Electrospun PAN/TEMPO nanofiber electrode: Dual charge storage mechanism for supercapacitor applications
subject: Clean energy; Composite nanofibers; Electrospinning; Energy storage; PAN; Supercapacitor; Sustainable; TEMPO
description: An advanced electrode material for asymmetric supercapacitors was created by electrospinning a polyacrylonitrile (PAN)/2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) composite. Strong interfacial interactions between the PAN chains and TEMPO nitroxide radicals were confirmed by Fourier transform infrared spectroscopy, which showed partial suppression of the PAN nitrile (C tbnd N) vibrations. X-ray diffraction revealed increased short-range molecular ordering of PAN caused by TEMPO via dipoledipole interactions, without changing the semicrystalline structure. In morphological studies, the incorporation of TEMPO showed decrease in the fiber diameter and enhanced surface roughness as compared to PAN fibers, resulting in the interconnected nanofibrous network with enhanced electrolyte accessibility. A mesoporous architecture with a quantifiable surface area and pore volume was characterized by BET analysis. A higher D-to-G band intensity ratio was found by Raman spectroscopy, which quantitatively indicated the formation of defects and improved electrochemically active sites in the PAN/TEMPO composite. The PAN/TEMPO electrode facilitates a dual charge storage mechanism that combines electrical double-layer capacitance from the nanofibrous PAN matrix and pseudocapacitance from reversible TEMPO redox activity due to these synergistic structural and chemical modifications. The assembled asymmetric supercapacitor exhibits a stable energy density of 7.71 Wh kg?1 and a power density of 365.33 W kg?1, and the composite electrode provides improved capacitive performance in acidic electrolyte. Additionally, Raman and EIS studies were performed for the PAN/TEMPO electrode after performing 5000 galvanostatic charge/discharge cycles to check the stability of the material. Overall, this work provides a novel approach to design supercapacitor electrodes with a structuredefectredox synergy in TEMPO-modified electrospun PAN nanofibers. 2026 The Authors
creator: Desai, Nakul; Mathew, Aishwarya Joji; Sudhakar, Y.N.; Vinod, T.P.; Joshi, Suraj Sunil; Choudhari, K.S.
source: Composites Part B: Engineering;Volume;313;Issue;;Article No.;113405;
publisher: Elsevier Ltd
date: 01-01-2026
rights: All Open Access; Hybrid Gold Open Access
relation: ISSN: 13598368; CODEN: CPBEF
format: online
language: English
type: Article
coverage: Desai N., Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, India; Mathew A.J., Department of Chemistry, Christ University, Hosur Road, Bengaluru, 560029, India; Sudhakar Y.N., Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, India; Vinod T.P., Department of Chemistry, Christ University, Hosur Road, Bengaluru, 560029, India, Centre for Renewable Energy and Environmental Sustainability, Christ University, Hosur Road, Bengaluru, 560029, India; Joshi S.S., Manipal Institute of Applied Physics, Manipal Academy of Higher Education, Manipal, Karnataka, 576104, India; Choudhari K.S., Manipal Institute of Applied Physics, Manipal Academy of Higher Education, Manipal, Karnataka, 576104, India