Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Faculty Publications Article Faculty Publications -Articles Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Creator An entity primarily responsible for making the resource Abraham, Anitha; Fernandes, Rohan; S M, Nandana; Sunny, Jismy; John, Riya Alice B.; Gupta, Suraj; Suryawanshi, Akash; Bhabal, Rinkoo; Patel, Rupali; Patel, Nainesh Title A name given to the resource Tailored cobaltnickel phospho-boride from metalorganic frameworks as high-performance catalyst for NaBH4 dehydrogenation Date A point or period of time associated with an event in the lifecycle of the resource 01-01-2025 Source A related resource from which the described resource is derived Journal of Alloys and Compounds;Volume;1040;Issue;;Article No.;183440; Identifier An unambiguous reference to the resource within a given context <a href="https://doi.org/10.1016/j.jallcom.2025.183440" target="_blank" rel="noreferrer noopener">https://doi.org/10.1016/j.jallcom.2025.183440</a> <br /><br /><a href="https://www.scopus.com/pages/publications/105015048279?origin=resultslist" target="_blank" rel="noreferrer noopener">https://www.scopus.com/pages/publications/105015048279?origin=resultslist</a> Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Abraham A., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Fernandes R., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; S M N., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Sunny J., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; John R.A.B., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Gupta S., Advanced Materials Department, Joef Stefan Institute, Jamova 39, Ljubljana, 1000, Slovenia; Suryawanshi A., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Bhabal R., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Patel R., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India; Patel N., Department of Physics and Electronics, CHRIST University, Bengaluru, 560029, India Description An account of the resource Achieving efficient hydrogen generation (HGR) via the hydrolysis of sodium borohydride (NaBH4) remains a key challenge in developing cost-effective and high-performance catalytic systems for chemical hydrogen storage. In this study, we present a novel bimetallic phospho-boride-modified metal-organic framework catalyst (CoNi-PB-MOF), synthesized through a two-step process involving hydrothermal assembly followed by chemical reduction. The co-incorporation of phosphorus and boron into the bimetallic Co-Ni MOF facilitates the formation of 2D MOF-derived nanoplates embedded with Co3O4 nanoparticles doped with P and B. This hybrid structure features a high surface area, abundant active sites, and reduced charge-transfer resistance, enabling superior catalytic activity. The CoNi-PB-MOF catalyst achieves an impressive HGR of 7.33 L/min/g from NaBH4 hydrolysis, outperforming its monometallic counterparts. Comprehensive physicochemical and electrochemical analyses confirm the synergistic roles of Co, Ni, P, and B in enhancing catalytic performance, while preserving the porous MOF morphology post-modification. The CoNi-PB-MOF catalyst exhibits a low activation energy of 25.6 kJ/mol, along with excellent thermal stability and cyclic durability under harsh conditions. Kinetic studies reveal a zero-order reaction with respect to NaBH4 concentration, attributed to efficient mass transport and surface diffusion on the optimized catalyst surface. 2025 Elsevier B.V. Subject The topic of the resource Bimetallic Catalysts; Hydrogen Generation Rate; Metal-Organic Framework; NaBH₄ Hydrolysis Publisher An entity responsible for making the resource available Elsevier Ltd Relation A related resource ISSN: 9258388; CODEN: JALCE Language A language of the resource English Type The nature or genre of the resource Article Rights Information about rights held in and over the resource Restricted Access; Hardcopy may be available in the library Format The file format, physical medium, or dimensions of the resource online