Bimetallic Cobalt-Vanadium Boride as a Bifunctional Electrocatalyst for Overall Water Splitting
subject: Amorphous metal boride; Bifunctional electrocatalyst; Cobalt-Vanadium boride; Hydrogen evolution reaction; Oxygen evolution reaction
description: The transition to a hydrogen-based economy necessitates the development of sustainable and cost-effective electrocatalysts for green hydrogen production via water electrolysis. In this study, we report a novel cobalt-vanadium boride (CoVB) catalyst, which exhibits enhanced bifunctional activity for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline media. CoVB was synthesized using a facile one-step chemical reduction method with varying vanadium concentrations, optimizing performance at a 3% vanadium content. Electrochemical analyses demonstrated that CoVB significantly outperformed cobalt boride (CoB), achieving an HER and OER overpotential (?10) of 80mV and 320mV, respectively, comparable to noble metal benchmarks. Characterization results revealed that V plays a promoting role in inhibiting the growth of particles and agglomeration of particles, leading to an increase in surface area and producing unique mixed amorphous and crystalline structures in CoVB to enhance catalytic activity by increasing the number of active sites and conductivity across the interface. Furthermore, in two-electrode systems, the cell voltage of 1.66V was needed to achieve 10mA/cm2 of current density with superior stability and reusability. Overall, the CoVB catalyst, a new candidate from the metal boride family, presents a promising alternative to precious metals for efficient and sustainable water-splitting in alkaline electrolyzers. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2025.
creator: Falake, Maheshwar B.; Bhabal, Rinkoo; Chunduri, Avani; Dhulia, Vinita; Patel, Rupali; Patel, Nainesh
source: Electrocatalysis;Volume;16;Issue;4;pp.645-654
publisher: Springer
date: 01-01-2025
rights: Restricted Access; Hardcopy may be available in the library
relation: ISSN: 18682529;
format: online
language: English
type: Article
coverage: Falake M.B., Department of Physics, NES Ratnam College of Arts, Science and Commerce, University of Mumbai, Bhandup (W), Mumbai, 400078, India, Department of Physics, SIES College of Arts, Science and Commerce, Sion (W), University of Mumbai, Mumbai, 400022, India; Bhabal R., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Chunduri A., Department of Physics, University of Mumbai, Vidyanagari, Santacruz (E), Mumbai, 400098, India; Dhulia V., Department of Physics, NES Ratnam College of Arts, Science and Commerce, University of Mumbai, Bhandup (W), Mumbai, 400078, India; Patel R., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Patel N., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India