, Imran; Vedarajan, Raman; Habibuddin, Shaik</text>
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              <text>Cobalt Embedded N-Doped Carbon Spheres Derived From Cassava Starch for Enhanced Oxygen Reduction Reaction in Alkaline Medium</text>
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              <text>01-01-2026</text>
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              <text>Particle and Particle Systems Characterization;Volume;43;Issue;4;Article No.;e70088;</text>
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              <text>&lt;a href="https://doi.org/10.1002/ppsc.70088" target="_blank" rel="noreferrer noopener"&gt;https://doi.org/10.1002/ppsc.70088&lt;/a&gt; &lt;br /&gt;&lt;br /&gt;&lt;a href="https://www.scopus.com/pages/publications/105035585918?origin=resultslist" target="_blank" rel="noreferrer noopener"&gt;https://www.scopus.com/pages/publications/105035585918?origin=resultslist&lt;/a&gt;</text>
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              <text>Toms S., Department of Physics and Electronics, CHRIST (Deemed to be University), Bengaluru, India; Jafri R I., Department of Physics and Electronics, CHRIST (Deemed to be University), Bengaluru, India; Vedarajan R., Centre for Fuel Cell Technology, International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Chennai, India; Habibuddin S., Department of Physics, School of Applied Sciences and Humanities, Vignan's Foundation for Science, Technology and Research, Guntur, India</text>
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              <text>Cathodic oxygen reduction reaction (ORR) is essential for fuel cells and metal-air batteries. The sluggishness of ORR necessitates the synthesis of effective and durable catalysts to intensify the reaction process without compromising cost-effectiveness. Here, cobalt and cobalt oxides were embedded on N-doped carbon microspheres (Co?N?C/CS) using cassava starch as a carbon source. The catalyst exhibits a surface area of 388.73 m2 g?1, with a predominantly mesoporous texture. The presence of the Co?N bond, along with pyridinic and graphitic nitrogen, contributes to the ORR activity by enhancing the density of active sites. The catalyst achieves a limiting current density of ?4.64mA cm?2 with an onset potential of 0.91V (vs RHE). The calculated electron transfer value of 3.74 indicates the 4e- pathway ORR mechanism supported by Co?N?C/CS. Moreover, the catalyst demonstrates a high stability in 0.1M KOH with 99% of current retention after 14000 s, exceeding commercial Pt/C. Relatively high methanol tolerance was also observed for Co?N?C/CS by the addition of 3M methanol in the electrolyte during current-time response, highlighting its suitability as a cathode catalyst for direct methanol fuel cells (DMFC).  2026 Wiley-VCH GmbH.</text>
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              <text>biomass-derived carbon; carbon microspheres; non-noble metal catalysts; oxygen reduction reaction</text>
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              <text>John Wiley and Sons Inc</text>
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              <text>ISSN: 9340866; CODEN: PPCHE</text>
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              <text>English</text>
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              <text>Restricted Access; Hardcopy may be available in the library</text>
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              <text>online</text>
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