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            <description>A name given to the resource</description>
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                <text>Faculty Publications</text>
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    <name>Article</name>
    <description>Faculty Publications -Articles</description>
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          <name>Creator</name>
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              <text>A, Akshaya; Bhamu, K.C.; Kalal, Shailesh; Bhabal, Rinkoo; Tayal, Akhil; Gloskovskii, Andrei; Zema, N.; Patel, Nainesh; Kang, Sung Gu; Hsiao, Ching-Lien; Gupta, Mukul</text>
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          <name>Title</name>
          <description>A name given to the resource</description>
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              <text>Negative-Valent Palladium-Stabilized CoPdN Thin Films as a Catalyst for the Oxygen Evolution Reaction</text>
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          <name>Date</name>
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            <elementText elementTextId="210236">
              <text>01-01-2025</text>
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          <name>Source</name>
          <description>A related resource from which the described resource is derived</description>
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            <elementText elementTextId="210237">
              <text>ACS Applied Nano Materials;Volume;8;Issue;50;pp.24003-24012</text>
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          <name>Identifier</name>
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              <text>&lt;a href="https://doi.org/10.1021/acsanm.5c04287" target="_blank" rel="noreferrer noopener"&gt;https://doi.org/10.1021/acsanm.5c04287&lt;/a&gt; &lt;br /&gt;&lt;br /&gt;&lt;a href="https://www.scopus.com/pages/publications/105025203960?origin=resultslist" target="_blank" rel="noreferrer noopener"&gt;https://www.scopus.com/pages/publications/105025203960?origin=resultslist&lt;/a&gt;</text>
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              <text>A A., UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore, 452001, India; Bhamu K.C., Department of Physics, SLAS, Mody University of Science and Technology, Lakshmangarh, Rajasthan, Sikar, 332311, India; Kalal S., Department of Physics, Chemistry and Biology, Linkings Universitet, Linking, SE-581 83, Sweden; Bhabal R., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Tayal A., Deutsches Elektronen-Synchrotron, Notkestrasse 85, Hamburg, 22607, Germany; Gloskovskii A., Deutsches Elektronen-Synchrotron, Notkestrasse 85, Hamburg, 22607, Germany; Zema N., Istituto Struttura della Materia-CNR (ISM-CNR), Via del Fosso del Cavaliere 100, Roma, 00133, Italy; Patel N., Department of Physics and Electronics, Christ University, Bengaluru, 560029, India; Kang S.G., School of Chemical Engineering, University of Ulsan, Ulsan Daehak-ro 93 Nam-gu, Ulsan, 44610, South Korea; Hsiao C.-L., Department of Physics, Chemistry and Biology, Linkings Universitet, Linking, SE-581 83, Sweden; Gupta M., UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore, 452001, India</text>
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              <text>The urgent global demand for sustainable energy drives the search for durable and efficient electrocatalysts for water splitting. Cobalt mononitride (CoN) stands out due to its earth abundance, high conductivity, and corrosion resistance, but its thermodynamic instability often results in cobalt-rich secondary phases. Here, we report a scalable reactive cosputtering approach for the controlled synthesis of CoN thin films, along with palladium (Pd) incorporation to enhance activity and stability. Pd doping induces a negative valence state and promotes electron transfer from nitrogen to Pd sites, thereby refining the microstructure, redistributing charge, and shifting the d-band center away from the Fermi level. These synergistic effects reduce the overpotential from 470 to 360 mV at 10 mAcm2 in a sample coated on the ITO substrate and deliver markedly improved long-term OER stability with increased catalytically active sites. The turnover frequency showed nearly twice the intrinsic activity with Pd doping. This work establishes Pd-doped CoN as a high-performance, durable electrocatalyst, offering a scalable pathway toward efficient water splitting technologies.  2025 American Chemical Society</text>
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              <text>cobalt mononitride; magnetron sputtering; oxygen evolution reaction; transition metal nitride</text>
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              <text>American Chemical Society</text>
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              <text>ISSN: 25740970;</text>
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              <text>English</text>
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              <text>Restricted Access; Hardcopy may be available in the library</text>
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              <text>online</text>
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