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                <text>Faculty Publications</text>
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          <name>Creator</name>
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              <text>Babu, Ann Mariella; Mathew, Sobin; Varghese, Anitha</text>
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              <text>Silver decorated copper coordination polymer for the electroreduction of CO2 to hydrocarbon liquid fuels</text>
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              <text>01-01-2025</text>
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              <text>Journal of Environmental Chemical Engineering;Volume;13;Issue;3;Article No.;116675;</text>
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              <text>&lt;a href="https://doi.org/10.1016/j.jece.2025.116675" target="_blank" rel="noreferrer noopener"&gt;https://doi.org/10.1016/j.jece.2025.116675&lt;/a&gt; &lt;br /&gt;&lt;br /&gt;&lt;a href="https://www.scopus.com/pages/publications/105004339725?origin=resultslist" target="_blank" rel="noreferrer noopener"&gt;https://www.scopus.com/pages/publications/105004339725?origin=resultslist&lt;/a&gt;</text>
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              <text>Babu A.M., CHRIST University, Karnataka, Bangalore, 560029, India; Mathew S., CHRIST University, Karnataka, Bangalore, 560029, India; Varghese A., CHRIST University, Karnataka, Bangalore, 560029, India</text>
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              <text>Recently, the development of bimetallic interfaces has emerged as a promising strategy for enhancing electrocatalytic CO2 electroreduction (CO2ER) efficiently, with selectivity towards energy-dense hydrocarbons. In this study, we report an electrochemically designed silver-decorated copper-dimercapto thiadiazole modified carbon electrode (Ag@Cu-DM), which facilitates a controlled transition from C1to C2liquid products. The optimized electrochemical synthesis method enabled precise control over the polymer-metal interface, promoting strong electronic interactions and charge transfer. The multiple characterizations conducted for the material revealed distinct lattice fringes corresponding to well-defined Cu and Ag phases. The interplay between Cu and Ag, along with the heteroatoms present within the polymer enhances CO2  activation and intermediate stabilization. The developed Ag@Cu-DM catalyst achieved 89 % F.E. for liquid products alone at a low potential of -0.73 V vs RHE and also demonstrated stable electrolysis for upto 8 Hr.  2025 Elsevier Ltd. All rights reserved.</text>
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              <text>C&lt;sub&gt;2&lt;/sub&gt;products; CO&lt;sub&gt;2&lt;/sub&gt;electroreduction; Copper-silver electrocatalysts; Electrochemical synthesis; Multi-carbon products</text>
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              <text>Elsevier Ltd</text>
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              <text>ISSN: 22133437;</text>
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              <text>Restricted Access; Hardcopy may be available in the library</text>
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              <text>online</text>
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