Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Faculty Publications Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Creator An entity primarily responsible for making the resource Manuel, Manju; Bisetty, Krishna; Kanchi, Suvardhan Title A name given to the resource Novel biogenic CNS@AgNPs hybrid nanostructures for electrochemical detection of sucralose: Experimental and in silico strategies Date A point or period of time associated with an event in the lifecycle of the resource 01-01-2025 Source A related resource from which the described resource is derived Diamond and Related Materials;Volume;160;Issue;;Article No.;112960; Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.diamond.2025.112960" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.diamond.2025.112960</a> <br /><br /><a href="https://www.scopus.com/pages/publications/105019741627?origin=resultslist" target="_blank" rel="noreferrer noopener">https://www.scopus.com/pages/publications/105019741627?origin=resultslist</a> Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Manuel M., Department of Chemistry, CHRIST University, Bengaluru, 560029, India, Centre for Renewable Energy and Environmental Sustainability, CHRIST University, Bengaluru, 560 029, India; Bisetty K., Department of Chemistry, Faculty of Applied Sciences, Durban University of Technology, Durban, 4000, South Africa; Kanchi S., Department of Chemistry, CHRIST University, Bengaluru, 560029, India, Centre for Renewable Energy and Environmental Sustainability, CHRIST University, Bengaluru, 560 029, India Description An account of the resource Carbon, the most abundant and versatile element, has played a significant role in scientific innovations, forming the backbone of material science and nanotechnology. This study presents the first reported simultaneous photogenic synthesis of carbon nanospheres (CNS) integrated with silver nanoparticles (CNS@AgNPs) using Coriander sativum seed extract for sucralose detection. The CNS@AgNPs formation, mediated by oleic acid from the extract, was confirmed with GCMS analysis. The morphology of the CNS@AgNPs was characterized using SEM, TEM, XPS, XRD, Raman, BET, Diffuse Reflectance Spectroscopy (DRS), and Thermogravimetric analysis (TGA). The fabricated GE/Nafion/CNS@AgNPs electrode demonstrated an intense oxidation peak current at +0.7V, with Differential Pulse Voltammetry (DPV) showing a linear response from 2.0 to 14?M, with a LOD and LOQ of 0.2?M and 0.62?M (R2=0.998), respectively. The Density Functional Theory (DFT) studies revealed key mechanistic insights, including the methanol cleavage energy (~3.135נ103eV) and HOMO-LUMO differences between neutral sucralose and its cationic form. Monte Carlo (MC) simulations confirmed favourable adsorption energy (?52.739kcal/mol) with specific binding interactions (3.3578.653 influencing electron transfer pathways. This eco-friendly approach presents the potential of sustainable materials for developing efficient electrochemical sensors for detecting artificial sweeteners in real samples. 2025 Elsevier B.V. All rights are reserved, including those for text and data mining, AI training, and similar technologies. Subject The topic of the resource Carbon nanospheres; DFT; Electrochemical sensor; Monte Carlo simulation; Silver nanoparticles; Sucralose Publisher An entity responsible for making the resource available Elsevier Ltd Relation A related resource ISSN: 9259635; CODEN: DRMTE Language A language of the resource English Type The nature or genre of the resource Article Rights Information about rights held in and over the resource Restricted Access; Hardcopy may be available in the library Format The file format, physical medium, or dimensions of the resource online